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Experimentation, Modeling, and Optimum Conditions of Pyro-Hydrometallurgical-Precipitation Reaction Technology for Recovery of Copper as Oxide of Nanoparticles from a Copper Dust

  • A. A. Adeleke
  • A. P. I. Popoola
  • O. M. Popoola
  • D. O. OkanigbeEmail author
Conference paper
Part of the The Minerals, Metals & Materials Series book series (MMMS)

Abstract

Conventionally, the leach-solvent extraction-electrowinning technology has been preferred for copper recovery from its primary and secondary sources as cathode slabs even though its recovery as copper oxide nano-particles (CuO NPs) is more preferred. Hence, this paper is aimed at presenting the production of CuO NPs from purified pregnant leach solution (PPLS) of a copper smelter dust (CSD); a by-product of primary copper ore smelting. This aim was achieved in four steps of roasting pretreatment, dissolution, precipitation reaction, and thermal decomposition. The CSD was first roasted in a muffle furnace; after which, its copper value was taken into solution via sulphuric agitation leaching using a magnetic stirrer with heater. The reduction of iron in the resultant pregnant leach solution is followed; it was achieved by optimizing the compositional proportion of H2SO4:FeSO4·7H2O. Copper precursor was then produced from the PPLS via dropwise addition of Na2CO3. The precipitate from reaction between chemical species in the PPLS and Na2CO3 served as copper precursor; this copper precursor was thermally decomposed to produce the CuO NPs. The optimum conditions for this process route are as follows: 2 h, 2 M, and 90 °C (agitation leaching); 800 °C for 2 h (oxidative roasting); 25 °C and 740 rpm (precipitation of copper precursor); 750 °C for 2 h (precipitation of copper nanoparticles). A grade of 51.30% CuO NPs was achieved from an initial 18.02% Cu content. The average crystallite size was estimated at 35 nm. The predicted outputs proportions obtained using the models were in good conformance with the experimental outputs with error margins between 0.00 and 0.07%.

Keywords

Copper dust Mathematical modeling Phase change Precipitation reaction Thermal decomposition 

Notes

Acknowledgements

The authors would like to thank the following institutions for their financial support towards the success of this paper:

1. Department of Science and Technology, Republic of South Africa

2. Council for Scientific and Industrial Research (CSIR), Pretoria, Republic of South Africa

3. National Research Foundation (NRF), Republic of South Africa.

We also extend our sincere gratitude to Palabora Copper (PTY) Ltd, Limpopo, Republic of South Africa, for providing the CSD used for this study and to Tshwane University of Technology (TUT), Pretoria for finance and facilities.

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Copyright information

© The Minerals, Metals & Materials Society 2020

Authors and Affiliations

  • A. A. Adeleke
    • 3
  • A. P. I. Popoola
    • 1
  • O. M. Popoola
    • 2
  • D. O. Okanigbe
    • 1
    Email author
  1. 1.Faculty of Engineering and the Built EnvironmentTshwane University of TechnologyPretoriaRepublic of South Africa
  2. 2.Centre for Energy and Electric Power(CEEP), Tshwane University of TechnologyPretoriaRepublic of South Africa
  3. 3.Obafemi Awolowo UniversityIfeNigeria

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