Advertisement

In Conclusion: Brief Summary of New vs Existing Paradigm of Spin Exchange

  • Kev M. Salikhov
Chapter

Abstract

The differences between the existing and new paradigms in three projections are briefly formulated: In calculations of the efficiency of spin exchange in one elementary act; In the manifestations of the transfer of spin coherence in the form of EPR spectra; The protocol for determining the spin exchange rate from EPR spectroscopy data.

References

  1. 1.
    Kivelson, D.: Theory of ESR line widths of free radicals. J. Chem. Phys. 33, 1094–1106 (1960)ADSCrossRefGoogle Scholar
  2. 2.
    Currin, J.D.: Theory of exchange relaxation of hyperfine structure in electron spin resonance. Phys. Rev. 126, 1995–2001 (1962)ADSCrossRefGoogle Scholar
  3. 3.
    Salikhov, K.M.: The contribution from exchange interaction to the line shifts in ESR spectra of paramagnetic particles in solutions. J. Magn. Res. 63, 271–279 (1985)ADSGoogle Scholar
  4. 4.
    Bales, B.L., Peric, M.: EPR line shifts and line shape changes due to spin exchange of nitroxide free radicals in liquids. J. Phys. Chem. B. 101, 8707–8716 (1997)CrossRefGoogle Scholar
  5. 5.
    Bales, B.L., Meyer, M., Smith, S., Peric, M.: EPR line shifts and line shape changes due to spin exchange of nitroxide free radicals in liquids 4. Test of a method to measure re-encounter rates in liquids employing 15N and 14N nitroxide spin probes. J. Phys. Chem. A. 112, 2177–2181 (2008)CrossRefGoogle Scholar
  6. 6.
    Kurban, M.R., Peric, M., Bales, B.L.: Nitroxide spin exchange due to re-encounter collisions in a series of n-alkanes. J. Chem. Phys. 129, 064501 (2008)ADSCrossRefGoogle Scholar
  7. 7.
    Zamaraev, К.I., Molin, Y.N., Salikhov, К.М.: Spin exchange. Nauka, Sibirian branch, Novosibirsk (1977)Google Scholar
  8. 8.
    Molin, Y.N., Salikhov, K.M., Zamaraev, K.I.: Spin exchange. Principles and applications in chemistry and biology. Springer, Heidelberg/Berlin (1980)Google Scholar
  9. 9.
    Salikhov, K.M.: Consistent paradigm of the spectra decomposition into independent resonance lines. Appl. Magn. Reson. 47, 1207–1228 (2016)CrossRefGoogle Scholar
  10. 10.
    Salikhov, K.M.: Peculiar features of the spectrum saturation effect when the spectral diffusion operates: system with two frequencies. Appl. Magn. Reson. 49, 1417–1430 (2018)CrossRefGoogle Scholar
  11. 11.
    Abragam, A.: The principles of nuclear magnetism. Clarendon Press, Oxford (1961)Google Scholar
  12. 12.
    Salikhov, К.М., Semenov, A.G., Tsvetkov, Y.D.: Electron spin echo and its application. Nauka, Siberian branch, Novosibirsk (1976)Google Scholar
  13. 13.
    Bales, B.L., Meyer, M., Smith, S., Peric, M.: EPR line shifts and line shape changes due to spin exchange of nitroxide free radicals in liquids 6: Separating line broadenning due to spin exchange and dipolar interactions. J. Phys. Chem. A. 113, 4930–4940 (2009)CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • Kev M. Salikhov
    • 1
  1. 1.Zavoisky Physical-Technical Institute of Russian Academy of SciencesKazanRussia

Personalised recommendations