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Effect of Various Grades of Na2SiO3 on Compressive Strength Development of Eggshells Powder-Based Alkaline Activated Mortar

  • Mohamed O. M. Mashri
  • Megat Azmi Megat JohariEmail author
  • M. J. A. Mijarsh
  • Zainal Arifin Ahmad
Conference paper
Part of the Lecture Notes in Civil Engineering book series (LNCE, volume 53)

Abstract

The effect of various grades of Na2SiO3 on the compressive strength (CS) development of alkaline activated binder mortar (AABM) synthesized from eggshells powder (ESP) with curing time of up to 28 days has been investigated. Three different mixtures of AABM were synthesized from the solid material and alkaline activator solution (AAS). The solid materials consisted of source material and aggregates. ESP was used as the sole source material for the AABM. The AAS was prepared from NaOH and various grades of Na2SiO3 which was characterized by their SiO2/Na2O molar ratio of 2.064 (#1), 2.27 (#2), and 3.3 (#3), respectively. The results showed that the mixture prepared with Na2SiO3 grade #1 has a higher CS than the other two mixtures. The highest CS was 12.31 MPa at 28 days. The CS development was associated with the formation of tilleyite phase as gel binder and it is in good agreement with the XRD analysis.

Keywords

Eggshell powder Geopolymer mortar Compressive strength Silica modulus Agricultural wastes 

Notes

Acknowledgements

The authors gratefully acknowledge the Ministry of Higher Education, Malaysia and Universiti Sains Malaysia for providing financial support through the Fundamental Research Grant Scheme (203/PAWAM/6071365) and University Bridging Grant Scheme (304/PAWAM/6316313), respectively for the undertaking of the research work.

References

  1. 1.
    Abdel-Gawwad HA, Abo-El-Enein SA (2016) A novel method to produce dry geopolymer cement powder. HBRC J 12(1):13–24CrossRefGoogle Scholar
  2. 2.
    Altuntas E, Sekeroglu A (2010) Mechanical behavior and physical properties of chicken egg as affected by different egg weights. J Food Process Eng 33(1):115–127CrossRefGoogle Scholar
  3. 3.
    ASTM (2013) Standard test method for compressive strength of hydraulic cement mortars (using 2-in. or [50-mm] cube specimens). Ann Book ASTM Stand 4(1):1–9Google Scholar
  4. 4.
    ASTM (2013) Standard practice for mechanical mixing of hydraulic cement pastes and mortars of plastic consistency. American Society for Testing and MaterialsGoogle Scholar
  5. 5.
    Hincke MTY, Nys J, Gautron K, Mann AB, Rodriguez N, McKee MD (2012) The eggshell: structure, composition and mineralization. Front Biosci 17(1266):80Google Scholar
  6. 6.
    Huseien GFARM, Sam KW, Shah JM, Tahir MM (2019) Evaluation of alkali-activated mortars containing high volume waste ceramic powder and fly ash replacing GBFS. Constr Build Mater 210:78–92CrossRefGoogle Scholar
  7. 7.
    Jhatial AAWI, Goh N, Mohamad SS, Lakhiar MT (2018) Utilization of palm oil fuel ash and eggshell powder as partial cement replacement—a review. Civil Eng J 4(8):1977–1984CrossRefGoogle Scholar
  8. 8.
    Lee WKW, van Deventer JSJ (2002) The effects of inorganic salt contamination on the strength and durability of geopolymers. Colloids Surf A 211(2–3):115–126CrossRefGoogle Scholar
  9. 9.
    Lunge SD, Thakre S, Kamble NL, Rayalu S (2012) Alumina supported carbon composite material with exceptionally high defluoridation property from eggshell waste. J Hazard Mater 237:161–169CrossRefGoogle Scholar
  10. 10.
    Mijarsh M, Johari MM, Ahmad ZA (2015) Effect of delay time and Na2SiO3 concentrations on compressive strength development of geopolymer mortar synthesized from TPOFA. Constr Build Mater 86:64–74CrossRefGoogle Scholar
  11. 11.
    Mijarsh MJA, Megat Johari MA, Ahmad ZA (2015) Compressive strength of treated palm oil fuel ash based geopolymer mortar containing calcium hydroxide, aluminum hydroxide and silica fume as mineral additives. Cement Concr Compos 60:65–81CrossRefGoogle Scholar
  12. 12.
    Mohamed Rashid MR, Mijarsh MJA, Seli H, Johari MAM, Ahmad ZA (2018) Sago pith waste ash as a potential raw material for ceramic and geopolymer fabrication. J Mater Cycles Waste Manage 20(2):1090–1098CrossRefGoogle Scholar
  13. 13.
    Okonkwo U, Odiong I, Akpabio E (2012) The effects of eggshell ash on strength properties of cement-stabilized lateritic. Int J Sustain Constr Eng Technol 3(1):18–25Google Scholar
  14. 14.
    Palacios M, Alonso M, Varga C, Puertas F (2019) Influence of the alkaline solution and temperature on the rheology and reactivity of alkali-activated fly ash pastes. Cement Concr Compos 95:277–284CrossRefGoogle Scholar
  15. 15.
    Pliya P, Cree D (2015) Limestone derived eggshell powder as a replacement in Portland cement mortar. Constr Build Mater 95:1–9CrossRefGoogle Scholar
  16. 16.
    Polowczyk I, Bastrzyk A, Fiedot M (2016) Protein-mediated precipitation of calcium carbonate. Materials 9(11):944CrossRefGoogle Scholar
  17. 17.
    Post J (1995) Crystal structure of hillebrandite: a natural analogue of calcium silicate hydrate (CSH) phases in Portland cement. Am Miner 80:841–844CrossRefGoogle Scholar
  18. 18.
    Rowles M, O’connor B (2003) Chemical optimisation of the compressive strength of aluminosilicate geopolymers synthesised by sodium silicate activation of metakaolinite. J Mater Chem 13(5):1161–1165CrossRefGoogle Scholar
  19. 19.
    Shahudin MS, Ghani AAA, Zamri-Saad M, Zuki AB, Abdullah FFJ, Wahid H, Hassim HA (2018) The necessity of a heard health management programme for dairy goat farma in Malaysia. Pertanika J Trop Agric Sci 41(1):1–18Google Scholar

Copyright information

© Springer Nature Switzerland AG 2020

Authors and Affiliations

  • Mohamed O. M. Mashri
    • 1
  • Megat Azmi Megat Johari
    • 1
    Email author
  • M. J. A. Mijarsh
    • 1
    • 2
  • Zainal Arifin Ahmad
    • 3
  1. 1.School of Civil EngineeringUniversiti Sains MalaysiaPenangMalaysia
  2. 2.Civil Engineering Department, Faculty of EngineeringAl-Merghab UniversityAl-KhumsLibya
  3. 3.Structural Materials Niche Area, School of Materials and Mineral Resources EngineeringUniversiti Sains MalaysiaPenangMalaysia

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