Abstract
Transition metal oxide-based pseudocapacitors fundamentally involve fast charge–discharge processes due to the fast-Faradaic redox reactions occurring at the interface between the active material and electrolyte. Thus, they exhibit high specific capacity and energy density compared to electrical double-layer capacitors. However, their poor conductivity and low surface area restricted their advanced application in supercapacitors. Therefore, to improve conductivity and surface area without losing pseudocapacity, a synergistic effect of transition metal oxides and electronically conducting polymers has been recognized to design composite electrode materials for supercapacitor. The formation of transition metal oxide-conducting polymer composite electrodes can achieve better electrical conductivity and electrochemical accessibility of redox sites for high-performance supercapacitors. Therefore, this chapter provides decent and updated coverage on synthesis, structure, properties, and supercapacitor performance of conducting polymers and their composites of transition metal oxides.
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The authors acknowledge the financial support provided by the Department of Science and Technology, India (DST/TMD/MES/2K16/37(G)) for carrying out this research work.
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De, B. et al. (2020). Transition Metal Oxide/Electronically Conducting Polymer Composites as Electrode Materials for Supercapacitors. In: Kar, K. (eds) Handbook of Nanocomposite Supercapacitor Materials II. Springer Series in Materials Science, vol 302. Springer, Cham. https://doi.org/10.1007/978-3-030-52359-6_14
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