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Scaling of Suprastructure and Dynamics in Pure and Mixed Debye Liquids

  • Sebastian Peter Bierwirth
  • Jennifer Bolle
  • Stefan Bauer
  • Christian Sternemann
  • Catalin Gainaru
  • Metin Tolan
  • Roland Böhmer
Chapter
Part of the Advances in Dielectrics book series (ADVDIELECT)

Abstract

Supramolecular relaxations of the Debye or near-Debye type are featured by monohydroxy alcohols, water, and several other liquids. Mainly focusing on results from broadband dielectric spectroscopy, shear rheology, X-ray diffraction, and near-infrared absorption, scaling properties of chain-forming and ring-forming monohydroxy alcohols are examined. Deviations from ideal-mixing behavior in binary solutions involving these liquids in their supercooled state are given particular attention. The present survey is selective rather than comprehensive with a focus on exciting recent developments in this scientific area. Although most of the research summarized in this chapter is based on experiments and analyses carried out under linear-response and ambient-pressure conditions, phenomena emerging beyond these regimes are briefly touched upon as well. Finally, aiming at a faithful representation of the molecular dynamics taking place in these liquids at the microscopic level, overarching aspects arising from the complementary application of experimental techniques as well as perspectives for future developments are discussed.

Notes

Acknowledgements

The support provided by the Deutsche Forschungsgemeinschaft under Grants No. BO1301/8-1, BO1301/8-2, and BO1301/14-1 is highly appreciated. Tina Hecksher kindly made available data for 2-ethyl-1-hexylamine and -thiol. Among our former students we thank in particular Thomas Büning, Kevin Moch, Marcel Preuß, and Hendrik Wittkamp for their contributions. We acknowledge DELTA synchrotron radiation source for allocating beamtime at beamline BL9, Michael Paulus for help with the X-ray diffraction experiments, as well as Patrick Degen and Heinz Rehage for enabling the density measurements.

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Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • Sebastian Peter Bierwirth
    • 1
  • Jennifer Bolle
    • 1
  • Stefan Bauer
    • 1
  • Christian Sternemann
    • 1
  • Catalin Gainaru
    • 1
  • Metin Tolan
    • 1
  • Roland Böhmer
    • 1
  1. 1.Technische Universität DortmundDortmundGermany

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