Mineralogie pp 425-450 | Cite as
Phasengleichgewichte und Mineralreaktionen in metamorphen Gesteinen
Zusammenfassung
Wie wir im vorausgehenden Kapitel gezeigt hatten, führt die Gesteinsmetamorphose zu tiefgreifenden Veränderungen im Gefüge und im Mineralbestand von Gesteinen. Durch prograde und retrograde Mineralreaktionen entstehen neue Mineralgesellschaften, die eine schrittweise Anpassung an die sich verändernden P-T-Bedingungen dokumentieren. Dabei kann – zumindest beim Höhepunkt der Metamorphose – ein thermodynamisches Gleichgewicht erreicht oder annähernd erreicht werden, so dass man von Gleichgewichtsparagenesen sprechen kann. Im folgenden Kapitel wollen wir wichtige Mineralreaktionen und die dabei entstehenden Paragenesen näher kennenlernen. Darüber hinaus sollen die Methoden diskutiert werden, mit denen man die Stabilitätsbedingungen metamorpher Paragenesen quantitativ abschätzen kann.
Preview
Unable to display preview. Download preview PDF.
Weiterführende Literatur
- Bucher K, Frey M (2002) Petrogenesis of metamorphic rocks. Springer Berlin Heidelberg New YorkGoogle Scholar
- Ernst WG (1976) Petrologic phase equilibria. Freeman, San FranciscoGoogle Scholar
- Harley SL, Kelly NM (2007) Zircon – tiny but timely. Elements 3: 13–18CrossRefGoogle Scholar
- Harley SL,Melly NM, Möller A (2007) Zircon behaviour and the thermal history of mountain chains. Elements 3:25–30CrossRefGoogle Scholar
- Miyashiro A (1994) Metamorphic petrology. UCL Press, LondonGoogle Scholar
- Powell R, Guiraud M, White RW (2005) Truth and beauty in metamorphic phase equilibria: Conjugate variables and phase diagrams. Canad Mineral 43:21–33CrossRefGoogle Scholar
- Rubatto D, Hermann J (2007) Zircon behaviour in deeply subducted rocks. Elements 3:31–3Google Scholar
- Seifert F (1978) Bedeutung und Nachweis von thermodynamischem Gleichgewicht und die Interpretation von Ungleichgewichten. Fortschr Mineral 55:111–134Google Scholar
- Spear FS (1993) Metamorphic phase equilibria and pressure– temperature–time paths.Mineral Soc America,Washington, DCGoogle Scholar
- Will TM (1998) Phase equilibria in metamorphic rocks – thermodynamic background and petrological applications. Springer, Berlin Heidelberg New YorkGoogle Scholar
- Yardley BWD (1989) An introduction to metamorphic petrology. Longman, Burnt Mill, Harlow, EnglandGoogle Scholar
Zitierte Literatur
- Berman RG (1988) Internally consistent thermodynamic data for minerals in the system Na2O–K2O–CaO–MgO–FeO–Fe2O3– Al2O3–SiO2–TiO2–H2O–CO2. J Petrol 29:445–522Google Scholar
- Bohlen SR, Montana A, Kerrick DM (1991) Precise determinations of equilibria kyanite ⇌ sillimanite and kyanite ⇌ andalusite and a revised triple point for Al2SiO5 polymorphs. Am Mineral 76:677–680Google Scholar
- Chatterjee ND (1970) Synthesis and upper stability of paragonite. Contrib Mineral Petrol 27:244–257CrossRefGoogle Scholar
- Chatterjee ND (1972) The upper stability limit of the assemblage paragonite + quartz and its natural occurrences. Contrib Mineral Petrol 34:288–303CrossRefGoogle Scholar
- Chatterjee ND, Johannes W (1974) Thermal stability and standard thermodynamic properties of synthetic 2 M1-muscovite, K[AlSi3O10(OH)2]. Contrib Mineral Petrol 48:89–114CrossRefGoogle Scholar
- Chernosky JV Jr., Day HW, Caruso LJ (1985) Equilibria in the system MgO–SiO2–H2O: Experimental determination of the stability of Mg-anthophyllite. Am Mineral 70:223–236Google Scholar
- Cho M, Maruyama S, Liou JG (1987) An experimental investigation of heulandite-laumontite equilibrium at 1 000 to 2 000 bar P fluid. Contrib Mineral Petrol 97:43–50CrossRefGoogle Scholar
- England PC, Thompson AB (1984) Pressure–temperature–time paths of regional metamorphism. Part I: Heat transfer during the evolution of regions of thickened continental crust. J Petrol 25:894–928Google Scholar
- Eugster HP (1957) Heterogeneous reactions involving oxidation and reduction at high temperatures. J Chem Phys 26:1760–1761CrossRefGoogle Scholar
- Evans BW, Johannes W, Oterdoom H, Trommsdorff V (1976) Stability of chrysotile and antigorite in the serpentinite multisystem. Schweiz Mineral Petrogr Mitt 56:79–93Google Scholar
- Goldschmidt VM (1911) Die Kontaktmetamorphose im Kristiania-Gebiet. Oslo Vidensk Skr, I Math-Nat K1, no 11Google Scholar
- Greenwood HJ (1961) The system NaAlSi2O6–H2O–argon: Total pressure and water pressure in metamorphism. J Geophys Res 66:3923–3946CrossRefGoogle Scholar
- Greenwood HJ (1967) Mineral equilibria in the system MgO–SiO2– H2O–CO2. In: Abelson PH (ed) Researches in Geochemistry. pp 542–567, Wiley, New YorkGoogle Scholar
- Gruner BB (2000) Metamorphoseentwicklung im Kaokogürtel, NW-Namibia: Phasenpetrologische und geothermobarometrische Untersuchungen panafrikanischer Metapelite. Freiberger Forschungshefte C486:221 ppGoogle Scholar
- Harker RI, Tuttle OF (1956) Experimental data on the P CO2-T curve for the reaction calcite + quartz = wollastonite + carbon dioxide. Am J Sci 254:239–256Google Scholar
- Hemley JJ (1967) Stability relations of pyrophyllite, andalusite, and quartz at elevated pressures and temperatures.Am Geophys Union Trans 48:224Google Scholar
- Holdaway MJ (1971) Stability of andalusite and the aluminum silicate phase diagram. Am J Sci 271:97–131Google Scholar
- Holdaway MJ,Mukhopadhyay B (1993) A reevaluation of the stability relations of andalusite: Thermochemical data and phase diagram for the aluminum silicates. Am Mineral 78:298–315Google Scholar
- Holland TJB,Powell R (1985) An internally consistent thermodynamic dataset with uncertainties and correlations: 2. Data and results. J Metam Geol 3:343–370CrossRefGoogle Scholar
- Holland TJB, Powell R (1990) An enlarged and updated internally consistent thermodynamic dataset with uncertainties and correlations: The system K2O–Na2O–CaO–MgO–MnO–FeO– Fe2O3–Al2O3–TiO2–SiO2–C–H2–O2. J Metam Geol 8:89–124CrossRefGoogle Scholar
- Hsu LC (1968) Selected phase relationships in the system Al–Mn– Fe–Si–O–H: A model for garnet equilibria. J Petrol 9:40–83Google Scholar
- Kennedy GC, Holser WT (1966) Pressure-volume-temperature and phase relations of water and carbon dioxide. Geol Soc America Mem 97:371–384Google Scholar
- Kerrick DM (1968) Experiments on the upper stability limit of pyrophyllite at 1.8 kilobars and 3.9 kilobars water pressure. Am J Sci 266:204–214Google Scholar
- Kerrick DM (1972) Experimental determination of muscovite + quartz stability with P H2O < P total. Am J Sci 272:946–958Google Scholar
- Liou JG (1971) P-T stabilities of laumontite, wairakite, lawsonite and related minerals in the system CaAl2Si2O8–SiO2–H2O. J Petrol 12:379–411Google Scholar
- Massonne HJ, Schreyer W (1987) Phengite geobarometry based on the limiting assemblage with K-feldspar,phlogopite, and quartz. Contrib Mineral Petrol 96:212–224CrossRefGoogle Scholar
- Massonne HJ, Schreyer W (1989) Stability field of the high-pressure assemblage talc + phengite and two new phengite barometers. Eur J Mineral 1:391–410Google Scholar
- Mezger K, Rawnsley CM, Bohlen SR, Hanson GN (1990) U-Pb garnet, sphene, monazite, and rutile ages: Implications for the duration of high-grade metamorphism and cooling histories, Adirondack Mts., New York. J Geol 99: 415–428CrossRefGoogle Scholar
- Miyashiro A (1973) Metamorphism and metamorphic belts. Allen & Unwin, LondonGoogle Scholar
- Ohmoto H,Kerrick D (1977) Devolatilization equilibria in graphite systems. Am J Sci 277:1013–1044Google Scholar
- Okrusch M (1969) Die Gneishornfelse um Steinach in der Oberpfalz. Eine phasenpetrologische Analyse. Contrib Mineral Petrol 22:32–72CrossRefGoogle Scholar
- Schreyer W (1988) Subduction of continental crust to mantle depths: Petrological evidence. Episodes 11:97–104Google Scholar
- Spear FS (1988) The Gibbs method and Duhem’s theorem: The quantitative relationships among P, T, chemical potential, phase composition, and reaction progress in igneous and metamorphic systems. Contrib Mineral Petrol 99:249–256CrossRefGoogle Scholar
- Spear FS, Peacock SM, Kohn MJ, Florence FP,Menard T (1991) Computer programs for petrological P-T-t path calculations. Am Mineral 76:2009–2012Google Scholar
- Storre B (1972) Dry melting of muscovite + quartz in the range P s=7 kb to P s= 20 kb. Contrib Mineral Petrol 37:87–89CrossRefGoogle Scholar
- Storre B, Karotke E (1972) Experimental data on melting reactions of muscovite + quartz in the system K2O–Al2O3–SiO2–H2O to 20 Kb water pressure. Contrib Mineral Petrol 36:343–345CrossRefGoogle Scholar
- Thompson AB (1971) Analcite-albite equilibria at low temperatures. Am J Sci 271:79–92Google Scholar
- Thompson AB (1970) A note on the kaolinite-pyrophyllite equilibrium. Am J Sci 268:454–458Google Scholar
- Winkler HGF (1979) Petrogenesis of metamorphic rocks, 5th edn. Springer, Berlin Heidelberg New YorkGoogle Scholar
- Zeh A, Holness M (2003) The effect of reaction overstep on garnet microstructures in metapelitic rocks of the Ilesha Schist Belt, SW Nigeria. J Petrol 44:967–994CrossRefGoogle Scholar
- Zen E-An (1966) Construction of pressure-temperature diagrams for multicomponent systems after the method of Schreinemakers – A geometric approach. US Geol Survey Bull no 1225, 56 ppGoogle Scholar