X-Ray Spectroscopy in Forensic Medicine-Metal Poisoning

  • D. F. Craston
Part of the Progress in Analytical Chemistry book series (PAC)

Abstract

X-ray spectrographic analysis is a very useful method for evaluation of certain element concentrations in biological tissues for purposes of clinical and toxicological investigation. The organic matrix prevents presentation of samples for analysis in their natural state; but after suitable isolation and in some cases preconcentration data of high accuracy and reproducibility are obtained with X-ray spectroscopy.

Methodology appropriate for clinical and toxicologic analysis with emphasis on metal poisonings will be presented, compared with other available methods and critically evaluated. The use of X-ray diffraction in forensic medicine and criminology will be discussed and documented with cases.

Keywords

Organic Matrix Barium Sulfate Metal Poisoning Acta Radio Toxicological Investigation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    A. Engstrom, Quantitative Microchemical and Histochemical Analysis of Elements by X-rays, Nature 158, 664 (1946).CrossRefGoogle Scholar
  2. 2.
    A. Engstrom, Microradiography in Biological and Medical Research, Medica Mundi 1, 119 (1955).Google Scholar
  3. 3.
    R. Amprino, and A. Engstrom, Studies on X-ray Absorption and Diffraction of Bone Tissue, Acta Anat. 15, 1 (1952).CrossRefGoogle Scholar
  4. 4.
    C. Lagergren, Biophysical Investigations of Urinary Calculi: An X-ray Crystallographic and Microradiographic study, Thesis, Acta Radiol., Suppl. 133 (1956).Google Scholar
  5. 5.
    K. A. Omnell, B. Lindstrom, F. C. Hoh, and E. Hammerlund-Essler, Method for Non-destructive Determination of Inorganic and Organic Material in Mineralized Tissues, Acta Radiol. 54, 209 (1960).CrossRefGoogle Scholar
  6. 6.
    A. Engstrom, and B. Lindstrom, A.Method for the Determination of the Mass of Extremely Small Biological Objects, Biochim. Biophys. Acta 4, 351 (1950).CrossRefGoogle Scholar
  7. 7.
    F. C. Hoh, and B. Lindstrom, On the Theory of Quantitative Microradiography in Biology, J. Ultrastructure Research 2, 512 (1959).CrossRefGoogle Scholar
  8. 8.
    B. Lindstrom, Roentgen Absorption Spectrophotometry in Quantitative Cytochemistry, Acta Radiol., Suppl 125 (1955).Google Scholar
  9. 9.
    A. Engstrom, Quantitative Micro-and Histochemical Elementary Analysis by Roentgen Absorption Spectrography, Thesis, Acta Radiol., Suppl. 63 (1946).Google Scholar
  10. 10.
    A. Engstrom, and J. B. Finean, Micro X-ray Diffraction in Histochemistry, Exptl. Cell Research 4, 484 (1953).CrossRefGoogle Scholar
  11. 11.
    V. E. Cosslett, A. Engstrom, and H. H. Pattee, X-Ray Microscopy and Microradiography, Academic Press, New York (1957).Google Scholar
  12. 12.
    A. Engstrom, V. E. Cosslett, and H. H. Pattee, X-Ray Microscopy and X-Ray Microanalysis, Elsevier Publishing Co., Amsterdam (1960).Google Scholar
  13. 13.
    H. H. Pattee, V. E. Cosslett, and A. Engstrom, X-Ray Optics and X-Ray Microanalysis, Academic Press, New York (1963).Google Scholar
  14. 14.
    L. S. Birks, X-Ray Spectrochemical Analysis, Interscience Publishers, Inc., New York (1959).Google Scholar
  15. 15.
    G. L. Clark, The Encyclopedia of Spectroscopy, Reinhold Publishing Corp., New York (1960).Google Scholar
  16. 16.
    H. A. Liebhafsky, H. G. Pfeiffer, E. H. Winslow, and P. D. Zemany, X-Ray Absorption and Emission in Analytical Chemistry, John Wiley and Sons, Inc., New York (1960).Google Scholar
  17. 17.
    G. H. Morrison, Trace Analysis (Physical Methods), Interscience Publishers, Inc., New York (1965).Google Scholar
  18. 18.
    E. Jackwerth, and H. G. Kloppenburg “Untersuchungen zur quantitativen Auwsertung von Papierchromatogrammen in der Spurenanalyse durch Roent-genfluoroescenzspectroskopie,” reprinted from Anal Chem. 179(3), 186 (1961).CrossRefGoogle Scholar
  19. 19.
    J. Cholak, and D. M. Hubbard, Determination of Manganese in Air and Biological Material, Reprinted from Am. Ind. Hyg. Assoc., Vol. 21, No. 5 (Oct. 1960).Google Scholar
  20. 20.
    J. C. Mathies, and P. K. Lund, X-Ray Spectroscopy in Biology and Medicine—III. Bromide (Total Bromine) in Human Blood Serum, Urine and Tissues, Reprinted from the Norelco Reporter, Vol. VII, No. 5 (Sept.-Oct. 1960).Google Scholar

Copyright information

© Springer Science+Business Media New York 1969

Authors and Affiliations

  • D. F. Craston
    • 1
    • 2
  1. 1.Office of Chief Medical ExaminerNew York CityUSA
  2. 2.Department of Forensic MedicineNew York University, School of MedicineUSA

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