GTER 2017: Advances and Applications in Geospatial Technology and Earth Resources pp 293-314 | Cite as
Isotopic and Hydrogeochemical Signatures in Evaluating Groundwater Quality in the Coastal Area of the Mekong Delta, Vietnam
Abstract
In the 21st century, fresh water scarcity is perhaps one of the biggest challenges in many coastal regions worldwide due to the rapid population growth, fast urbanization and unpredictable impacts of global climate change. Given this context, the identification of groundwater status is a crucial task for sustainable groundwater use and management practices in coastal areas around the world. This work, conducted in coastal areas of Soc Trang province, is an effort to assess groundwater quality and its controlling factors in a coastal area of the Mekong Delta, Vietnam. In this study, we investigate groundwater quality based on chemical parameters, stable isotopes (δ18O, δ2H) and saturation indices (SI). The study showed that groundwater in the study area is mainly classified into four groups: Na-Cl, Na-Mg-Ca-HCO3, Na-Mg-Ca-HCO3-SO4 and Na-HCO3-Cl. Groundwater quality might be substantially controlled by the rock-water interaction, particularly by mineral dissolution and ion-exchange process. Further, the stable isotopes and saturation indices depict the origin of salt water presenting in the aquifers because of three factors, including paleo-saline water dissolution at deeper aquifers, seawater intrusion into shallow aquifers and saline water diffusion at middle aquifers. This result suggests that the characteristics of hydrogeology, inappropriate groundwater pumping activities and change of hydrological regimes might be the main driving forces of disturbance groundwater flow systems and expansion of saline boundary in the coastal areas of the Vietnamese Mekong Delta.
Keywords
Stable isotopes Hydrogeochemistry Groundwater quality Soc Trang Mekong DeltaNotes
Acknowledgments
The authors would like to express their gratefulness to University of Tsukuba, Japan for providing necessary facilities for this research. We also would like to thank the Thuyloi University, Department of Natural Resources and Environment of Soc Trang Province, Vietnam for their support during the field surveys between 2013 and 2014. Our thankfulness also is extended to Dr. Bui Tran Vuong, Vice Director of the Division for Water Resources and Planning for South Vietnam, and Mr. Nguyen Van Chanh, Mr. Thach Hoang Linh the hydro-geological specialists in Soc Trang province for their kind supports. Particularly, we would like to address special thanks to Japanese Grant Aid for Human Resources Development Scholarship (JDS program) and MEXT scholarship for supporting successful completion of this study.
References
- 1.Wichelns, D.: Volumetric water footprints, applied in a global context, do not provide insight regarding water scarcity or water quality degradation. Ecol. Ind. 74, 420–426 (2017)CrossRefGoogle Scholar
- 2.Liu, J., Liu, Q., Yang, H.: Assessing water scarcity by simultaneously considering environmental flow requirements, water quantity, and water quality. Ecol. Ind. 60, 434–441 (2016)CrossRefGoogle Scholar
- 3.Aeschbach-Hertig, W., Gleeson, T.: Regional strategies for the accelerating global problem of groundwater depletion. Nat. Geosci. 5, 853–861 (2012)CrossRefGoogle Scholar
- 4.Alaya, M.B., Saidi, S., Zemni, T., Zargouni, F.: Suitability assessment of deep groundwater for drinking and irrigation use in the Djeffara aquifers (Northern Gabes, south-eastern Tunisia). Environ. Earth Sci. 71, 3387–3421 (2014)CrossRefGoogle Scholar
- 5.Zhang, R., Hu, S., Zhang, X., Yu, W.: Dissolution kinetics of dolomite in water at elevated temperatures. Aquat. Geochem. 13, 309–338 (2007)CrossRefGoogle Scholar
- 6.Rosenthal, E., Zilberbrand, M., Livshitz, Y.: The hydrochemical evolution of brackish groundwater in central and northern Sinai (Egypt) and in the western Negev (Israel). J. Hydrol. 337, 294–314 (2007)CrossRefGoogle Scholar
- 7.Wen, X., Diao, M., Wang, D., Gao, M.: Hydrochemical characteristics and salinization processes of groundwater in the shallow aquifer of Eastern Laizhou Bay, China. Hydrol. Process. 26, 2322–2332 (2012)CrossRefGoogle Scholar
- 8.Singh, C.K., Kumar, A., Shashtri, S., Kumar, A., Kumar, P., Mallick, J.: Multivariate statistical analysis and geochemical modeling for geochemical assessment of groundwater of Delhi, India. J. Geochem. Explor. 175, 59–71 (2017)CrossRefGoogle Scholar
- 9.Kaltreider, R.C., Davis, A.M., Lariviere, J.P., Hamilton, J.W.: Arsenic alters the function of the glucocorticoid receptor as a transcription factor. Environ. Health Perspect. 109, 245–251 (2001)CrossRefGoogle Scholar
- 10.Mandal, B.K., Suzuki, K.T.: Arsenic round the world: a review. Talanta 58, 201–235 (2002)CrossRefGoogle Scholar
- 11.Bui Huy, T., Tuyet-Hanh, T.T., Johnston, R., Nguyen-Viet, H.: Assessing health risk due to exposure to arsenic in drinking water in Hanam Province, Vietnam. Int. J. Environ. Res. Public Health 11, 7575–7591 (2014)CrossRefGoogle Scholar
- 12.Shankar, S., Shanker, U., Shikha: Arsenic contamination of groundwater: a review of sources, prevalence, health risks, and strategies for mitigation. Sci. World J. 2014, 18 (2014)CrossRefGoogle Scholar
- 13.Jiang, J.-Q., Ashekuzzaman, S.M., Jiang, A., Sharifuzzaman, S.M., Chowdhury, S.R.: Arsenic contaminated groundwater and its treatment options in Bangladesh. Int. J. Environ. Res. Public Health 10, 18–46 (2013)CrossRefGoogle Scholar
- 14.Singh, B., Sekhon, G.S.: Nitrate pollution of groundwater from nitrogen fertilizers and animal wastes in the Punjab, India. Agric. Environ. 3, 57–67 (1976)CrossRefGoogle Scholar
- 15.Zhang, W.L., Tian, Z.X., Zhang, N., Li, X.Q.: Nitrate pollution of groundwater in northern China. Agr. Ecosyst. Environ. 59, 223–231 (1996)CrossRefGoogle Scholar
- 16.Almasri, M.N.: Nitrate contamination of groundwater: a conceptual management framework. Environ. Impact Assess. Rev. 27, 220–242 (2007)CrossRefGoogle Scholar
- 17.Vithanage, M., Mikunthan, T., Pathmarajah, S., Arasalingam, S., Manthrithilake, H.: Assessment of nitrate-N contamination in the Chunnakam aquifer system, Jaffna Peninsula, Sri Lanka. SpringerPlus 3, 271 (2014)CrossRefGoogle Scholar
- 18.Zhang, Q., Sun, J., Liu, J., Huang, G., Lu, C., Zhang, Y.: Driving mechanism and sources of groundwater nitrate contamination in the rapidly urbanized region of south China. J. Contam. Hydrol. 182, 221–230 (2015)CrossRefGoogle Scholar
- 19.Zhai, Y., Zhao, X., Teng, Y., Li, X., Zhang, J., Wu, J., Zuo, R.: Groundwater nitrate pollution and human health risk assessment by using HHRA model in an agricultural area, NE China. Ecotoxicol. Environ. Saf. 137, 130–142 (2017)CrossRefGoogle Scholar
- 20.Vengosh, A.: 9.09 - Salinization and Saline Environments A2 - Holland, Heinrich D. In: Turekian, K.K. (ed.) Treatise on Geochemistry, pp. 1–35. Pergamon, Oxford (2003)Google Scholar
- 21.Abd-Elhamid, H.F., Javadi, A.A.: Impact of sea level rise and over-pumping on seawater intrusion in coastal aquifers. J. Water Clim. Chang. 2, 19–28 (2011)CrossRefGoogle Scholar
- 22.Park, H.-Y., Jang, K., Ju, J.W., Yeo, I.W.: Hydrogeological characterization of seawater intrusion in tidally-forced coastal fractured bedrock aquifer. J. Hydrol. 446–447, 77–89 (2012)CrossRefGoogle Scholar
- 23.Werner, A.D., Bakker, M., Post, V.E.A., Vandenbohede, A., Lu, C., Ataie-Ashtiani, B., Simmons, C.T., Barry, D.A.: Seawater intrusion processes, investigation and management: recent advances and future challenges. Adv. Water Resour. 51, 3–26 (2013)CrossRefGoogle Scholar
- 24.De Filippis, G., Foglia, L., Giudici, M., Mehl, S., Margiotta, S., Negri, S.L.: Seawater intrusion in karstic, coastal aquifers: Current challenges and future scenarios in the Taranto area (southern Italy). Sci. Total Environ. 573, 1340–1351 (2016)CrossRefGoogle Scholar
- 25.Mahlknecht, J., Merchán, D., Rosner, M., Meixner, A., Ledesma-Ruiz, R.: Assessing seawater intrusion in an arid coastal aquifer under high anthropogenic influence using major constituents, Sr and B isotopes in groundwater. Sci. Total Environ. 587–588, 282–295 (2017)CrossRefGoogle Scholar
- 26.Ferguson, G., Gleeson, T.: Vulnerability of coastal aquifers to groundwater use and climate change. Nature Clim. Change 2, 342–345 (2012)CrossRefGoogle Scholar
- 27.Russo, T.A., Lall, U.: Depletion and response of deep groundwater to climate-induced pumping variability. Nature Geosci 10, 105–108 (2017)CrossRefGoogle Scholar
- 28.Gleeson, T., Wada, Y., Bierkens, M.F.P., van Beek, L.P.H.: Water balance of global aquifers revealed by groundwater footprint. Nature 488, 197–200 (2012)CrossRefGoogle Scholar
- 29.Chae, G.-T., Yun, S.-T., Kim, K., Mayer, B.: Hydrogeochemistry of sodium-bicarbonate type bedrock groundwater in the Pocheon spa area, South Korea: water–rock interaction and hydrologic mixing. J. Hydrol. 321, 326–343 (2006)CrossRefGoogle Scholar
- 30.Lorenzen, G., Sprenger, C., Baudron, P., Gupta, D., Pekdeger, A.: Origin and dynamics of groundwater salinity in the alluvial plains of western Delhi and adjacent territories of Haryana State, India. Hydrol. Process. 26, 2333–2345 (2012)CrossRefGoogle Scholar
- 31.Slimani, R., Guendouz, A., Trolard, F., Moulla, A.S., Hamdi-Aïssa, B., Bourrié, G.: Identification of dominant hydrogeochemical processes for groundwaters in the Algerian Sahara supported by inverse modeling of chemical and isotopic data. Hydrol. Earth Syst. Sci. 21, 1669–1691 (2017)CrossRefGoogle Scholar
- 32.Ben Moussa, A., Mzali, H., Zouari, K., Hezzi, H.: Hydrochemical and isotopic assessment of groundwater quality in the Quaternary shallow aquifer, Tazoghrane region, north-eastern Tunisia. Quatern. Int. 338, 51–58 (2014)CrossRefGoogle Scholar
- 33.Mohammed, N., Celle-Jeanton, H., Huneau, F., Le Coustumer, P., Lavastre, V., Bertrand, G., Charrier, G., Clauzet, M.L.: Isotopic and geochemical identification of main groundwater supply sources to an alluvial aquifer, the Allier River valley (France). J. Hydrol. 508, 181–196 (2014)CrossRefGoogle Scholar
- 34.Boschetti, T., González-Hernández, P., Hernández-Díaz, R., Naclerio, G., Celico, F.: Seawater intrusion in the Guanahacabibes Peninsula (Pinar del Rio Province, western Cuba): effects on karst development and water isotope composition. Environ. Earth Sci. 73, 5703–5719 (2015)CrossRefGoogle Scholar
- 35.Lu, C., Xin, P., Li, L., Luo, J.: Seawater intrusion in response to sea-level rise in a coastal aquifer with a general-head inland boundary. J. Hydrol. 522, 135–140 (2015)CrossRefGoogle Scholar
- 36.Arfib, B., Charlier, J.-B.: Insights into saline intrusion and freshwater resources in coastal karstic aquifers using a lumped Rainfall–Discharge–Salinity model (the Port-Miou brackish spring, SE France). J. Hydrol. 540, 148–161 (2016)CrossRefGoogle Scholar
- 37.Mehdizadeh, S.S., Karamalipour, S.E., Asoodeh, R.: Sea level rise effect on seawater intrusion into layered coastal aquifers (simulation using dispersive and sharp-interface approaches). Ocean Coast. Manag. 138, 11–18 (2017)CrossRefGoogle Scholar
- 38.Hornero, J., Manzano, M., Ortega, L., Custodio, E.: Integrating soil water and tracer balances, numerical modelling and GIS tools to estimate regional groundwater recharge: application to the Alcadozo aquifer system (SE Spain). Sci. Total Environ. 568, 415–432 (2016)CrossRefGoogle Scholar
- 39.Minderhoud, P.S.J., Erkens, G., Pham, V.H., Bui, V.T., Erban, L., Kooi, H., Stouthamer, E.: Impacts of 25 years of groundwater extraction on subsidence in the Mekong Delta, Vietnam. Environ. Res. Lett. 12, 064006 (2017)CrossRefGoogle Scholar
- 40.Benner, S.G., Polizzotto, M.L., Kocar, B.D., Ganguly, S., Phan, K., Ouch, K., Sampson, M., Fendorf, S.: Groundwater flow in an arsenic-contaminated aquifer, Mekong Delta, Cambodia. Appl. Geochem. 23, 3072–3087 (2008)CrossRefGoogle Scholar
- 41.Merola, R.B., Hien, T.T., Quyen, D.T.T., Vengosh, A.: Arsenic exposure to drinking water in the Mekong Delta. Sci. Total Environ. 511, 544–552 (2015)CrossRefGoogle Scholar
- 42.Stuckey, J.W., Schaefer, M.V., Kocar, B.D., Benner, S.G., Fendorf, S.: Arsenic release metabolically limited to permanently water-saturated soil in Mekong Delta. Nat. Geosci. 9, 70–76 (2016)CrossRefGoogle Scholar
- 43.Ho, H.D., Aramyossy, J.F., Louvat, D., Huu, M.Q., Nguyen, T.V., Nguyen, K.C.: Environmental isotopes study related to the origin, salinization and movement of groundwater in the Mekong Delta (Vietnam). IAEA, UNESCO (1991)Google Scholar
- 44.Khoi, L.V., Chinh, N.K., Hung, D.T.: Groundwater salinity study in the Mekong Delta using isotope techniques. Commun. Phys. 1, 30–35 (2002)Google Scholar
- 45.An, T.D., Tsujimura, M., Le Phu, V., Kawachi, A., Ha, D.T.: Chemical characteristics of surface water and groundwater in coastal watershed, Mekong Delta, Vietnam. Procedia Environ. Sci. 20, 712–721 (2014)CrossRefGoogle Scholar
- 46.Wagner, F., Tran, V.B., Renaud, F.G.: Groundwater resources in the Mekong Delta: availability, utilization and risks. In: Renaud, F., Kuenzer, C. (eds.) The Mekong Delta System: Interdisciplinary Analyses of a River Delta. Springer, Dordrecht (2010). Chap. 7Google Scholar
- 47.Slimani, R., Guendouz, A., Trolard, F., Moulla, A.S., Hamdi-Aissa, B., Bourrié, G.: Geochemical inverse modeling of chemical and isotopic data from groundwaters in Sahara (Ouargla Basin, Algeria). Hydrol. Earth Syst. Sci. Discuss. 2016, 1–49 (2016)CrossRefGoogle Scholar
- 48.Indraratna, B., Sullivan, J., Nethery, A.: Effect of groundwater table on the formation of acid sulphate soils. Mine Water Environ. 14, 71–83 (1995)Google Scholar
- 49.Vahedian, A., Aghdaei, S.A., Mahini, S.: Acid sulphate soil interaction with groundwater: a remediation case study in East Trinity. APCBEE Procedia 9, 274–279 (2014)CrossRefGoogle Scholar
- 50.Erban, L.E., Gorelick, S.M., Zebker, H.A., Fendorf, S.: Release of arsenic to deep groundwater in the Mekong Delta, Vietnam, linked to pumping-induced land subsidence. Proc. Natl. Acad. Sci. 110, 13751–13756 (2013)CrossRefGoogle Scholar
- 51.Piper, A.M.: A graphic procedure in the geochemical interpretation of water-analyses. EOS Trans. Am. Geophys. Union 25, 914–928 (1944)CrossRefGoogle Scholar
- 52.Hoang, T.M., van Lap, N., Oanh, T.T.K., Jiro, T.: The influence of delta formation mechanism on geotechnical property sequence of the late Pleistocene-Holocene sediments in the Mekong River Delta. Heliyon 2, e00165 (2016)CrossRefGoogle Scholar
- 53.Delsman, J.R., Hu-a-ng, K.R.M., Vos, P.C., de Louw, P.G.B., Oude Essink, G.H.P., Stuyfzand, P.J., Bierkens, M.F.P.: Paleo-modeling of coastal saltwater intrusion during the Holocene: an application to the Netherlands. Hydrol. Earth Syst. Sci. 18, 3891–3905 (2014)CrossRefGoogle Scholar
- 54.Robinson, G., Ahmed, A.A., Hamill, G.A.: Experimental saltwater intrusion in coastal aquifers using automated image analysis: Applications to homogeneous aquifers. J. Hydrol. 538, 304–313 (2016)CrossRefGoogle Scholar
- 55.West, A.G., February, E.C., Bowen, G.J.: Spatial analysis of hydrogen and oxygen stable isotopes (“isoscapes”) in ground water and tap water across South Africa. J. Geochem. Explor. 145, 213–222 (2014)CrossRefGoogle Scholar
- 56.Craig, H.: Isotopic variations in meteoric waters. Science 133, 1702–1703 (1961)CrossRefGoogle Scholar
- 57.Kabeya, N., Shimizu, A., Chann, S., Tsuboyama, Y., Nobuhiro, T., Keth, N., Tamai, K.: Stable isotope studies of rainfall and stream water in forest watersheds in Kampong Thom, Cambodia. In: Sawada, H., Araki, M., Chappell, N.A., LaFrankie, J.V., Shimizu, A. (eds.) Forest Environments in the Mekong River Basin, pp. 125–134. Springer, Tokyo (2007)CrossRefGoogle Scholar
- 58.Coplen, T.B., Hanshaw, B.B.: Ultrafiltration by a compacted clay membrane—I. Oxygen and hydrogen isotopic fractionation. Geochim. Cosmochim. Acta 37, 2295–2310 (1973)CrossRefGoogle Scholar
- 59.Thu, N.T.: Groundwater and surface water cycle system in Mekong Delta, Vietnam. Life and Environmental Sciences, p. 171. University of Tsukuba, Tsukuba (2017)Google Scholar
- 60.Tsujimura, M., Abe, Y., Tanaka, T., Shimada, J., Higuchi, S., Yamanaka, T., Davaa, G., Oyunbaatar, D.: Stable isotopic and geochemical characteristics of groundwater in Kherlen River Basin, a semi-arid region in eastern Mongolia. J. Hydrol. 333, 47–57 (2007)CrossRefGoogle Scholar
- 61.Senthilkumar, S., Balasubramanian, N., Gowtham, B., Lawrence, J.F.: Geochemical signatures of groundwater in the coastal aquifers of Thiruvallur district, south India. Appl. Water Sci. 7, 263–274 (2017)CrossRefGoogle Scholar
- 62.Wang, Y., Jiao, J.J.: Origin of groundwater salinity and hydrogeochemical processes in the confined Quaternary aquifer of the Pearl River Delta, China. J. Hydrol. 438–439, 112–124 (2012)CrossRefGoogle Scholar
- 63.Li, C., Liu, T., Xu, S., Gao, X., Wang, Y.: Groundwater salinization in shallow aquifers adjacent to a low-altitude inland salt lake: a case study at Yuncheng Basin, northern China. Environ. Earth Sci. 75, 370 (2016)CrossRefGoogle Scholar
- 64.Tijani, M.N.: Evolution of saline waters and brines in the Benue-Trough, Nigeria. Appl. Geochem. 19, 1355–1365 (2004)CrossRefGoogle Scholar
- 65.Kim, Y., Lee, K.-S., Koh, D.-C., Lee, D.-H., Lee, S.-G., Park, W.-B., Koh, G.-W., Woo, N.-C.: Hydrogeochemical and isotopic evidence of groundwater salinization in a coastal aquifer: a case study in Jeju volcanic island, Korea. J. Hydrol. 270, 282–294 (2003)CrossRefGoogle Scholar
- 66.Ghabayen, S.M.S., McKee, M., Kemblowski, M.: Ionic and isotopic ratios for identification of salinity sources and missing data in the Gaza aquifer. J. Hydrol. 318, 360–373 (2006)CrossRefGoogle Scholar