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Chemical Metallization of Insulating Polymeric Surfaces Through Simple Diazonium-Based Covalent Amination

  • Viet Anh Ly
  • Ngoc Pi Vu
  • Duy Cuong Nguyen
  • Xuan Truong Duong
  • Gul Zeb
  • Xuan Tuan LeEmail author
Conference paper
Part of the Lecture Notes in Networks and Systems book series (LNNS, volume 63)

Abstract

Electroless plating or autocatalytic deposition on insulating polymeric substrates via surface amination is currently of potential interest since the grafted amine functionalities significantly decrease the total quantity of noble metal catalyst and offer good adhesion between the polymer substrate and the deposited film. Among various wet-chemical amination strategies available in the literature, diazonium-induced anchoring process appears to be very promising due to many advantages: one-step aqueous chemical process, provides covalent grafting of amine-terminated groups, carried out in open air and at room temperature. This work covers our recent studies on the grafting of aminophenyl and vinylpyridine groups through diazonium chemistry onto various polymers. We discuss the ability of these amine-terminated functionalities towards the chemisorption of acidic palladium chloride activators, which subsequently initiate autocatalytic deposition process. Our studied polymers functionalized with these palladium complexes perfectly suit the subsequent electroless nickel plating process. The covalently grafted amine groups provide excellent adhesion of the deposited nickel film on polymers. SEM, AFM, EDX and XPS techniques are used to characterize the electrolessly deposited metallic film.

Keywords

Diazonium chemistry Covalent amination Green chemistry Palladium activation Autocatalytic deposition 

Notes

Acknowledgement

The authors wish to thank Thai Nguyen University of Technology (Vietnam) and MiQro Innovation Collaborative Centre (Canada) for technical support and financial assistance.

References

  1. 1.
    Zeb, G., Duong, X.T., Vu, N.P., Phan, Q.T., Nguyen, D.T., Ly, V.A., Salimy, S., Le, X.T.: Chemical metallization of KMPR photoresist polymer in aqueous solutions. Appl. Surf. Sci. 407, 518–525 (2017)CrossRefGoogle Scholar
  2. 2.
    Vu, N.P., Duong, X.T., Ly, V.A., Nguyen, D.C., Tran, M.D., Phan, Q.T., Balazinski, M., Son, L.T., Zeb, G., Le, X.T.: Electroless nickel plating onto Plexiglas® through simple covalent grafting of vinylpyridine seed layer. Mater. Des. 144, 151–158 (2018)CrossRefGoogle Scholar
  3. 3.
    Wang, M.Q., Yan, J., Du, S.G., Li, H.G.: Electroless plating of PVC plastic through new surface modification method applying a semi-IPN hydrogel film. Appl. Surf. Sci. 277, 249–256 (2013)CrossRefGoogle Scholar
  4. 4.
    Schaubroecka, D., Mader, L., Dubruel, P., Vanfleteren, J.: Surface modification of an epoxy resin with polyamines and polydopamine: adhesion toward electroless deposited copper. Appl. Surf. Sci. 353, 238–244 (2015)CrossRefGoogle Scholar
  5. 5.
    Shao, Q.S., Bai, R.C., Tang, Z.Y., Gao, Y.F., Sun, J.L., Ren, M.S.: Durable electroless Ni and Ni-P-B plating on aromatic polysulfonamide (PSA) fibers with different performances via chlorine-aided silver activation strategy. Surf. Coat. Technol. 302, 185–194 (2016)CrossRefGoogle Scholar
  6. 6.
    Klages, C.-P., Hinze, A., Willich, P., Thomas, M.: Atmospheric-pressure plasma amination of polymer surfaces. J. Adhes. Sci. Technol. 24, 1167–1180 (2010)CrossRefGoogle Scholar
  7. 7.
    Bradley, T.J., Schofield, W.C.E., Garrod, R.P., Badyal, J.P.S.: Electroless metallization onto pulsed plasma deposited poly (4-vinylpyridine) surfaces. Langmuir 22(18), 7552–7555 (2006)CrossRefGoogle Scholar
  8. 8.
    Le, X.T., Poirier, J.-S., Michel, S.: Completely aqueous route for metallization of structural polymeric materials in micro-electro-mechanical systems. J. Electrochem. Soc., under reviewGoogle Scholar
  9. 9.
    Zeb, G., Zafar, M., Palacin, S., Le, X.T.: An application of diazonium-induced anchoring process in the fabrication of micro-electro-mechanical systems. Adv. Mater. Technol. 2(12), 1700159 (2017)CrossRefGoogle Scholar
  10. 10.
    Le, X.T., Viel, P., Sorin, A., Jegou, P., Palacin, S.: Electrochemical behaviour of polyacrylic acid coated gold electrodes: an application to remove heavy metal ions from wastewater. Electrochim. Acta 54(25), 6089–6093 (2009)CrossRefGoogle Scholar
  11. 11.
    Vitry, V., Bonin, L.: Increase of boron content in electroless nickel-boron coating by modification of plating conditions. Surf. Coat. Technol. 311, 164–171 (2017)CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  1. 1.Research International GroupThai Nguyen University of TechnologyThai NguyenVietnam
  2. 2.Department of Mechanical EngineeringEcole polytechnique de MontréalMontréalCanada
  3. 3.iCantech Innovation Inc.GranbyCanada
  4. 4.MiQro Innovation Collaborative Centre (C2MI)BromontCanada

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