Aqueous Proton Transfer Pathways in Bimolecular Acid-Base Neutralization

  • Omar F. Mohammed
  • Katrin Adamczyk
  • Dina Pines
  • Ehud Pines
  • Erik T. J. Nibbering
Chapter
Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 92)

Abstract

We expand the classic Eigen-Weller reaction model with solvent-switch pathways, mediating proton transfer between acids and bases, having one or several water molecules, activated by the solvent and controlled by the base strength.

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References

  1. 1.
    A. Weller, Progr. React. Kinet. 1, 187, 1961.Google Scholar
  2. 2.
    M. Eigen, Angew. Chem. Int. Ed. 3, 1, 1964.CrossRefGoogle Scholar
  3. 3.
    M. Rini, B.-Z. Magnes, E. Pines and E.T.J. Nibbering, Science 301, 349, 2003.CrossRefADSGoogle Scholar
  4. 4.
    O. F. Mohammed, D. Pines, J. Dreyer, E. Pines and E. T. J. Nibbering, Science 310, 83, 2005.CrossRefADSGoogle Scholar
  5. 5.
    O. F. Mohammed, D. Pines, E. T. J. Nibbering, E. Pines, Angew Chem. Intl. Ed. 46, 1458, 2007.CrossRefGoogle Scholar
  6. 6.
    O. F. Mohammed, D. Pines, E. Pines, E. T. J. Nibbering, Chem. Phys. 341, 240 (2007).CrossRefADSGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2009

Authors and Affiliations

  • Omar F. Mohammed
    • 1
  • Katrin Adamczyk
    • 1
  • Dina Pines
    • 2
  • Ehud Pines
    • 2
  • Erik T. J. Nibbering
    • 1
  1. 1.Max Born Institut für Nichtlineare Optik und KurzzeitspektroskopieBerlinGermany
  2. 2.Department of ChemistryBen Gurion University of the NegevBeer-ShevaIsrael

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