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Dissolution of Sapphire and Alumina–Magnesia Particles in CaO–SiO2–Al2O3 Liquid Slags

  • Hamed Abdeyazdan
  • Neslihan DoganEmail author
  • Raymond J. Longbottom
  • M. Akbar Rhamdhani
  • Michael W. Chapman
  • Brian J. Monaghan
Conference paper
Part of the The Minerals, Metals & Materials Series book series (MMMS)

Abstract

Understanding the dissolution kinetics of non-metallic inclusions in liquid slag is key in optimization of slag composition for inclusion removal. In this study, the rate of dissolution of high-precision spheres of sapphire and alumina–magnesia particles in CaO–SiO2–Al2O3 liquid slags was measured in situ using a laser scanning confocal microscope at 1500 °C. It was found that the rate of dissolution of both sapphire and alumina–magnesia particles increased when the slag basicity is increased. A layer was observed around the dissolving sapphire. This layer may be a product layer and/or indicative of a mass transfer rate-controlling system. In the case of alumina–magnesia particle, the kinetics appeared more complex and depended on slag composition. No product layer or mass transfer layer was observed around the particle dissolving in slag with low basicity, whereas for the high basicity slag, a product or stagnant layer was observed, similar to that of the sapphire particle. Assuming a mass transfer-controlled system, measured diffusion coefficients for sapphire particles in slags tested in this study ranged from 10−11 to 10−10 m2 s−1 at 1500 °C.

Keywords

Dissolution kinetics Inclusion removal Slag Inclusions Clean steel 

Notes

Acknowledgements

The authors acknowledge the support of BlueScope and the use of the Australian Research Council funded JEOL-JSM 6490 LV SEM at the UOW Electron Microscopy Centre.

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Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  • Hamed Abdeyazdan
    • 1
  • Neslihan Dogan
    • 3
    Email author
  • Raymond J. Longbottom
    • 1
  • M. Akbar Rhamdhani
    • 2
  • Michael W. Chapman
    • 4
  • Brian J. Monaghan
    • 1
  1. 1.PYROmetallurgical Research Group, School of Mechanical, Materials, Mechatronic and Biomedical EngineeringUniversity of WollongongWollongongAustralia
  2. 2.Department of Mechanical and Product Design EngineeringSwinburne University of TechnologyHawthornAustralia
  3. 3.Department of Materials Science and EngineeringMcMaster UniversityHamiltonCanada
  4. 4.BlueScope LtdPort KemblaAustralia

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