Gap States in Phosphorus-Doped a-Si:H

  • Kazunobu Tanaka
  • Hideyo Okushi
  • Satoshi Yamasaki
Part of the Institute for Amorphous Studies Series book series (IASS)

Abstract

The density-of-state distribution of gap states and their relevant defect structures in phosphorus-doped a-Si:H have been investigated by ICTS (isothermal capacitance transient spectroscopy), PAS (photoacoustic spectroscopy) and ESR measurements. Two broad peaks are observed in the gap-state profile; D at 0. 52 eV below Ec, and *D (D coupled with P+ 4) at 0.6–0.8 eV above Ev. ESR hyperfine spectra of the specimen deposited at room temperature suggest the existence of deep unpaired-spin centers coupled with P nuclei. Photo-induced effect is discussed in terms of *D-D transformation and P-Si weak bond formation.

Keywords

Doping Level Amorphous Silicon Capture Cross Section Deep Level Transient Spectroscopy Dangling Bond 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    R. A. Street and N. F. Mott, States in the gap in glassy semiconductors, Phys. Rev. Lett. 35: 1293 (1975).CrossRefGoogle Scholar
  2. 2.
    M. Kastner, D. Adler and H. Fritzsche, Valence-alternation model for localized gap states in lone-pair semiconductors, Phys. Rev. Lett. 37: 1504 (1976).CrossRefGoogle Scholar
  3. 3.
    J. C. Phillips, Topology of covalent non-crystalline solids I:short-range order in chalcogenide alloys, J. Non-Cryst. Solids 39: 153 (1979).CrossRefGoogle Scholar
  4. 4.
    D. L. Staebler and C. R. Wronski, Reversible conductivity change in discharge-produced amorphous Sir Appl. Phys. Lett. 31: 292 (1977).Google Scholar
  5. 5.
    M. H. Tanielian, N. B. Goodman and H. Fritzsche, Photo-creation of defects in plasma-deposited a-Si:H, J. de Phys. suppl. 42: C4–375 (1981).Google Scholar
  6. 6.
    H. Okushi, T. Takahama, Y. Tokumaru, S. Yamasaki, H. Oheda and K. Tanaka, Temperature dependence of electron capture cross section of localized state in a-Si:H, Phys. Rev. B27: 5184 (1983).CrossRefGoogle Scholar
  7. 7.
    H. Okushi, A study of gap states in P-doped amorphous silicon by ICTS, Philos. Mag. (1985)(in press).Google Scholar
  8. 8.
    K. Tanaka and H. Okushi, Defect states and carrier capture processes in a-Si:H, J. Non-Cryst. Solids 66: 205 (1984).CrossRefGoogle Scholar
  9. 9.
    H. Okushi, M. Itoh. T. Okuno, Y. Hosokawa, S. Yamasaki and K. Tanaka, Gap states dynamics observed in light soaked P-doped a-Si:H, in AIP Conf. Proc. NO. 120 “Optical effects in amorphous semiconductors”, P. C. Taylor and D. G. Bishop, ed., A. I. P. New York (1984).Google Scholar
  10. 10.
    S. Yamasaki, H. Okushi, A. Matsuda, H. Oheda, N. Hata and K. Tanaka, Determination of optical constants of thin films using photoacoustic spectroscopy, J. J. Appl. Phys. 20: L665 (1981).CrossRefGoogle Scholar
  11. 11.
    K. Tanaka and S. Yamasaki, PAS study of gap-state profiles of P-doped and undoped a-Si:H, Solar Energy Materials 8: 277 (1982).CrossRefGoogle Scholar
  12. 12.
    D. V. Lang. J. D. Cohen and J. P. Harbison, Measurement of the density of gap states in hydrogenated amorphous silicon by space charge spectroscopy, Phys. Rev. B25: 5285 (1982).CrossRefGoogle Scholar
  13. 13.
    J. D. Cohen, J. P. Harbison and K. W. Wecht, Identification of the dangling-bond state within the mobility gap of a-Si:H by depletion-width modulated ESR spectroscopy, Phys. Rev. Lett. 48: 109 (1982).CrossRefGoogle Scholar
  14. 14.
    N. M. Johnson, Measurement of deep levels in hydrogenated amorphous silicon by transient voltage spectroscopy, J. Appl. Phys. 51: 327 (1983).Google Scholar
  15. 15.
    K. Morigaki, Y. Sano and I. Hirabayashi, Radiative and nonradiative recombination processes in hydrogenated amorphous silicon as elucidated by optically detected magnetic resonance, Solid State Commun. 39: 947 (1981).CrossRefGoogle Scholar
  16. 16.
    H. Oheda, S. Yamasaki, T. Yoshida, A. Matsuda, H. Okushi and K. Tanaka, Gap states distribution of undoped a-Si:H determined with phase-shift analysis of the modulated photocurrent, J. J. Appl. Phys. 21: L440 (1982).CrossRefGoogle Scholar
  17. 17.
    W. E. Spear, H. L. Steemers, P. G. LeComber and R. A. Gibson, Majority and minority carrier lifetimes in doped a-Si junctions and the energy of the dangling-bond state, Philos. Mag. B50: L33 (1984).Google Scholar
  18. 18.
    R. A. Street, Doping and Fermi energy in amorphous silicon, Phys. Rev. Lett. 49: 1187 (1982).CrossRefGoogle Scholar
  19. 19.
    R. A. Street. D. K. Biegelsen and J. C. Knights, Defect states in doped and compensated a-Si:H, Phys. Rev. B24: 969 (1981).CrossRefGoogle Scholar
  20. 20.
    B. von Roedern, L. Ley, M. Cardona and F. W. Smith, Photoemission studies on in situ prepared hydrogenated amorphous silicon films, Philos. Mag. 40: 433 (1979).Google Scholar
  21. 21.
    M. Stutzmann and J. Stuke, New paramagnetic states in amorphous silicon and germanium, J. Non-Cryst. Solids 66: 145 (1984).CrossRefGoogle Scholar
  22. 22.
    I. Hirabayashi, K. Morigaki, S. Yamasaki and K. Tanaka, Photoinduced absorption and photoinduced absorption-detected ESR, in Ref. 9.Google Scholar
  23. 23.
    M. Stutzmann and R. A. Street (to be published).Google Scholar
  24. 24.
    N. Ishii, M. Kumeda and T. Shimizu, P-related defects in P-doped a-Si:H, Solid State Commun. (1985)(in press).Google Scholar
  25. 25.
    J. Robertson, Unified theory of bonding at defects and dopants in amorphous semiconductors, in Ref. 9.Google Scholar
  26. 26.
    D. Adler, Density of states in the gap of tetrahedrally bonded amorphous semiconductors, Phys. Rev. Lett. 41: 1755 (1978).CrossRefGoogle Scholar
  27. 27.
    C. C. Tsai, J. C. Knights and M. J. Thompson, ‘Clean’ a-Si:H prepared in a UHV system, J. Non-Cryst. Solids 66: 45 (1984).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1985

Authors and Affiliations

  • Kazunobu Tanaka
    • 1
  • Hideyo Okushi
    • 1
  • Satoshi Yamasaki
    • 1
  1. 1.Electrotechnical LaboratoryIbarakiJapan

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