Abstract
Smelting-acid leaching process is a way to treat high-content arsenic containing copper. However, smelting process makes a low recovery of valuable metals and acid-leaching process makes large amounts of arsenic-iron slag. Arsenic sulphuration volatilization at a low temperature was studied in this paper and valuable metals were recovered with different methods. Arsenic recycled as As2O3 was separated from other valuable metals selectively and calcines were treated by acid pressure leaching. Indium and copper in leaching liquor were made into sponge indium/copper after the processes of extraction-re-extraction-displacing process (ERD process) and displacing process. ZnSO4ยท7H2O was collected after concentrating while recovering zinc. Metals, such as tin, bismuth and lead, were recycled as raw materials for tin metallurgy.
References
W. Chen et al., Study on the new process for treating copper converter dusts. Non-ferrous Min. Metall. 3(19), 45โ47 (2003)
Y. Xu et al., A new process for comprehensive utilization of high-arsenic dust from Isa furnace. China Nonferrous Metall. 5, 16โ18 (2005)
H. Li, The process practice for recycle of lead, copper and bismuth from the fume of the copper converter. Yunnan Metall. 2(40), 52โ56 (2011)
Z. Liu, Analysis and suggestion on comprehensive recovery process of copper smelting dust. China Nonferrous Metall. 5, 44โ48 (2015)
S. Ruan, Y. Lu, On comprehensive recovery of valuable metals from ESP dust in copper smelting. Nonferrous Smelting 6, 41โ44 (2003)
Z. Yu, Comprehensive utilization of copper converter dust. Nonferrous Smelting (1), 37โ40 (1997)
T. Li, Process and practice of hydrometallurgical treatment of as-enriched dust. China Nonferrous Metall. 5, 11โ14 (2015)
J.-J. Ke, R.-Y. Qiu, Recovery of metal values from copper smelter flue dust. Hydrometallurgy 12(2), 217โ224 (1984)
Z. Xu et al., Pressure leaching technique of smelter dust with high-copper and high-arsenic. Chin. J. Nonferrous Metals 18(1), S59โS63 (2008)
M. Li, Comprehensive recovery of valuable elements in copper smelting process. China Nonferrous Metall. 2, 71โ73 (2014)
Z. Wang et al., The new technics processing of recovering valuable metals by using hydrometallurical process to treat the copper dust. Hunan Nonferrous Metals 6(26), 20โ23 (2010)
L. Guan et al., Leaching process for comprehensive recovery of valuable metals from copper smelter dust with low indium. Chin. J. Rare Metals 1(32), 88โ93 (2008)
A.J. Monhemius, P.M. Swash, Removing and stabilizing as from copper refining circuits by hydrothermal processing. JOM 9, 30โ33 (1999)
Y. Liao et al., Research on kinetics of leaching of arsenic from dust containing high arsenic. J. Sichuan Univ. (Eng. Sci. Ed.) 3(45), 200โ206 (2015)
A.A. Samuel, S. Ake, Selective leaching arsenic and antimony from a tetrahedrite rich complex sulphide concentrate using alkaline sulphide solution. Miner. Eng. 23, 1227โ1236 (2010)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
ยฉ 2017 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Li, X., Liu, D. (2017). Recovery of Valuable Metals from High-Content Arsenic Containing Copper Smelting Dust. In: Kim, H., Alam, S., Neelameggham, N., Oosterhof, H., Ouchi, T., Guan, X. (eds) Rare Metal Technology 2017. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-51085-9_19
Download citation
DOI: https://doi.org/10.1007/978-3-319-51085-9_19
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-51084-2
Online ISBN: 978-3-319-51085-9
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)