Some Physical Properties of Tellurite Glasses

  • Raouf El-Mallawany


The present chapter summarizes some physical properties of tellurite glasses when modified with transition metal oxides (TMO) and with rare-earth oxides (REO). The physical properties were thermal, optical, electrical, and mechanical. Also, some recent applications of tellurite glasses have been collected.


  1. 1.
    J.E. Stanworth, Tellurite glasses. Nature 169, 581–582 (1952)ADSCrossRefGoogle Scholar
  2. 2.
    A. Yakhkind, Tellurite Glasses. J. Am. Ceramic Soc. 49, 670–675 (1966). CrossRefGoogle Scholar
  3. 3.
    B. Flynn, A. Owen and J. Robertson, Proc. of the “7-th inter. conf. on amorphous and liquid semi”, UK, 678 (1977)Google Scholar
  4. 4.
    E.F. Lambson, G.A. Saunders, B. Bridge, R.A. El-Mallawany, The elastic behaviour of TeO2 glass under uniaxial and hydrostatic pressure. J. Non-Cryst. Solids 69(1), 117–133 (1984)ADSCrossRefGoogle Scholar
  5. 5.
    R.El-Mallawany, The optical properties of tellurite glasses. J. Appl. Phys. 72(5), 1774–1777 (1992)ADSCrossRefGoogle Scholar
  6. 6.
    G. Ghosh, Sellmeier coefficients and chromatic dispersions for some Tellurite glasses. 78, 2828–2830 (1995).
  7. 7.
    M.N. Azlan, M.K. Halimah, R. El-Mallawany, M.F. Faznny, C. Eevon, Optical properties of zinc borotellurite glass system doped with erbium and erbium nanoparticles for photonic applications. J. Mater. Sci. Mater. Electron. 28, 4318–4327 (2017). CrossRefGoogle Scholar
  8. 8.
    R. El-Mallawany, M.S. Gaafar, Y.A. Azzam, Prediction of ultrasonic parameters at low temperatures for tellurite glasses using ANN. Chalcogenide Lett. 11(5), 227–232 (2014)Google Scholar
  9. 9.
    R. El-Mallawany, H.M. Diab, Effect of pre-readout annealing treatments on TL mechanism in tellurite glasses at therapeutic radiation doses level. Measurement 46, 1722–1725 (2013)CrossRefGoogle Scholar
  10. 10.
    R. El-Mallawany, M.I. Sayyed, M.G. Dong, Comparative shielding properties of some Tellurite glasses: Part 2. J. Non-Crystalline Solids 474, 16–23 (2017)ADSCrossRefGoogle Scholar
  11. 11.
    F. Yang, C. Liu, D. Wei, Y. Chen, L. Jingxiao, S.-e. Yang, Er3+ –Yb3+ co-doped TeO2–PbF2 oxyhalide tellurite glasses for amorphous silicon solar cells. Opt. Mater. 36, 1040–1043 (2014)ADSCrossRefGoogle Scholar
  12. 12.
    R. El-Mallawany, Tellurite Glasses Handbook: Physical Properties and Data, CRC Press, USA, 1st (2002), ISBN: 0849303680 9780849303685, 540 Page, (, engineering /Chemical,T)
  13. 13.
    R. El-Mallawany, Tellurite Glasses Handbook: Physical Properties and Data (CRC Press, USA) 2nd ed, (2011), ISBN: 9781439849835 1439849838 9781439849842 1439849846, 532 Pages,
  14. 14.
    R. El-Mallawany, Introduction to Tellurite glasses, springer series in materials science, “Technological Advances in Tellurite Glasses: Properties, Processing and Applications”, Edit by V.A.G. Revera and D. Manzani, 254. (2017) 1–13.,
  15. 15.
    R.El-Mallawany, An introduction to Telluirte Glasses, (2005), 5 Video taped lectures provided as an educational resource for the entire international glass community available in video streaming format on IMI website;,
  16. 16.
    M.M. El-Zaidia, A.A. Ammar, R.A. El-Mallwany, Infra-red spectra, electron spin resonance spectra, and density of (TeO2) 100− x–(WO3) x and (TeO2) 100− x–(ZnCl2) x glasses. Phys. Status Solidi A 91(2), 637–642 (1985)ADSCrossRefGoogle Scholar
  17. 17.
    A. Abdel-Kader, R. El-Mallawany, M.M. Elkholy, Network structure of tellurite phosphate glasses: Optical absorption and infrared spectra. J. Appl. Phys. 73(1), 71–74 (1993)ADSCrossRefGoogle Scholar
  18. 18.
    I.Z. Hager, R. El-Mallawany, A. Bulou, Luminescence spectra and optical properties of TeO 2–WO 3–Li 2 O glasses doped with Nd, Sm and Er rare earth ions. Physica B: Condensed Matter 406 (4), 972–980 (2011) 406(4), 1844 (2011)CrossRefGoogle Scholar
  19. 19.
    I.Z. Hager, R. El-Mallawany, Preparation and structural studies in the (70− x) TeO2–20WO3–10Li2O–xLn2O3 glasses. J. Mater. Sci. 45(4), 897 (2010)ADSCrossRefGoogle Scholar
  20. 20.
    N.S. Hussain, G. Hungerford, R. El-Mallawany, M.J.M. Gomes, M.A. Lopes, N. Ali, J.D. Santos, S. Buddhudu, Absorption and emission analysis of RE3+ (Sm3+ and Dy3+): Lithium Boro Tellurite glasses. J. Nanosci. Nanotechnol. 9(6), 3672–3677 (2009)CrossRefGoogle Scholar
  21. 21.
    R. El-Mallawany, M. Sidkey, A. Khafagy, H. Afifi, Ultrasonic attenuation of tellurite glasses. Mater. Chem. Phys. 37(2), 197–200 (1994)CrossRefGoogle Scholar
  22. 22.
    M.M. Elkholy, R.A. El-Mallawany, Ac conductivity of tellurite glasses. Mater. Chem. Phys. 40(3), 163–167 (1995)CrossRefGoogle Scholar
  23. 23.
    A. El-Adawy, R. El-Mallawany, Elastic modulus of tellurite glasses. J. Mater. Sci. Lett. 15(23), 2065–2067 (1996)Google Scholar
  24. 24.
    H.M.M. Moawad, H. Jain, R. El-Mallawany, T. Ramadan, M. El-Sharbiny, Electrical conductivity of silver vanadium tellurite glasses. J. Am. Ceram. Soc. 85(11), 2655–2659 (2002)CrossRefGoogle Scholar
  25. 25.
    R. El-Mallawany, Specific heat capacity of semiconducting glasses: Binary vanadium tellurite. Phys. Status Solidi A 177(2), 439–444 (2000)ADSCrossRefGoogle Scholar
  26. 26.
    R. El-Mallawany, A. Abd El-Moneim, Comparison between the elastic moduli of tellurite and phosphate glasses. Phys. Status Solidi A 166(2), 829–834 (1998)ADSCrossRefGoogle Scholar
  27. 27.
    R. El-Mallawany, A.H. El-Sayed, M.M. HA El-Gawad, ESR and electrical conductivity studies of (TeO2) 0.95 (CeO2) 0.05 semiconducting glasses. Mater. Chem. Phys. 41(2), 87–91 (1996)CrossRefGoogle Scholar
  28. 28.
    H.M.M. Moawad, H. Jain, R. El-Mallawany, DC conductivity of silver vanadium tellurite glasses. J. Phys. Chem. Solids 70(1), 224–233 (2009)ADSCrossRefGoogle Scholar
  29. 29.
    R. El-Mallawany, Theoretical analysis of the electrical properties of tellurite glasses. Mater. Chem. Phys. 37(4), 376–381 (1994)CrossRefGoogle Scholar
  30. 30.
    R. El-Mallawany, Phase separation ultrasonic detection of microphase separation in Tellurite glasses. Phys. Stat. Soli. (a) 133, 245 (1992)ADSCrossRefGoogle Scholar
  31. 31.
    A. Mirgorodsky, M. Colas, M. Smirnov, T. Merle-Méjean, R. El-Mallawany, Philippe Thomas, structural peculiarities and Raman spectra of TeO2/WO3-based glasses: A fresh look at the problem. J. Solid State Chem. 190, 45–51 (2012)ADSCrossRefGoogle Scholar
  32. 32.
    R. El-Mallawany, M. Sidkey, A. Khafagy, H. Afifi, Elastic constants of semiconducting tellurite glasses. Mater. Chem. Phys. 37(3), 295–298 (1994)CrossRefGoogle Scholar
  33. 33.
    M. Sidky, R. El-Mallawany, R. Nakhala, A. El-Moneim, Ultrasonic attenuation at low temperature of TeO2-V2O5 glasses. Phys. Stat. Soli. (a) 159, 397 (1997)ADSCrossRefGoogle Scholar
  34. 34.
    R. El-Mallawany, Theoretical analysis of ultrasonic wave attenuation and elastic moduli of Tellurite glasses. Mater. Chem. Phys. 39, 161 (1994)CrossRefGoogle Scholar
  35. 35.
    R. El-Mallawany, H.M. Diab, Improving dosimetric properties of tellurite glasses. Phys. B Condens. Matter 407(17), 3580–3585 (2012)ADSCrossRefGoogle Scholar
  36. 36.
    M.A. Merzliakov, V.V. Kouhar, G.E. Malashkevich, E.V. Pestryakov, Spectroscopy of Yb-doped tungsten-tellurite glass and assessment of its lasing properties. Opt. Mater. 75, 142–149 (2018)ADSCrossRefGoogle Scholar
  37. 37.
    R. El-Mallawany, M.S. Gaafar, M.A.M. Abdeen, S.Y. Marzouk, Simulation of acoustic properties of some tellurite glasses. Ceram. Int. 40, 7389–7394 (2014)CrossRefGoogle Scholar
  38. 38.
    M.A. Sidky, R.A. El-Mallawany, A.A. Aboushly, Y.B. Saddeek, Relaxation of longitudinal ultrasonic waves in some tellurite glasses. Mater. Chem. Phys. 74(2), 222–229 (2002)CrossRefGoogle Scholar
  39. 39.
    R. El-Mallawany, Devitrification and Vitrification of Tellurite glasses. J. Mater. Sci. Elect. 6(1) (1995)Google Scholar
  40. 40.
    R.A. El-Mallawany, L.M. Sharaf El-Deen, M.M. Elkholy, Dielectric properties and polarizability of molybdenum tellurite glasses. J. Mater. Sci. 31(23), 6339–6343 (1996)ADSCrossRefGoogle Scholar
  41. 41.
    R. El Allawany, Debye temperature of ternary tellurite glasses at room temperature. Phys. Status Solidi A 130(1), 103–108 (1992)ADSCrossRefGoogle Scholar
  42. 42.
    V. Uma, M. Vijayakumar, K. Marimuthu, G. Muralidharan, Luminescence and energy transfer studies on Sm3+ /Tb3+ codoped telluroborate glasses for WLED applications. J. Mol. Struct. 1151, 266–276 (2018)ADSCrossRefGoogle Scholar
  43. 43.
    D.S. da Silva, N.U. Wetter, W. de Rossi, L.R.P. Kassab, R.E. Samad, Production and characterization of femtosecond laser-written double line waveguides in heavy metal oxide glasses. Opt. Mater. 75, 267–273 (2018)ADSCrossRefGoogle Scholar
  44. 44.
    Y. Sun, Q. Yang, H. Wang, Y. Shao, Sensitization of Ho3+ on the 2.7 μm emission of Er3+ in (Y0.9La0.1)2O3transparent ceramics. J. Lumin. 194, 50–55 (2018)CrossRefGoogle Scholar
  45. 45.
    R. El-Mallawany, H.A. Afifi, M. El-Gazery, A.A. Ali, Effect of Bi2O3 addition on the ultrasonic properties of pentaternary borate glasses. Measurement 116, 314–317 (2018)CrossRefGoogle Scholar
  46. 46.
    V. Himamaheswara Rao, P. Syam Prasad, M. Mohan Babu, P. Venkateswara Rao, T. Satyanarayana, L.F. Santos, N. Veeraiah, Spectroscopic studies of Dy3+ ion doped tellurite glasses for solid state lasers and white LEDs. Spectrochim. Acta A Mol. Biomol. Spectrosc. 188, 516–524 (2018)ADSCrossRefGoogle Scholar
  47. 47.
    M.E. Alvarez-Ramos, J. Alvarado-Rivera, M.E. Zayas, U. Caldino, J. Hern_andez-Paredes, Yellow to orange-reddish glass phosphors: Sm3+, Tb3+and Sm3+/Tb3+ in zinc tellurite-germanate glasses. Opt. Mater. 75, 88–93 (2018)ADSCrossRefGoogle Scholar
  48. 48.
    S.H. Alazoumia, S.A. Aziza, R. El-Mallawany, U. Sa'ad Aliyud, H.M. Kamari, M.H.M.M. Zaida, K.A. Matoria, A. Ushah, Optical properties of zinc tellurite glasses. Resul. Phys. 9, 1371–1376 (2018)ADSCrossRefGoogle Scholar
  49. 49.
    A. Tubtimtae, S. Phadungdhitidhada, D. Wongratanaphisan, A. Gardchareon, S. Choopun, Tailoring Cu2_xTe quantum-dot-decorated ZnO nanoparticles for potential solar cell applications. Curr. Appl. Phys. 14, 772–777 (2014)ADSCrossRefGoogle Scholar
  50. 50.
    O.A. Zamyatin, M.F. Churbanov, J.A. Medvedeva, S.A. Gavrin, E.V. Zamyatina, A.D. Plekhovich, Glass-forming region and optical properties of the TeO2 – ZnO – NiO system. J. Non-Cryst. Solids 479, 29–41 (2018)ADSCrossRefGoogle Scholar
  51. 51.
    R.El-Mallawany, Evaluation of optical parameters of some tellurite glasses. Optik-Int. J. Light Electron Opt. 125(20), 6344–6346 (2014)CrossRefGoogle Scholar
  52. 52.
    S.H. Elazoumi, H.A.A. Sidek, Y.S. Rammah, R. El-Mallawany, M.K. Halimah, K.A. Matori, M.H.M. Zaid, Effect of PbO on optical properties of tellurite glass. Res. Phys. 8, 16–25 (2018)Google Scholar
  53. 53.
    R. El-Mallawany, Y.S. Rammah, A. El Adawy, Z. Wassel, Optical and thermal properties of some Tellurite glasses. Am. J. Opt. Photon. 5(2), 11–18 (2017.), doi:10.11648/j.ajop.20170502.11, ISSN: 2330-8486 (Print); ISSN: 2330-8494 (Online)CrossRefGoogle Scholar
  54. 54.
    A. Abdel Kader, A. Higazy, R. EL-Mallawany, M. ElKholy, The effect of gamma irradiation on the electrical conductivity of TeO2 -P2O5 and Bi2O2 -TeO2 -P2O5 glasses. Radiat. Eff. Defects Solids 124, 401 (1992)ADSCrossRefGoogle Scholar

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© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • Raouf El-Mallawany
    • 1
  1. 1.Physics Department, Faculty of ScienceMenoufia UniversityShebin ElKommEgypt

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