Abstract
First attempts to create batteries using an ion other than the proton were done in the 1970s with the fabrication of lithium primary cells. It was the fast development of the electronic devices that pouch electrochemists in the new world of lithium. After primary cells came secondary (rechargeable) lithium batteries in the 1980s. Innovations and advances in insertion electrode materials have improved the stored energy compared with other systems. For half-a-century, lithium batteries are increasingly used in a huge number of applications from watches, portable electronics to electric transportation and stationary grid storage. While older technologies such as Zn-MnO2, lead-acid, and Ni-Cd are still used, the increasing battery market is now dominated by Li-ion batteries. The purpose of this chapter is to introduce the technologies of primary and secondary lithium electrochemical cells with a special focus on lithium-ion batteries and lithium-metal polymer batteries.
Keywords
Polymer Electrolyte Lower Unoccupied Molecular Orbital Solid Electrolyte Interphase Lithium Cell Secondary Lithium BatterieReferences
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