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Defects induced by electron irradiation in hollandite ceramics, specific radioactive cesium-host wasteforms: a 57Fe Mössbauer study

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ICAME 2005

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Abstract

Several single phase hollandite ceramics having Ba2+ xCs+ y(C = Al,Fe)3+ 2x+y Ti4+ 8−2x−y O16 composition have been synthesized and irradiated under external electron beams simulating the β-irradiation of radioactive cesium. These samples have been characterized by 57Fe transmission Mössbauer spectroscopy. Mössbauer results show that the irradiation modifies the local arrangements of Ba cations around Fe3+ ions by atomic displacement of Ba ions.

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Author information

Authors and Affiliations

  1. CRISMAT (CNRS-UMR 6508), ENSICAEN, 6, bd du Maréchal Juin, F-14050, Caen cedex, France

    N. Nguyen, A. Ducouret & F. Studer

  2. LCAES (CNRS UMR 7574), 11, rue Pierre et Marie Curie, 75231, Paris, France

    V. Aubin, D. Caurant & D. Gourier

  3. CEA/DMN/SRMA, 91191 Gif sur Yvette, Paris, France

    J -M. Costantini

Authors
  1. N. Nguyen
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  2. A. Ducouret
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  3. F. Studer
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  4. V. Aubin
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  5. D. Caurant
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  6. D. Gourier
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  7. J -M. Costantini
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Corresponding author

Correspondence to F. Studer .

Editor information

Editors and Affiliations

  1. Université Montpellier II - CNRS, Montpellier, France

    P. -E. Lippens  & J. -C. Jumas  & 

  2. Université Henri Poincaré-Nancy I, Villers-lès-Nancy, France

    J. -M. R. Génin

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© 2006 Springer Science + Business Media B.V.

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Nguyen, N. et al. (2006). Defects induced by electron irradiation in hollandite ceramics, specific radioactive cesium-host wasteforms: a 57Fe Mössbauer study. In: Lippens, P.E., Jumas, J.C., Génin, J.M.R. (eds) ICAME 2005. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-49850-6_76

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  • DOI: https://doi.org/10.1007/978-3-540-49850-6_76

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-49848-3

  • Online ISBN: 978-3-540-49850-6

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

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