Organogels pp 17-36 | Cite as
Thermodynamic and Kinetic Aspects
Chapter
First Online:
Abstract
As was mentioned in the previous chapter, organogel formation and melting proceed chiefly from first-order transitions.
Keywords
Phase Diagram Benzyl Alcohol Homogeneous Nucleation Spinodal Decomposition Liquid Phase Separation
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References
- 1.Terech, P., Schaffhauser, V., Maldivi, P., Guenet, J.M.: Rheological and neutron scattering investigations of the jelly state of binuclear copper complexes in cyclohexane. Europhys. Lett. 17, 515 (1992)ADSCrossRefGoogle Scholar
- 2.Cates, M.E.: Reptation of living polymers: dynamics of entangled polymers in the presence of reversible chain-scission reactions. Macromolecules 20, 2289 (1987); Cates, M.E.: Dynamics of living polymers and flexible surfactant micelles: scaling laws for dilution. J. Phys. Fr. 49, 1593 (1988)Google Scholar
- 3.Terech, P., Schaffhauser, V., Maldivi, P., Guenet, J.M.: Living polymers in organic solvents. Langmuir 8, 2104 (1992)CrossRefGoogle Scholar
- 4.Schmelzer, J.W.P.: Phase transitions, and nucleation. In: Hubbard, A. (Ed.) Encyclopedia of Surface and Colloid Science, pp. 4017–4029. Marcel Dekker, New-York (2002)Google Scholar
- 5.Gibbs, J.W.: Elementary Principles in Statistical Mechanics. Charles Scribner’s Sons, New York (1902)MATHGoogle Scholar
- 6.Francois, J., Gan, Y.S., Guenet, J.M.: The sol–gel transition and phase diagram of the system aPS-CS2. Macromolecules 19, 2755 (1986) (experimental examples)Google Scholar
- 7.Cahn, J.W., Hilliard, J.E.: Free energy of a nonuniform system. I. Interfacial free energy. J. Chem. Phys. 28, 258 (1958)ADSCrossRefGoogle Scholar
- 8.Guenet, J.M.: Thermoreversible Gels from Polymer and Biopolymers. Academic Press, London (1992)Google Scholar
- 9.Terech, P., Pasquier, D., Bordas, V., Rossat, C.: Rheological properties and structural correlations in molecular organogels. Langmuir 16, 4485–4494 (2000)CrossRefGoogle Scholar
- 10.Reisman, A.: Phase Equilibria. Academic Press, New York (1970)Google Scholar
- 11.Atkins, P.W., de Paula, J.: Physical Chemistry, 9th edn. Oxford University Press, Oxford (2010)Google Scholar
- 12.Guenet, J.M.: Polymer-Solvent Molecular Compounds. Elsevier, London (2008)Google Scholar
- 13.Cahn, J.W.: The metastable liquidus and its effect on the crystallization of glass. J. Am. Ceram. Soc. 52, 118 (1969)Google Scholar
- 14.Zarzycki, J.: Phase-separated systems. Disc. Farad. Soc. 1970, 122 (1971)Google Scholar
- 15.Dasgupta, D., Srinivasan, S., Rochas, C., Ajayaghosh, A., Guenet, J.M.: Solvent-mediated fiber growth in organogels. Soft Matter 7, 9311 (2011)ADSCrossRefGoogle Scholar
- 16.Daniel, C., De Luca, M.D., Brulet, A., Menelle, A., Guenet, J.M.: Thermoreversible gelation of syndiotactic polystyrene in benzene. Polymer 37, 1273 (1996)Google Scholar
- 17.Sarbu, A., Biniek, L., Guenet, J.M., Mesini, P.J., Brinkmann, M.: Reversible J- to H-aggregate transformation in thin films of a perylene-bisimide organogelator. J. Mater Chem. C. 3, 1235 (2015)CrossRefGoogle Scholar
- 18.Flory, P.J.: Principles of Polymer Chemistry. Cornell University Press, New York (1953)Google Scholar
- 19.Feng, L., Cavicchi, K.A.: Investigation of the relationships between the thermodynamic phase behavior and gelation behavior of a series of tripodal trisamide compounds. Soft Matter 8, 6483 (2012)CrossRefGoogle Scholar
- 20.Nonappa, Lahtinen M., Behera, B., Kolehmainen, E., Maitra, U.: Unraveling the packing pattern to gelation using SS NMR and X-ray diffration: direct observation of the evolution of self-assemble fibres. Soft Matter 6, 1748 (2010)ADSCrossRefGoogle Scholar
- 21.Christ, E. et al. Origin of invariant gel melting temperatures in the c-T phase diagram of an organogel. Langmuir (2016). http://dx.doi.org/10.1021/acs.langmuir.6b00995
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© Jean-Michel Guenet 2016