Shock Waves pp 781-785 | Cite as

Shock-tube study of the ignition delay time of tetraethoxysilane (TEOS)

  • A. Abdali
  • M. Fikri
  • H. Wiggers
  • C. Schulz

Summary

Ignition delay times of tetraethoxysilane (TEOS) mixtures diluted with dry and humid synthetic air were measured behind reflected shock waves by monitoring the chemiluminescence emission of the CH* radical near 431 nm. The measurements were carried out for temperatures ranging from 1150 to 1350 K and an average pressure of 8 bar. The ignition-delay times of TEOS were determined as a function of water concentration. Additionally, TEOS stability in presence of humid air was investigated by means of Fourier transform infrared spectroscopy (FTIR) to insure that the mixture does not react prior to shock-wave heating. The results show that the stability of TEOS is not affected under the experimental conditions but that the presence of moisture in the TEOS/air mixture increases the ignition-delay times systematically.

Keywords

Silica Nanoparticles Shock Tube Rotary Pump Drive Section Chemiluminescence Emission 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    A. Gutsch, H. Mühlenweg, et al. Tailor-made nanoparticles via gas-phase synthesis. Small, 1(1): 30-46, 2005CrossRefGoogle Scholar
  2. 2.
    R. Mueller, H. K. Kammler, S. E. Pratsinis, A. Vital, G. Beaucage, P. Burtscher. Non-agglomerated dry silica nanoparticles. Powder Technol. 140: 40-48, 2004.CrossRefGoogle Scholar
  3. 3.
    S. E. Pratsinis. Material synthesis in aerosol reactors. Chem. Eng. Prog. 85(5): 62-66, 1989.Google Scholar
  4. 4.
    J. Herzler, J. A. Manion, et al. Single-Pulse Shock Tube Study of the Decomposition of Tetraethoxysilane and Related Compounds. J. Phys. Chem. A 101(30): 5500 -5508, 1997.CrossRefGoogle Scholar
  5. 5.
    J. C. S. Chu, R. S., M. C. Lin. Thermal Decomposition of Tetraethyl Orthosilicate in the Gas Phase: An Experimental and Theoretical Study of the Initiation Process. Journal of Physical Chemistry 99: 663-672, 1995.CrossRefGoogle Scholar
  6. 6.
    H. Takeuchi, H. Izami, and A. Kawasaki. Decomposition study on TEOS. Mater. Res. Soc. Symp. Proc. 334: 45, 1994Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2009

Authors and Affiliations

  • A. Abdali
    • 1
  • M. Fikri
    • 1
  • H. Wiggers
    • 1
    • 2
  • C. Schulz
    • 1
    • 2
  1. 1.IVGUniversität Duisburg-Essen47057 DuisburgGermany
  2. 2.CeNIDECenter for Nanointegration Duisburg-EssenDuisburgGermany

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