Carbon Nanomaterials for Energy Storage Devices

  • Zhipeng Wang
  • Gan Jet Hong MelvinEmail author


In accordance to the fast technology development and rapid increment in world population, the demand on energy supply is getting stronger and higher. The advancement of nanotechnology has enables new cutting edge materials science and engineering to tackle the challenges. Various types of nanomaterials were fabricated in order to achieve higher performance and efficiency, where conventional or bulk materials meet their limitations, not only in the energy-related fields but numerous fields. In energy storage, particularly supercapacitor applications, carbon nanomaterials such as carbon nanotubes, graphene, and their derivatives have received much attention due to their remarkable structure, morphology, electrical, and mechanical properties that are essential for enhancing energy storage capabilities. This chapter provides introduction of electrochemical capacitors or supercapacitors; introduction of carbon nanomaterials, specifically carbon nanotubes and graphene, which is highly associated with supercapacitor electrode materials; discussion on influence factors that affect energy storage process; reviews on research and development of carbon nanomaterial-based supercapacitors; and future perspectives, opportunities, and challenges.


  1. Abioye AM, Noorden ZA, Ani FN (2017) Synthesis and characterizations of electroless oil palm shell based-activated carbon/nickel oxide nanocomposite electrodes for supercapacitor applications. Electrochim Acta 225:493–502. Scholar
  2. An KH, Kim WS, Park YS, Moon J-M, Bae DJ, Lim SC, Lee YS, Lee YH (2001) Electrochemical properties of high-power supercapacitors using single-walled carbon nanotube electrodes. Adv Funct Mater 11(5):387–392. Scholar
  3. Barbieri O, Hahn M, Herzog A, Kotz R (2005) Capacitance limits of high surface area activated carbons for double layer capacitors. Carbon 43:1303–1310. Scholar
  4. Bavio MA, Acosta GG, Kessler T (2014) Synthesis and characterization of polyaniline and polyaniline-carbon nanotubes nanostructures for electrochemical supercapacitors. J Power Sources 245:475–481. Scholar
  5. Becker H I (1957) Low voltage electrolytic capacitor. US Patent 2800616Google Scholar
  6. Bichat MP, Raymundo-Piñero E, Béguin F (2010) High voltage supercapacitor built with seaweed carbons in neutral aqueous electrolyte. Carbon 48(15):4351–4361. Scholar
  7. Boos D L (1970) Electrolytic capacitor having carbon paste electrodes. US Patent 3536963Google Scholar
  8. Borenstein A, Hanna O, Attias R, Luski S, Brousse T, Aurbach D (2017) Carbon-based composite materials for supercapacitor electrode: a review. J Mater Chem A 5(25):12653–12672. Scholar
  9. Cai M, Outlaw RA, Quinlan RA, Premathilake D, Butler SM, Miller JR (2014) Fast response, vertically oriented graphene nanosheet electric double layer capacitors synthesized from C2H2. ACS Nano 8(6):5873–5882. Scholar
  10. Chang H-H, Chang C-K, Tsai Y-C, Liao C-S (2012) Electrochemically synthesized graphene/polypyrrole composites and their use in supercapacitor. Carbon 50(6):2331–2336. Scholar
  11. Chen T, Dai L (2013) Carbon nanomaterials for high-performance supercapacitors. Mater Today 16(7-8):272–280. Scholar
  12. Chen X, Chen X, Xu X, Yang Z, Liu Z, Zhang L, Xu X, Chen Y, Huang S (2014) Sulfur-doped porous reduced graphene oxide hollow nanosphere frameworks as metal-free electrocatalysts for oxygen reduction reaction and as supercapacitor electrode materials. Nanoscale 6(22):13740–13747. Scholar
  13. Cheng Q, Tang J, Ma J, Zhang H, Shinya N, Qin L-C (2011) Graphene and nanostructured MnO2 composite electrodes for supercapacitors. Carbon 49(9):2917–2925. Scholar
  14. Chmiola J, Yushin G, Dash R, Gogotsi Y (2006a) Effect of pore size and surface area of carbide derived carbons on specific capacitance. J Power Sources 158(1):765–772. Scholar
  15. Chmiola J, Yushin G, Gogotsi Y, Portet C, Simon P, Taberna PL (2006b) Anomalous increase in carbon capacitance at pore sizes less than l nanometer. Science 313(5794):1760–1763. Scholar
  16. Conway BE (1999) Electrochemical supercapacitors: scientific fundamentals and technological applications. Kluwer Academic/Plenum Publishers, New York, NYCrossRefGoogle Scholar
  17. Dai L, Chang DW, Baek J-B, Lu W (2012) Carbon nanomaterials for advanced energy conversion and storage. Small 8(8):1130–1166. Scholar
  18. Dinh TM, Achour A, Vizireanu S, Dinescu G, Nistor L, Armstrong K, Guay D, Pech D (2014) Hydrous RuO2/carbon nanowalls hierarchical structures for all-solid-state ultrahigh-energy-density micro-supercapacitors. Nano Energy 10:288–294. Scholar
  19. Dong Y, Wu Z-S, Ren W, Cheng HM, Bao X (2017) Graphene: a promising 2D material for electrochemical energy storage. Sci Bull 62(10):724–740. Scholar
  20. Dulyaseree P, Yordsri V, Wongwiriyapan W (2016) Effects of microwave and oxygen plasma treatments on capacitive characteristics of supercapacitor based on multiwealled carbon nanoutbes. Jpn J Appl Phys 55:02BD05. Scholar
  21. El-Kady MF, Strong V, Dubin S, Kaner RB (2012) Laser scribing of high-performance and flexible graphene-based electrochemical capacitors. Science 335(6074):1326–1330. Scholar
  22. Fauvarque JF, Simon P (2010) Principles of electrochemistry and electrochemical methods. In: Béguin F, Frackowiak E (eds) Carbons for electrochemical energy storage and conversion systems. CRC Press, Boca Raton, pp 1–36Google Scholar
  23. Frackowiak E, Béguin F (2001) Carbon materials for the electrochemical storage of energy in capacitors. Carbon 39(6):937–950. Scholar
  24. Frackowiak E, Metenier K, Bertagna V, Beguin F (2000) Supercapacitor electrodes from multiwalled carbon nanotubes. Appl Phys Lett 77:2421–2423. Scholar
  25. Frackowiak E, Delpeux S, Jurewicz K, Szostak K, Cazorla-Amoros D, Beguin F (2002) Enhanced capacitance of carbon nanotubes through chemical activation. Chem Phys Lett 361(1–2):35–41. Scholar
  26. Futaba DN, Hata K, Yamada T, Hiraoka T, Hayamizu Y, Kakudate Y, Tanaike O, Hatori H, Yumura M, Iijima S (2006) Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes. Nat Mater 5(12):987–994. Scholar
  27. Gu W, Yushin G (2014) Review of nanostructured carbon materials for electrochemical capacitor applications: advantages and limitations of activated carbon, carbide-derived carbon, zeolite-templated carbon, carbon aerogels, carbon nanotubes, onion-like carbon and graphene. WIREs Energy Environ 3(5):424–473. Scholar
  28. Gueon D, Moon JH (2015) Nitrogen-doped carbon nanotube spherical particles for supercapacitor applications: emulsion-assisted compact packing and capacitance enhancement. ACS Appl Mater Interfaces 7(36):20083–20089. Scholar
  29. Han J, Zhang LL, Lee S, Oh J, Lee K-S, Potts JR, Ji J, Zhao X, Ruoff RS, Park S (2012) Generation of B-doped graphene nanoplatelets using a solution process and their supercapcitor applications. ACS Nano 7(1):19–26. Scholar
  30. Han ZJ, Pineda S, Murdock AT, Seo DH, Ostrikov K, Bendavid A (2017) RuO2-coated vertical graphene hybrid electrodes for high-performance solid-state supercapacitors. J Mater Chem A 5(33):17293–17301. Scholar
  31. Hassan S, Suzuki M, Mori S, El-Moneim AA (2014a) MnO2/carbon nanowalls composite electrode for supercapacitor applications. J Power Sources 249:21–27. Scholar
  32. Hassan S, Suzuki M, Mori S, El-Moneim AA (2014b) MnO2/carbon nanowall electrode for future energy storage application: effect of carbon nanowall growth period and MnO2 mass loading. RSC Adv 4(39):20479–20488. Scholar
  33. He N, Yildiz O, Pan Q, Zhu J, Zhang X, Bradford PD, Gao W (2017) Pyrolytic-carbon coating in carbon nanotube foams for better performance in supercapacitors. J Power Sources 343:492–501. Scholar
  34. Hierold C, Brand O, Fedder GK, Korvink JG, Tabata O (2008) Carbon nanotube devices: properties, modeling, integration and applications, vol 8. John Wiley & Sons, ChichesterCrossRefGoogle Scholar
  35. Hsu Y-K, Chen Y-C, Lin Y-G, Chen L-C, Chen K-H (2012) High-cell-voltage supercapacitor of carbon nanotube/carbon cloth operating in neutral aqueous solution. J Mater Chem 22(8):3383–3387. Scholar
  36. Hu L, Hecht DS, Gruner G (2010) Carbon nanotube thin films: fabrication, properties, and applications. Chem Rev 110(10):5790–5844. Scholar
  37. Huang Y, Liu Y, Zhao G, Chen JY (2017) Sustainable activated carbon fiber from sawdust by reactivation for high-performance supercapacitors. J Mater Sci 52(1):478–488. Scholar
  38. Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354(6348):56–58. Scholar
  39. Iijima S, Ichihashi T (1993) Single-shell carbon nanotubes of 1-nm diameter. Nature 363(6430):603–605. Scholar
  40. Jeong HM, Lee JW, Shin WH, Choi YJ, Shin HJ, Kang JK, Choi JW (2011) Nitrogen-doped graphene for high-performance ultracapacitors and the importance of nitrogen-doped sites at basal planes. Nano Lett 11(6):2472–2477. Scholar
  41. Jiang Q, Qu MZ, Zhou GM, Zhang BL, Yu ZL (2002) A study of activated carbon nanotubes as electrochemical super capacitors electrode materials. Mater Lett 57(4):988–991. Scholar
  42. Jo EH, Jang HD, Chang H, Kim SK, Choi J-H, Lee CM (2017) 3D network-structured crumpled graphene/carbon nanotube/polyaniline composites for supercapacitors. ChemSusChem 10(10):2210–2217. Scholar
  43. Jurewicz K, Delpeux S, Bertagna V, Beguin F, Frackowiak E (2001) Supercapacitors from nanoubes/polypyrrole composites. Chem Phys Lett 347(1–3):36–40. Scholar
  44. Karthika P, Rajalakshmi N, Dhathathreyan KS (2013) Phosphorus-doped exfoliated graphene for supercapacitor electrodes. J Nanosci Nanotechnol 13(3):1746–1751. Scholar
  45. Ke Q, Wang J (2016) Graphene-based materials for supercapacitor electrodes—a review. J Mater 2(1):37–54. Scholar
  46. Kim YJ, Yang C-M, Park KC, Kaneko K, Kim YA, Noguchi M, Fujino T, Oyama S, Endo M (2012) Edge-enriched, porous carbon-based, high energy density supercapacitors for hybrid electric vehicles. ChemSusChem 5(3):535–541. Scholar
  47. Kim T, Jung G, Yoo S, Suh KS, Ruoff RS (2013) Activated graphene-based carbons as supercapacitor electrodes with macro- and mesopores. ACS Nano 7(8):6899–6905. Scholar
  48. Kroto HW, Heath JR, O’Brien SC, Curl RF, Smalley RE (1985) C60: Buckminsterfullerene. Nature 318(6042):162–163. Scholar
  49. Largeot C, Portet C, Chmiola J, Taberna P-L, Gogotsi Y, Simon P (2008) Relation between the ion size and pore size for an electric double-layer capacitor. J Am Chem Soc 130(9):2730–2731. Scholar
  50. Li H, Wang J, Chu Q, Wang Z, Zhang F, Wang S (2009) Theoretical and experimental specific capacitance of polyaniline in sulfuric acid. J Power Sources 190(2):578–586. Scholar
  51. Li P, Shi E, Yang Y, Shang Y, Peng Q, Wu S, Wei J, Wang K, Zhu H, Yuan Q (2014) Carbon nanotube-polypyrrole core-shell sponge and its application as highly compressible supercapacitor electrode. Nano Res 7(2):209–218. Scholar
  52. Lin T, Chen I-W, Liu F, Yang C, Bi H, Xu F, Huang F (2015) Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage. Science 350(6267):1508–1513. Scholar
  53. Lu W, Qu L, Henry K, Dai L (2009) High performance electrochemical capacitors from aligned carbon nanotube electrodes and ionic liquid electrolytes. J Power Sources 189(2):1270–1277. Scholar
  54. Lu Y, Zhang S, Yin J, Bai C, Zhang J, Li Y, Yang Y, Ge Z, Zhang M, Wei L, Ma M, Ma Y, Chen Y (2017) Mesoporous activated carbon materials with ultrahigh mesopore volume and effective specific surface area for high performance supercapacitors. Carbon 124:64–71. Scholar
  55. Lv W, Li Z, Deng Y, Yang Q-H, Kang F (2016) Graphene-based materials for electrochemical energy storage devices: opportunities and challenges. Energy Storage Mater 2:107–138. Scholar
  56. Ma R, Wei B, Xu C, Liang J, Wu D (2000) The development of carbon nanotubes/ RuO2·xH2O electrodes for electrochemical capacitors. Bull Chem Soc Jpn 73(8):1813–1816. Scholar
  57. Melvin GJH, Wang Z, Siambun NJ, Rahman MM (2017a) Carbon materials derived from rice husks at low and high temperatures. IOP Conf Ser Mater Sci Eng 217:012017. Scholar
  58. Melvin GJH, Wang Z, Ni QQ, Siambun NJ, Rahman MM (2017b) Fabrication and characterization of carbonized rice husk/barium titanate nanocomposites. IOP Conf Ser Mater Sci Eng 229:012024. Scholar
  59. Miller JR, Outlaw RA, Holloway BC (2010) Graphene double-layer capacitor with ac-line filtering performance. Science 329(5999):1637–1639. Scholar
  60. Muramatsu H, Kim YA, Yang K-S, Cruz-Silva R, Toda I, Yamada T, Terrones M, Endo M, Hayashi T, Saitoh H (2014) Rice husk-derived graphene with nano-sized domains and clean edges. Small 10(14):2766–2770. Scholar
  61. Niu C, Sichel EK, Hoch R, Moy D, Tennent H (1997) High power electrochemical capacitors based on carbon nanotube electrodes. Appl Phys Lett 70:1480–1482. Scholar
  62. Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA (2004) Electric field effect in atomically thin carbon films. Science 306(5696):666–669. Scholar
  63. Oberlin A, Endo M, Koyama T (1976) Filamentous growth of carbon through benzene decomposition. J Cryst Growth 32(3):335–349. Scholar
  64. Paul S, Lee Y-S, Choi J-A, Kang Y-C, Kim D-W (2010) Synthesis and electrochemical characterization of polypyrrole/multiwalled carbon nanotube composite electrodes for supercapacitor applications. Bull Kor Chem Soc 31(5):1228–1232. Scholar
  65. Popov VN (2004) Carbon nanotubes: properties and application. Mater Sci Eng R 43(3):61–102. Scholar
  66. Pumera M (2010) Graphene-based nanomaterials and their electrochemistry. Chem Soc Rev 39(11):4146–4157. Scholar
  67. Pumera M (2011) Graphene-based nanomaterials for energy storage. Energy Environ Sci 4(3):668–674. Scholar
  68. Raymundo-Piñero E, Leroux F, Béguin F (2006) A high-performance carbon for supercapacitors obtained by carbonization of a seaweed biopolymer. Adv Mater 18(14):1877–1882. Scholar
  69. Rightmire R A (1966) Electrical energy storage apparatus. US Patent 3288641Google Scholar
  70. Segalini J, Iwama E, Taberna P-L, Gogotsi Y, Simon P (2012) Steric effects in adsorption of ions from mixed electrolytes into microporous carbon. Electrochem Commun 15(1):63–65. Scholar
  71. Sharma P, Bhatti TS (2010) A review on electrochemical double-layer capacitors. Energy Convers Manag 51(12):2901–2912. Scholar
  72. Simon P, Gogotsi Y (2008) Materials for electrochemical capacitors. Nat Mater 7(11):845–854. Scholar
  73. Simon P, Gogotsi Y (2013) Capacitive energy storage in nanostructured carbon-electrolyte systems. Acc Chem Res 46(5):1094–1103. Scholar
  74. Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8(10):3498–3502. Scholar
  75. Tanahashi I, Yoshida A, Nishino A (1990) Electrochemical characterization of activated carbon-fiber cloth polarizable electrodes for electric double-layer capacitors. J Electrochem Soc 137(10):3052–3057. Scholar
  76. Thostenson ET, Ren Z, Chou T-W (2001) Advances in the science and technology of carbon nanotubes and their composites: a review. Compos Sci Technol 61(13):1899–1912. Scholar
  77. Toupin M, Brousse T, Bélanger D (2004) Charge storage mechanism of MnO2 electrode used in aqueous electrochemical capacitor. Chem Mater 16(16):3184–3190. Scholar
  78. Vix-Guterl C, Frackowiak E, Jurewicz K, Friebe M, Parmentier J, Béguin F (2005) Electrochemical energy storage in ordered porous carbon materials. Carbon 43(6):1293–1302. Scholar
  79. Wallar C, Luo D, Poon R, Zhitomirsky I (2017) Manganese dioxide-carbon nanotube composite electrodes with high active mass loading for electrochemical supercapacitors. J Mater Sci 52(7):3687–3696. Scholar
  80. Wang D-W, Li F, Zhao J, Ren W, Chen Z-G, Tan J, Wu Z-S, Gentle L, Lu GQ, Cheng H-M (2009) Fabrication of graphene/polyaniline composite paper via in situ anode electropolymerization for high-performance flexible electrode. ACS Nano 3(7):1745–1752. Scholar
  81. Wang X, Liu J, Wang Y, Zhao C, Zheng W (2014a) Ni(OH)2 nanoflakes electrodeposited on Ni foam-supported vertically oriented graphene nanosheets for applications in asymmetric supercapacitors. Mater Res Bull 52:89–95. Scholar
  82. Wang X, Sun G, Routh P, Kim D-H, Huang W, Chen P (2014b) Heteroatom-doped graphene materials: syntheses, properties and applications. Chem Soc Rev 43(20):7067–7098. Scholar
  83. Wang Z, Ogata H, Morimoto S, Ortiz-Medina J, Fujishige M, Takeuchi K, Muramatsu H, Hayashi T, Terrones M, Hashimoto Y, Endo M (2015) Nanocarbons from rice husk by microwave plasma irradiation: from graphene and carbon nanotubes to graphenated carbon nanotube hybrids. Carbon 94:479–484. Scholar
  84. Weinstein L, Dash R (2013) Supercapacitor carbons. Mater Today 10(16):356–357. Scholar
  85. Xiong G, Hembram KPSS, Reifenberger RG, Fisher TS (2013) MnO2-coated graphitic petals for supercapacitor electrodes. J Power Sources 227:254–259. Scholar
  86. Xu G, Ding B, Nie P, Shen L, Wang J, Zhang X (2013) Porous nitrogen-doped carbon nanotubes derived from tubular polypyrrole for energy-storage applications. Chem Eur J 19(37):12306–12312. Scholar
  87. Xu R, Wei J, Guo F, Cui X, Zhang T, Zhu H, Wang K, Wu D (2015) Highly conductive, twistable and bendable polypyrrole-carbon nanotube fiber for efficient supercapacitor electrodes. RSC Adv 2015(28):22015–22021. Scholar
  88. Yan J, Fan Z, Wei T, Cheng J, Shao B, Wang K, Song L, Zhang M (2009a) Carbon nanotube/MnO2 composites synthesized by microwave-assisted method for supercapacitors with high power and energy densities. J Power Sources 194(2):1202–1207. Scholar
  89. Yan S, Wang H, Qu P, Zhang Y, Xiao Z (2009b) RuO2/carbon nanotubes composites synthesized by microwave-assisted method for electrochemical supercapacitor. Synth Met 159(1-2):158–161. Scholar
  90. Yan J, Fan Z, Wei T, Qian W, Zhang M, Wei F (2010) Fast and reversible surface redox reaction of graphene-MnO2 composites as supercapacitor electrodes. Carbon 48(13):3825–3833. Scholar
  91. Yang Z, Zhang J, Kintner-Meyer MCW, Lu X, Choi D, Lemmon JP, Liu J (2011) Electrochemical energy storage for green grid. Chem Rev 111(5):3577–3613. Scholar
  92. Yang Z, Ren J, Zhang Z, Chen X, Guan G, Qiu L, Zhang Y, Peng H (2015) Recent advancement of nanostructured carbon for energy applications. Chem Rev 115(11):5159–5223. Scholar
  93. Yen H-F, Horng Y-Y, Hu M-S, Yang W-H, Wen J-R, Ganguly A, Tai Y, Chen K-H, Chen L-C (2015) Vertically aligned epitaxial graphene nanowalls with dominated nitrogen doping for superior supercapcitors. Carbon 82:124–134. Scholar
  94. Yoon B-J, Jeong S-H, Lee K-H, Kim HS, Park CG, Han JH (2004) Electrical properties of electrical double layer capacitors with integrated carbon nanotube electrodes. Chem Phys Lett 388(1–3):170–174. Scholar
  95. Young RJ, Lovell PA (2011) Introduction to polymers. CRC Press, Boca RatonCrossRefGoogle Scholar
  96. Yu A, Chabot V, Zhang J (2013) Electrochemical supercapacitors for energy storage and delivery: fundamentals and applications. CRC Press, Boca RatonGoogle Scholar
  97. Zhai Y, Dou Y, Zhao D, Fulvio PF, Mayes RT, Dai S (2011) Carbon materials for chemical capacitive energy storage. Adv Mater 23(42):4828–4850. Scholar
  98. Zhang K, Zhang LL, Zhao XS, Wu J (2010) Graphene/polyaniline nanofiber composites as supercapacitor electrodes. Chem Mater 22(4):1392–1401. Scholar
  99. Zhang K, Mao L, Zhang LL, On Chan HS, Zhao XS, Wu J (2011) Surfactant-intercalated, chemically reduced graphene oxide for high performance supercapacitor electrodes. J Mater Chem 21(20):7302–7307. Scholar
  100. Zhao X, Tian H, Zhu M, Tian K, Wang JJ, Kang F, Outlaw RA (2009) Carbon nanosheets as the electrode material in supercapacitors. J Power Sources 194(2):1208–1212. Scholar
  101. Zhong C, Deng Y, Hu W, Qiao J, Zhang L, Zhang J (2015) A review of electrolyte materials and compositions for electrochemical supercapacitors. Chem Soc Rev 44(21):7484–7539. Scholar
  102. Zhu Y, Murali S, Stoller MD, Ganesh KJ, Cai W, Ferreira PJ, Pirkle A, Wallace RM, Cychosz KA, Thommes M, Su D, Stach EA, Ruoff RS (2011) Carbon-based supercapacitors produced by activation of graphene. Science 332(6037):1537–1541. Scholar

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© Springer Nature Switzerland AG 2019

Authors and Affiliations

  1. 1.Institute of Advanced MaterialsJiangxi Normal UniversityNanchangChina
  2. 2.Material and Mineral Research Unit (MMRU), Faculty of EngineeringUniversiti Malaysia SabahKota KinabaluMalaysia

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