The Iron(III) Thiocyanate Reaction pp 31-39 | Cite as
The Reaction: Chemical Affinity and Controversy
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Abstract
In 1855, the nature of a chemical reaction was still being hotly debated amongst chemists. They drew upon the concept of ‘chemical affinity’ to explain why substance A might react with substance B, but not substance C, in that A had a stronger affinity for B, than it did for C, or was more strongly attracted to B than to C.
References
- 1.Leicester HM (1971) The historical background of chemistry (Dover ed). Dover Pub Inc., New York, pp 125–129. (Originally published by Wiley, New York, 1956)Google Scholar
- 2.Gladstone JH (1855) On circumstances modifying the action of chemical affinity. Phil Trans R Soc Lond 145:179–223CrossRefGoogle Scholar
- 3.Gladstone JH (1855) On circumstances modifying the action of chemical affinity. Phil Trans R Soc Lond 145:181Google Scholar
- 4.Gladstone JH (1855) On circumstances modifying the action of chemical affinity. Phil Trans R Soc Lond 145:183Google Scholar
- 5.Perrin DD (1958) The ion Fe(CNS)2+. Its association constant and absorption spectrum. J Am Chem Soc 80(15):3852–3856CrossRefGoogle Scholar
- 6.Bjerrum J (1985) The iron(III)-thiocyanate system. The stepwise equilibria studied by measurements of the distribution of tris(thiocyanato)iron(III) between octan-2-ol and aqueous thiocyanate solutions. Acta Chem Scand A 39:327–340CrossRefGoogle Scholar
- 7.de Berg K, Maeder M, Clifford S (2016) A new approach to the equilibrium study of iron(III) thiocyanates which accounts for the kinetic instability of the complexes particularly observable under high thiocyanate concentrations. Inorg Chim Acta 445:155–159CrossRefGoogle Scholar
- 8.Hill ZD, MacCarthy P (1986) Novel approach to Job’s method. J Chem Educ 63(2):162–167Google Scholar
- 9.Najib FM, Hayder OI (2011) Study of stoichiometry of ferric thiocyanate complex for analytical purposes including F− determination. Iraqi Nat J Chem 42:135–155Google Scholar
- 10.Sultan SM, Bishop E (1982) A study of the formation and stability of the iron(III)-thiocyanate complex in acidic media. Analyst 107:1060–1064CrossRefGoogle Scholar
- 11.Ghirardi M, Marchetti F, Pettinari C, Regis A, Roletto E (2014) A teaching learning sequence for learning the concept of chemical equilibrium in secondary school education. J Chem Educ 91(1):59–65CrossRefGoogle Scholar
- 12.Gladstone JH (1855) On circumstances modifying the action of chemical affinity. Phil Trans R Soc Lond 145:185Google Scholar
- 13.Holmes FL (1962) From elective affinities to chemical equilibria: Berthollet’s law of mass action. Chymia 8:105–145, 109CrossRefGoogle Scholar
- 14.Holmes FL (1962) From elective affinities to chemical equilibria: Berthollet’s law of mass action. Chymia 8:105–145, 110CrossRefGoogle Scholar
- 15.Fowles G (1937) Lecture experiments in chemistry. G. Bell & Sons Ltd., LondonGoogle Scholar
- 16.Driscoll DR (1979) Invitation to enquiry: the Fe3+/CNS− equilibrium. J Chem Educ 56(9):603CrossRefGoogle Scholar
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