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Metal Surface Engineering Based on Formation of Nanoscaled Phase Protective Layers

  • V. M. Ledovskykh
  • Yu. P. Vyshnevska
  • I. V. Brazhnyk
  • S. V. Levchenko
Conference paper
Part of the Springer Proceedings in Physics book series (SPPHY, volume 221)

Abstract

The processes of formation of phase protective layers in the presence of numerous individual inhibitors and their mixtures have been investigated. The results of characterization of the protective films for determining the influence of the concentration ratio of the mixture components and the deposition conditions on the distribution of elemental composition within layer thickness using Auger spectroscopy with ion etching have been presented. The influence of the metal potential and pH on the mechanism of action and the efficiency of the individual additives and their compositions has been determined. It was shown that the most dense nanoscale phase layers that ensure highest protective efficiency may be formed using synergistic mixtures of inhibitors with different mechanisms of action.

Keywords

Surface engineering Nanocoatings Phase layers Synergistic mixtures Ion etching 

References

  1. 1.
    Rozenfeld IL (1977) Corrosion Inhibitors. Khimiya, MoscowGoogle Scholar
  2. 2.
    Antropov LI, Makushin EM, Panasenko VF (1981) Inhibitors of the corrosion of metals. Tekhnika, KievGoogle Scholar
  3. 3.
    Tzaneva B (2013) Effect of pH on the corrosion behaviour of high nitrogen stainless steel in chloride medium. J Chem Technol Metall 48(4):383–390Google Scholar
  4. 4.
    Cui J, Yuan W, Yuan D, Pei Y (2017) Effect of pH on the passivation of carbon steel by sodium borosilicate controlled-release inhibitor in simulated recirculating cooling water. Ind Eng Chem Res 56(25):7239–7252.  https://doi.org/10.1021/acs.iecr.7b01433 CrossRefGoogle Scholar
  5. 5.
    Hussain RR (2014) Passive layer development and corrosion of steel in concrete at the nano-scale. J Civil Environ Eng 4:e116.  https://doi.org/10.4172/2165-784X.1000e116 CrossRefGoogle Scholar
  6. 6.
    Ledovskykh VM, Vyshnevska YP, Brazhnyk IV, Levchenko SV (2017) Metal surface modification for obtaining nano- and sub-nanostructured protective layers. Nanoscale Res Lett 12:186–191.  https://doi.org/10.1186/s11671-017-1964-5 ADSCrossRefGoogle Scholar
  7. 7.
    Ledovs’kykh VM, Vyshnevs’ka YP, Brazhnyk IV, Levchenko SV (2017) Development and optimization of synergistic compositions for the corrosion protection of steel in neutral and acid media. Mater Sci 52(5):634–642.  https://doi.org/10.1007/s11003-017-0002-1 CrossRefGoogle Scholar
  8. 8.
    Ledovskikh VM (1983) Synergetic inhibition of steel corrosion in neutral media by nitrogenous organic alkalis with sodium nitrite. Prot Met 19(1):84–91Google Scholar
  9. 9.
    Min J, Park JH, Sohn H-K, Park JM (2012) Synergistic effect of potassium metal siliconate on silicate conversion coating for corrosion protection of galvanized steel. J Ind Eng Chem 18(2):655–660.  https://doi.org/10.1016/j.jiec.2011.11.057 CrossRefGoogle Scholar
  10. 10.
    Truc AT, Pébère N, Xuan Hang T, Hervaud Y, Boutevin B (2002) Study of the synergistic effect observed for the corrosion protection of a carbon steel by an association of phosphates. Corros Sci 44:2055–2071.  https://doi.org/10.1016/S0010-938X(02)00013-6 CrossRefGoogle Scholar
  11. 11.
    Pourbaix M (1974) Atlas of electrochemical equilibria in aqueous solutions. National Association of Corrosion Engineers, Houston, p 551Google Scholar
  12. 12.
    Ledovs’kykh VM, Levchenko SV, Tulainov SM (2013) Synergistic extrema of the mixtures of corrosion inhibitors for metals in aqueous salt solutions. Mater Sci 49(6):827–832.  https://doi.org/10.1007/s11003-014-9680-0 CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • V. M. Ledovskykh
    • 1
  • Yu. P. Vyshnevska
    • 2
    • 3
  • I. V. Brazhnyk
    • 4
  • S. V. Levchenko
    • 1
  1. 1.National Aviation UniversityKyivUkraine
  2. 2.National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”KyivUkraine
  3. 3.Institute for Renewable Energy NAS of UkraineKyivUkraine
  4. 4.Gimasi SA Ukraine R&D Centre, Via Luigi LavizzariMendrisioSwitzerland

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