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Characterization of Pigments in Wall Paintings of Macedonian Tombs Using Noninvasive and Nondestructive Techniques

  • Alexandros Konstanta
  • Georgia Theofanidou
  • Vasileios Tsinaridis
  • Ioannis Karapanagiotis
Chapter

Abstract

The goal of the study is the identification of pigments and other materials contained in wall paintings of three Macedonian tombs which date back to the fourth to third century BC: the tomb I of Dion, the tomb IV of Dion, and the tomb A (Heuzey). The investigation is carried out in two phases. First, portable X-ray fluorescence (XRF) spectroscopy is used for in situ measurements. In the second phase, 12 microsamples which were removed from damaged areas of the wall paintings are investigated using optical microscopy, micro-Raman, and micro-FTIR spectroscopy.

The following pigments are identified: red ochre, yellow ochre, Egyptian blue, and carbon black. Moreover, the dominant presence of calcite is revealed, while gypsum is identified in the preparation layers of only two samples. Finally, an organic material (probably egg yolk) is detected in three samples by FTIR. Based on these findings, an interpretation of the possible (fresco/secco) painting technique(s) which could have been applied in the Macedonian paintings is provided, in light of previously published reports.

Keywords

Painting Macedonian Ochre Egyptian blue Carbon black Egg XRF Raman FTIR 

Notes

Acknowledgment

The authors would like to thank the Ephorate of Antiquities of Pieria and the Ministry of Culture of Greece for providing the permission to study the mural paintings and the corresponding samples.

References

  1. 1.
    Lampakis D, Karapanagiotis I, Katsibiri O (2017) Spectroscopic investigation leading to the documentation of three post-byzantine wall paintings. Appl Spectrosc 7:129–140CrossRefGoogle Scholar
  2. 2.
    Brecoulaki H (2006) La peinture funeraire de Macedoine. Emplois et fonctions de la couleur IVe–IIe s. av. J.-C. Athens, National Hellenic Research FoundationGoogle Scholar
  3. 3.
    Andreotti A, Carmignani A, Colombini MP, Modugno F (2006) Characterization of paint organic materials in wall decorations of Macedonian tombs. In: La peinture funeraire de Macedoine. Emplois et fonctions de la couleur IVe–IIe s. av. J.-C., Appendix IV, H. National Hellenic Research Foundation, Brecoulaki, AthensGoogle Scholar
  4. 4.
    Karydas AG (2006) In situ XRF analyses of wall-painting pigments on ancient funeral Macedonian monuments. In: La peinture funeraire de Macedoine. Emplois et fonctions de la couleur IVe–IIe s. av. J.-C., Appendix II, H. National Hellenic Research Foundation, Brecoulaki, AthensGoogle Scholar
  5. 5.
    Brecoulaki H, Fiorin E, Vigato PA (2006) The funerary klinai of tomb 1 from Amphipolis and a sarcophagus from ancient Tragilos, eastern Macedonia: a physico-chemical investigation on the painting materials. J Cult Herit 7:301–311CrossRefGoogle Scholar
  6. 6.
    Kakamanoudis A (2012) Painting techniques in ancient Greece, Ms Thesis. Aristotle University of Thessaloniki, Thessaloniki. [Α. Κακαμανούδης, Τεχνικές ζωγραφικής στην αρχαία Ελλάδα, Μεταπτυχιακή Εργασία, ΑΠΘ, 2012]Google Scholar
  7. 7.
    Kasprzyk A (1994) Distribution of strontium in the Badenian (middle Miocene) gypsum deposits of the Nida area, southern Poland. Geological Q 38:497–512Google Scholar
  8. 8.
    Aloupi E, Karydas AG, Paradellis T (2000) Pigment analysis of wall paintings and ceramics from Greece and Cyprus. X-Ray Spectrom 29:18–24CrossRefGoogle Scholar
  9. 9.
    Playa E, Rosell L (2005) The celestite problem in gypsum Sr geochemistry: an evaluation of purifying methods of gypsiferous samples. Chem Geol 221:102–116CrossRefGoogle Scholar
  10. 10.
    Franceschi E, Locardi F (2013) Strontium, a new marker of the origin of gypsum in cultural heritage? J Cult Herit 15:522–527CrossRefGoogle Scholar
  11. 11.
    Bell IM, Clark RJH, Gibbs PJ (1997) Raman spectroscopic library of natural and synthetic pigments (pre- 1850 AD). Spectrochim Acta A 53:2159–2179CrossRefGoogle Scholar
  12. 12.
    Kustova GN, Burgina EB, Sadykov VA, Poryvaev SG (1992) Vibrational spectroscopic investigation of the goethite thermal decomposition products. Phys Chem Miner 18:379–382CrossRefGoogle Scholar
  13. 13.
    de Faria DLA, Venâncio Silva S, de Oliveira MT (1997) Raman Microspectroscopy of some Iron oxides and Oxyhydroxides. J Raman Spectrosc 28:873–878CrossRefGoogle Scholar
  14. 14.
    Tuinstra F, Koenig JL (1970) Raman spectrum of graphite. J Chem Phys 53:1126–1130CrossRefGoogle Scholar
  15. 15.
    Nakamizo M, Kammereck R, Walker PL Jr (1974) Laser Raman studies on carbons. Carbon 12:259–267CrossRefGoogle Scholar
  16. 16.
    Hatton GH, Shortland AJ, Tite MS (2008) The production technology of Egyptian blue and green frits from second millennium BC Egypt and Mesopotamia. J Archaeol Sci 35:1591–1604CrossRefGoogle Scholar
  17. 17.
    Jaksch H, Seipel W, Weiner KL, El Goresy A (1983) Egyptian blue - cuprorivaite a window to ancient Egyptian technology. Naturwissenschaften 70:525–535CrossRefGoogle Scholar
  18. 18.
    Franquelo ML, Duran A, Herrera LK, Jimenez de Haro MC, Perezrodriguez JL (2009) Comparison between micro-Raman and micro-FTIR spectroscopy techniques for the characterization of pigments from southern Spain cultural heritage. J Mol Struct 924–926:404–412CrossRefGoogle Scholar
  19. 19.
    Gunasekaran S, Anbalagan G, Pandi S (2006) Raman and infrared spectra of carbonates of calcite structure. J Raman Spectrosc 37:892–899CrossRefGoogle Scholar
  20. 20.
    Baraldi P, Bonazzi A, Gioedani N, Paccagnella F, Zannini P (2006) Analytical characterization of roman plasters of the ‘Domus Farini’ in Modena. Archaeometry 48:481–499CrossRefGoogle Scholar
  21. 21.
    Prinsloo LC, Tournié A, Colomban P, Paris C, Bassett ST (2013) In search of the optimum Raman/IR signatures of potential ingredients used in san/bushman rock art paint. J Archaeol Sci 40:2981–2990CrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • Alexandros Konstanta
    • 1
  • Georgia Theofanidou
    • 2
  • Vasileios Tsinaridis
    • 1
  • Ioannis Karapanagiotis
    • 1
  1. 1.Department of Management and Conservation of Ecclesiastical Cultural Heritage ObjectsUniversity Ecclesiastical Academy of ThessalonikiThessalonikiGreece
  2. 2.Faculty of Engineering, Interdisciplinary Ms Program in Preservation and Restoration of Mechanisms and Works of ArtAristotle University of ThessalonikiThessalonikiGreece

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