XUV Attosecond Photoionization and Related Ultrafast Processes in Diatomic and Large Molecules

  • Victor Despré
  • Alexandre Marciniak
  • Thomas Barillot
  • Vincent Loriot
  • Arnaud Rouzée
  • Marc. J. J. Vrakking
  • Franck Lépine
Chapter
Part of the Springer Series on Atomic, Optical, and Plasma Physics book series (SSAOPP, volume 86)

Abstract

New means of inducing and probing in real-time charge dynamics and energy flow in molecules have evolved with progresses made in laser technology and secondary sources. One significant example is the light source based on high harmonic generation (HHG). Such a source typically allows the production of extreme ultraviolet (XUV) radiations temporally confined in very short pulses down to a few tens of femtoseconds and even attosecond duration. This naturally offers new opportunities to study extremely fast processes in very excited molecular species and to track dynamics down to the ultimate time scale of electronic motion. This chapter summarizes recent results obtained in simple and complex molecular species using these short XUV pulses. It demonstrates the potential impact of pump-probe XUV science in molecular physics, chemistry, plasmonic or astrochemistry. Hints of dynamics below 1 fs in pump-probe experiments are already observed in increasingly large systems showing the way to chemistry on attosecond time scale.

Keywords

High Harmonic Generation Attosecond Pulse Charge Dynamic Carrier Envelope Phase Attosecond Pulse Train 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    F. Lépine, M.Y. Ivanov, M.J.J. Vrakking, Nat. Photonics 8, 195–204 (2014)ADSCrossRefGoogle Scholar
  2. 2.
    M. Krausz, M. Ivanov, Attosecond physics. Rev. Mod. Phys. 81, 163–234 (2009)ADSCrossRefGoogle Scholar
  3. 3.
    J. Itatani, J. Levesque, D. Zeidler, H. Niikura, H. Pepin, J.C. Kieffer, P.B. Corkum, D.M. Villeneuve, Nature 432, 867–871 (2004)ADSCrossRefGoogle Scholar
  4. 4.
    O. Smirnova, Y. Mairesse, S. Patchkovskii, N. Dudovich, D. Villeneuve, P. Corkum, M.Y. Ivanov, High harmonic interferometry of multi-electron dynamics in molecules. Nature 460, 972–977 (2009)ADSCrossRefGoogle Scholar
  5. 5.
    P.A. Carpeggiani, P. Tzallas, A. Palacios, D. Gray, F. Martín, D. Charalambidis, Phys. Rev. A 89, 023420 (2014)ADSCrossRefGoogle Scholar
  6. 6.
    A.I. Kuleff, L.S. Cederbaum, Dynamics. J. Phys. B 47, 1240021–12400212 (2014)CrossRefGoogle Scholar
  7. 7.
    F. Calegari, D. Ayuso, A. Trabattoni, L. Belshaw, S. De Camillis, S. Anumula, F. Frassetto, L. Poletto, A. Palacios, P. Decleva et al., Science 346, 336–339 (2014)ADSCrossRefGoogle Scholar
  8. 8.
    J.J. Larsen, H. Sakai, C.P. Safvan, I. Wendt-Larsen, H. Stapelfeldt, J. Chem. Phys. 111, 7774–7781 (1999)ADSCrossRefGoogle Scholar
  9. 9.
    C. Neidel, J. Klei, C.H. Yang, A. Rouzée, M.J.J. Vrakking, K. Klünder, M. Miranda, C.L. Arnold, T. Fordell, A. L’Huillier, M. Gisselbrecht, P. Johnsson, M.P. Dinh, E. Suraud, P.G. Reinhard, V. Despré, M.A.L. Marques, F. Lépine, Phys. Rev. Lett. 111, 033001 (2013)ADSCrossRefGoogle Scholar
  10. 10.
    M. Ruberti, R. Yun, K. Gokhberg, S. Kopelke, L.S. Cederbaum, F. Tarantelli, V. Averbukh, J. Chem. Phys. 140, 184107 (2014)ADSCrossRefGoogle Scholar
  11. 11.
    J.C. Baggesen, L.B. Madsen, Phys. Rev. Lett. 104, 043602 (2010)ADSCrossRefGoogle Scholar
  12. 12.
    F. Kelkensberg, W. Siu, J.F. Perez-Torres, F. Morales, G. Gademann, A. Rouzee, P. Johnsson, M. Lucchini, F. Calegari, J.L. Sanz-Vicario, F. Martin, M.J.J. Vrakking, Phys. Rev. Lett. 107, 043002 (2011)ADSCrossRefGoogle Scholar
  13. 13.
    H.G. Muller, Reconstruction of attosecond harmonic beating by interference of two-photon transitions. Appl. Phys. B-Lasers Opt. 74, S17–S21 (2002)ADSCrossRefGoogle Scholar
  14. 14.
    W. Siu, F. Kelkensberg, G. Gademann, A. Rouzée, P. Johnsson, D. Dowek, M. Lucchini, F. Calegari, U. De Giovannini, A. Rubio, R.R. Lucchese, H. Kono, F. Lépine, M.J.J. Vrakking, Attosecond control of dissociative ionization of \(\text{ O }_2\) molecules. Phys. Rev. A 84, 063412 (2011)Google Scholar
  15. 15.
    G. Sansone, F. Kelkensberg, J.F. Perez-Torres, F. Morales, M.F. Kling, W. Siu, O. Ghafur, P. Johnsson, M. Swoboda, E. Benedetti, F. Ferrari, F. Lepine, J.L. Sanz-Vicario, S. Zherebtsov, I. Znakovskaya, A. L’Huillier, M.Y. Ivanov, M. Nisoli, F. Martin, M.J.J. Vrakking, Electron localization following attosecond molecular photoionization. Nature 465, 763–U763 (2010)ADSCrossRefGoogle Scholar
  16. 16.
    F. Martin, J. Fernandez, T. Havermeier, L. Foucar, T. Weber, K. Kreidi, M. Schoffler, L. Schmidt, T. Jahnke, O. Jagutzki, A. Czasch, E.P. Benis, T. Osipov, A.L. Landers, A. Belkacem, M.H. Prior, H. Schmidt-Bocking, C.L. Cocke, R. Dorner, Single photon-induced symmetry breaking of \(\text{ H }_2\) dissociation. Science 315, 629–633 (2007)Google Scholar
  17. 17.
    P. Dietrich, M.Y. Ivanov, F.A. Ilkov, P.B. Corkum, Two-electron dissociative ionization of \({\rm H}_2\) and \({\rm D}_2\) in infrared laser fields. Phys. Rev. Lett. 77, 4150–4153 (1996)Google Scholar
  18. 18.
    F. Kelkensberg, G. Sansone, M.Y. Ivanov, M. Vrakking, A semi-classical model of attosecond electron localization in dissociative ionization of hydrogen. Phys. Chem. Chem. Phys. 13, 8647–8652 (2011)CrossRefGoogle Scholar
  19. 19.
    A. Marciniak, V. Despré, T. Barillot, A. Rouzée, M.C.E. Galbraith, J. Klei, C-H. Yang, C. T. L. Smeenk, V. Loriot, S. Nagaprasad Reddy, A.G.G.M. Tielens, S. Mahapatra, A.I. Kuleff, M.J.J. Vrakking & F. Lépine Femto-Astrochemistry: XUV Multi-electronic excitation followed by ultrafast non-adiabatic relaxation in PAH molecules. Nat. Commun. (in press 2015)Google Scholar
  20. 20.
    J. Breidbach and L. S. Cederbaum J. Chem. Phys. 118, 3983 (2003)Google Scholar
  21. 21.
    A.G.G.M. Tielens, Rev. Mod. Phys. 85, 1021 (2013)ADSCrossRefGoogle Scholar
  22. 22.
    F. Lépine, Multiscale dynamics of C\(_{60}\): from attosecond to statistical physics. J. Phys. B: At. Mol. Opt. Phys topical review. 48, 122002 (2015)Google Scholar
  23. 23.
    M. Schultze et al., Science 328, 1658 (2010)ADSCrossRefGoogle Scholar
  24. 24.
    S. Haessler et al., Phys. Rev. A 80, 011404 (2009)ADSCrossRefGoogle Scholar
  25. 25.
    G. Dixit, H.S. Chakraborty, M.E. Madjet, Phys. Rev. Lett. 111, 203003 (2013)ADSCrossRefGoogle Scholar
  26. 26.
    E.P. Wigner, Phys. Rev. 98, 145–147 (1955)MathSciNetADSCrossRefMATHGoogle Scholar
  27. 27.
    T. Barillot, C. Cauchy, P-A. Hervieux, M. Gisselbrecht, S. Canton, Per Johnson, K. Hansen, C. Arnold, S. Sorensen and F. Lépine, Angular asymmetry and attosecond time delay from giant plasmon in C\(_{60}\) photoionization. Phys. Rev. A 91, 033413 (2015)Google Scholar

Copyright information

© Springer International Publishing Switzerland 2016

Authors and Affiliations

  • Victor Despré
    • 1
  • Alexandre Marciniak
    • 1
  • Thomas Barillot
    • 1
  • Vincent Loriot
    • 1
  • Arnaud Rouzée
    • 2
  • Marc. J. J. Vrakking
    • 2
  • Franck Lépine
    • 1
  1. 1. Institut Lumière Matière ILMCNRSVilleurbanne CEDEXFrance
  2. 2.Max-Born Institute (MBI)BerlinGermany

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