Skip to main content

Transition Metal Oxide/Carbon Nanofiber Composites as Electrode Materials for Supercapacitors

  • Chapter
  • First Online:
Handbook of Nanocomposite Supercapacitor Materials II

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 302))

Abstract

The supercapacitor is recognized as an important device for next-generation energy storage due to its high-power densities. Carbon-based materials are the most widely considered as electrodes for supercapacitors due to their large specific surface area and excellent electrical conductivity. However, they generally suffer from low specific capacitance values and therefore poor energy densities. Recently, transition metal oxides are vastly integrated with carbon materials to design hybrid supercapacitors to improve energy density. Due to the existence of high electrical conductivity and specific surface area, carbon nanofibers are widely used in hybrid supercapacitor electrodes with different transition metal oxides like MnO2, RuO2, and V2O5. These hybrid supercapacitors simultaneously deliver high energy and power densities with long cycle life and rate capability. Therefore, this chapter is mainly focused on hybrid supercapacitors of transition metal oxides with carbon nanofiber. The chapter provides decent and updated coverage on the fabrication and structure of different hybrid supercapacitors based on transition metal oxides and carbon nanofiber, and their electrochemical performance.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 149.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 199.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 199.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. S. Banerjee, B. De, P. Sinha, Jayesh Cherusseri, K. K. Kar, Applications of supercapacitors, in Handbook of Nanocomposite Supercapacitor Materials I Characteristics, ed. by K. K. Kar (Springer, Heidelberg, 2020). https://doi.org/10.1007/978-3-030-43009-2_13

  2. J. Tahalyani, J. Akhtar, J. Cherusseri, K. K. Kar, Characteristics of capacitor: fundamental aspects, in Handbook of Nanocomposite Supercapacitor Materials I Characteristics, ed. by K. K. Kar (Springer, Heidelberg, 2020). https://doi.org/10.1007/978-3-030-43009-2_1

  3. S. Banerjee, P. Sinha, K.D. Verma, T. Pal, B. De, J. Cherusseri, P.K. Manna, K. K. Kar, Capacitor to supercapacitor, in Handbook of Nanocomposite Supercapacitor Materials I Characteristics, ed. by K. K. Kar (Springer, Heidelberg, 2020). https://doi.org/10.1007/978-3-030-43009-2_2

  4. L.L. Zhang, X.S. Zhao, Chem. Soc. Rev. 38, 2520 (2009)

    Article  CAS  Google Scholar 

  5. Z. Yang, J. Ren, Z. Zhang, X. Chen, G. Guan, L. Qiu, Y. Zhang, H. Peng, Chem. Rev. 115, 5159 (2015)

    Article  CAS  Google Scholar 

  6. C.C. Hu, K.H. Chang, M.C. Lin, Y.T. Wu, Nano Lett. 6, 2690 (2006)

    Article  CAS  Google Scholar 

  7. W. Xiao, H. Xia, J.Y.H. Fuh, L. Lu, J. Power Sources 193, 935 (2009)

    Article  CAS  Google Scholar 

  8. R. Sharma, K.K. Kar, J. Mater. Chem. A 3, 11948 (2015)

    Article  CAS  Google Scholar 

  9. M. Zhi, C. Xiang, J. Li, M. Li, N. Wu, Nanoscale 5, 72 (2013)

    Article  CAS  Google Scholar 

  10. O. Borenstein, R. Hanna, S. Attias, T. Luski, D. Brousse, J. Aurbach, Mater. Chem. A 5, 12653 (2017)

    Article  CAS  Google Scholar 

  11. G. Wang, L. Zhang, J. Zhang, Chem. Soc. Rev. 41, 797 (2012)

    Article  CAS  Google Scholar 

  12. H. Wang, H. Dai, Chem. Soc. Rev. 42, 3088 (2013)

    Article  CAS  Google Scholar 

  13. R. Kumar, S. Sahoo, E. Joanni, R.K. Singh, W.K. Tan, K.K. Kar, A. Matsuda, Prog. Energy Combust. Sci. 75, 100786 (2019)

    Article  Google Scholar 

  14. W. Li, F. Zhang, Y. Dou, Z. Wu, H. Liu, X. Qian, D. Gu, Y. Xia, B. Tu, D. Zhao, Adv. Energy Mater. 1, 382 (2011)

    Article  CAS  Google Scholar 

  15. B. Zhang, Y. Yu, Z. Huang, Y.-B. He, D. Jang, W.-S. Yoon, Y.-W. Mai, F. Kang, J.-K. Kim, Energy Environ. Sci. 5, 9895 (2012)

    Article  CAS  Google Scholar 

  16. K. K. Kar, A. Hodzic, Carbon Nanotube Based Nanocomposites: Recent Developments. Le, 1st ed. (Research publishing, 2011)

    Google Scholar 

  17. L.-F. Chen, Z.-H. Huang, H.-W. Liang, Q.-F. Guan, S.-H. Yu, Adv. Mater. 25, 4746 (2013)

    Article  CAS  Google Scholar 

  18. S.-C. Lin, Y.-T. Lu, J.-A. Wang, C.-C.M. Ma, C.-C. Hu, J. Power Sources 400, 415 (2018)

    Article  CAS  Google Scholar 

  19. J. Cherusseri, K.K. Kar, J. Mater. Chem. A 3, 21586 (2015)

    Article  CAS  Google Scholar 

  20. R. Sharma, K.K. Kar (2020) Characteristics of carbon nanofibers, in Handbook of Nanocomposite Supercapacitor Materials I Characteristics, ed. by K. K. Kar (Springer, Heidelberg, 2020). https://doi.org/10.1007/978-3-030-43009-2_7

  21. Tyagi, S. Banerjee, J. Cherusseri, K. K. Kar, Characteristics of transition metal oxides, in Handbook of Nanocomposite Supercapacitor Materials I Characteristics, ed. by K. K. Kar (Springer, Heidelberg, 2020). https://doi.org/10.1007/978-3-030-43009-2_3

  22. F. Wang, Z. Chang, M. Li, Y. Wu, Nanocarbon-based materials for asymmetric supercapacitors, in Nanocarbons for Advanced Energy Storage, ed. by X. Feng (Wiley, 2015). https://doi.org/10.1002/9783527680054.ch14

  23. K. K. Kar, Carbon Nanotubes: Synthesis, Characterization and Applications, 1st ed. (Research publishing, 2011)

    Google Scholar 

  24. W. Wei, X. Cui, W. Chen, D.G. Ivey, Chem. Soc. Rev. 40, 1697 (2011)

    Article  CAS  Google Scholar 

  25. B. De, A. Yadav, S. Khan, K.K. Kar, A.C.S. Appl, Mater. Interfaces 9, 19870 (2017)

    Article  CAS  Google Scholar 

  26. J. Liu, J. Essner, J. Li, Chem. Mater. 22, 5022 (2010)

    Article  CAS  Google Scholar 

  27. M. Zhi, A. Manivannan, F. Meng, N. Wu, J. Power Sources 208, 345 (2012)

    Article  CAS  Google Scholar 

  28. J.-G. Wang, Y. Yang, Z.-H. Huang, F. Kang, Electrochim. Acta 56, 9240 (2011)

    Article  CAS  Google Scholar 

  29. Y. Yang, S. Lee, D.E. Brown, H. Zhao, X. Li, D. Jiang, S. Hao, Y. Zhao, D. Cong, X. Zhang, Y. Ren, Electrochim. Acta 211, 524 (2016)

    Article  CAS  Google Scholar 

  30. V. Augustyn, P. Simon, B. Dunn, Energy Environ. Sci. 7, 1597 (2014)

    Article  CAS  Google Scholar 

  31. B.J. Lee, S.R. Sivakkumar, J.M. Ko, J.H. Kim, S.M. Jo, D.Y. Kim, J. Power Sources 168, 546 (2007)

    Article  CAS  Google Scholar 

  32. J. Cherusseri, R. Sharma R, K. K. Kar, Nanotechnology advancements on carbon nanotube/polypyrrole composite electrodes for supercapacitors, in Handbook of Polymer Nanocomposites. Processing, Performance and Application, ed. by K. K. Kar, J. K. Pandey, S. Rana (Springer, Heidelberg, 2015). https://doi.org/10.1007/978-3-642-45229-1_22

  33. C.-M. Chuang, C.-W. Huang, H. Teng, J.-M. Ting, Compos. Sci. Technol. 72, 1524 (2012)

    Article  CAS  Google Scholar 

  34. F. Pico, J. Ibañez, M.A. Lillo-Rodenas, A. Linares-Solano, R.M. Rojas, J.M. Amarilla, J.M. Rojo, J. Power Sources 176, 417 (2008)

    Article  CAS  Google Scholar 

  35. M. Li, G. Sun, P. Yin, C. Ruan, K. Ai, A.C.S. Appl, Mater. Interfaces 5, 11462 (2013)

    Article  CAS  Google Scholar 

  36. S. Boukhalfa, K. Evanoff, G. Yushin, Energy Environ. Sci. 5, 6872 (2012)

    Article  CAS  Google Scholar 

  37. S. Banerjee, K.K. Kar, J. Appl. Polym. Sci. 133, 42952 (2016)

    Article  Google Scholar 

  38. S. Banerjee, R. Sharma, K.K. Kar, Nanocomposites based on carbon nanomaterials and electronically nonconducting polymers, in Composite Materials, ed. by K. K. Kar (Springer, Heidelberg, 2017). https://doi.org/10.1007/978-3-662-49514-8_8

  39. Pan, H. Bin Wu, L. Yu, X.W.D. Lou, Angew. Chemie Int. Ed. 52, 2226 (2013)

    Google Scholar 

  40. Q. Pan, H. Bin Wu, L. Zhang, X. W. (David) Lou, Energy Environ. Sci. 6, 1476 (2013)

    Google Scholar 

  41. B.-H. Kim, C.H. Kim, K.S. Yang, A. Rahy, D.J. Yang, Electrochim. Acta 83, 335 (2012)

    Article  CAS  Google Scholar 

  42. E.J. Ghosh, M. Ra, H.-K. Jin, T.H. Jeong, C. Kim, Y.H. Biswas, Lee. Adv. Funct. Mater. 21, 2541 (2011)

    Article  CAS  Google Scholar 

  43. L. Li, S. Peng, H. Bin Wu, L. Yu, S. Madhavi, X. W. D. Lou, Adv. Energy Mater. 5, 1500753 (2015)

    Google Scholar 

  44. T.-Y. Wei, C.-H. Chen, H.-C. Chien, S.-Y. Lu, C.-C. Hu, Adv. Mater. 22, 347 (2010)

    Article  CAS  Google Scholar 

  45. J.-S. Wei, H. Ding, P. Zhang, Y.-F. Song, J. Chen, Y.-G. Wang, H.-M. Xiong, Small 12, 5927 (2016)

    Article  CAS  Google Scholar 

  46. S. Banerjee, K.K. Kar, High Perform. Polym. 28, 1043 (2016)

    Article  CAS  Google Scholar 

  47. G. Zhang, X. W. (David) Lou, Sci. Rep. 3, 1470 (2013)

    Google Scholar 

  48. D. Lei, X.-D. Li, M.-K. Seo, M.-S. Khil, H.-Y. Kim, B.-S. Kim, Polymer J. 132, 31 (2017)

    Article  CAS  Google Scholar 

  49. L. Zhang, Q. Ding, Y. Huang, H. Gu, Y.-E. Miao, T. Liu, A.C.S. Appl, Mater. Interfaces 7, 22669 (2015)

    Article  CAS  Google Scholar 

  50. Y. Yang, F. Yang, H. Hu, S. Lee, Y. Wang, H. Zhao, D. Zeng, B. Zhou, S. Hao, Chem. Eng. J. 307, 583 (2017)

    Article  CAS  Google Scholar 

  51. S. Abouali, M. Akbari Garakani, B. Zhang, Z.-L. Xu, E. Kamali Heidari, J. Huang, J. Huang, J.-K. Kim, ACS Appl. Mater. Interfaces 7, 13503 (2015)

    Google Scholar 

  52. R. Kumar, S. Sahoo, E. Joanni, R. K. Singh, K. Maegawa, W. K. Tan, G. Kawamura, K. K. Kar, A.Matsuda. Mater. Today (2020). https://doi.org/10.1016/j.mattod.2020.04.010

Download references

Acknowledgements

The authors acknowledge the financial support provided by the Department of Science and Technology, India (DST/TMD/MES/2K16/37(G)), for carrying out this research work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kamal K. Kar .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

De, B., Banerjee, S., Verma, K.D., Pal, T., Manna, P.K., Kar, K.K. (2020). Transition Metal Oxide/Carbon Nanofiber Composites as Electrode Materials for Supercapacitors. In: Kar, K. (eds) Handbook of Nanocomposite Supercapacitor Materials II. Springer Series in Materials Science, vol 302. Springer, Cham. https://doi.org/10.1007/978-3-030-52359-6_8

Download citation

Publish with us

Policies and ethics