Advertisement

Abstract

Water. At least with dilute anions Zn2+ is [Zn(H2O)6]2+, although the ligancy falls from six to four with much HClO4; cf. Br− below in 12.1.3. Zinc nitrate (6 H2O), halides (fluoride excepted), and chlorate are deliquescent; the sulfate (7 H2O) is efflorescent. Zinc basic carbonate, cyanide, oxalate, phosphate, arsenate, sulfide, periodate, hexacyanoferrate(II and III), and hexacyanocobaltate(III) are insoluble in water; the sulfite is sparingly soluble. Pure water (free of air) does not oxidize zinc. Zinc(2+) is hydrolyzed to Zn2(μ-OH)3+, Zn4(OH)4 4+ etc.

Keywords

Mercury Dibromide Cadmium Oxalate Mercury Mercury Mercury Diiodide Zinc Basic Carbonate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Brodersen K, Hummel HU in Wilkinson G, Gillard RD, McCleverty JA (eds) (1987) Comprehensive coordination chemistry, vol 5. Pergamon, Oxford, p 1048.Google Scholar
  2. 2.
    McAuliffe CA (ed) (1977) The chemistry of mercury. Macmillan, LondonGoogle Scholar
  3. 3.
    Aylett BJ (1975) The chemistry of zinc, cadmium and mercury. Pergamon, New YorkGoogle Scholar
  4. 4.
    Farnsworth M, Kline CH (1973) Zinc chemicals. Zinc Institute, New YorkGoogle Scholar
  5. 5.
    Makarova LG, Nesmeyanov AN (eds) (1967) The organic compounds of mercury, methods of elemento-organic chemistry, vol 4. North Holland, AmsterdamGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2007

Personalised recommendations