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Chemical Reduction and Oxidation of Organic Contaminants by Nanoscale Zerovalent Iron

  • Tanapon Phenrat
  • Thi Song Thao Le
  • Bhanuphong Naknakorn
  • Gregory V. Lowry
Chapter

Abstract

This chapter critically reviews the kinetics of NZVI used to reductively and oxidatively transform various kinds of priority organic contaminants including chlorinated ethenes, chlorinated ethanes, chlorinated and aromatic nitro hydrocarbons, chlorinated biphenyls, halogenated bisphenol A, explosives, dyes, and pesticides. All kinds of NZVI, including bare, bimetallic, polymer-modified, and supported NZVI, are reviewed. A total of 102 datasets of laboratory-scale experiments over 20 years (1997–2017) of NZVI research are evaluated to extract state-of-the-art understanding. This chapter elaborates not only reductive transformation pathways of priority organic contaminants but also two factors governing NZVI reactivity: intrinsic properties of the materials and environmental conditions where NZVI particles are applied. These include the particle crystallinity and chemical composition (noble metal), the effect of polymeric surface modification, and the effects of sorptive support, aging effects, pH, anionic and cationic solutes, natural organic matter, aquifer material, contaminant concentration, and the presence of dense nonaqueous phase liquid. Similarly, various factors affecting oxidative degradation of contaminants of concern using NZVI-induced Fenton’s reaction are reviewed.

Keywords

Nanoscale zerovalent iron Reductive dechlorination Fenton reaction Chlorinated organics Degradation kinetics Degradation mechanisms 

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Copyright information

© Springer International Publishing AG, part of Springer Nature 2019

Authors and Affiliations

  • Tanapon Phenrat
    • 1
    • 2
  • Thi Song Thao Le
    • 1
    • 2
  • Bhanuphong Naknakorn
    • 3
    • 4
  • Gregory V. Lowry
    • 4
    • 5
  1. 1.Department of Civil Engineering, Environmental Engineering ProgramNaresuan UniversityPhitsanulokThailand
  2. 2.Center of Excellence for Sustainability of Health, Environment and Industry (SHEI), Faculty of EngineeringNaresuan UniversityPhitsanulokThailand
  3. 3.Thai Plastic and Chemicals PCLBangkokThailand
  4. 4.Center for Environmental Implications of Nanotechnology (CEINT)Carnegie Mellon UniversityPittsburghUSA
  5. 5.Department of Civil & Environmental EngineeringCarnegie Mellon UniversityPittsburghUSA

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