Advertisement

Discrete Molecular Dynamics and NMR Line Shape Effects. General Exchange

  • Sławomir SzymańskiEmail author
  • Piotr Bernatowicz
Chapter

Abstract

The theory of NMR line shapes for systems of coupled nuclei undergoing any type of exchange is exposed, with the focus on the intermolecular processes. The issue of molecular symmetry in intermolecular exchange is addressed. The formalism is illustrated by a number of simple examples, where explicit forms of the exchange superoperators are presented.

References

  1. 1.
    J.I. Kaplan, G. Fraenkel, J. Am. Chem. Soc. 94, 2907 (1972)CrossRefGoogle Scholar
  2. 2.
    J.I. Kaplan, J. Chem. Phys. 29, 462 (1958)Google Scholar
  3. 3.
    G. Binsch, J. Am. Chem. Soc. 91, 1304 (1969)CrossRefGoogle Scholar
  4. 4.
    S. Szymański, Mol. Phys. 60, 897 (1987)Google Scholar
  5. 5.
    L.T. Kuhn (ed.), in Hyperpolarization methods in NMR Spectroscopy (Springer, Heidelberg, 2013)Google Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Institute of Organic ChemistryPolish Academy of SciencesWarsawPoland
  2. 2.Institute of Physical ChemistryPolish Academy of SciencesWarsawPoland

Personalised recommendations