Mass Transfer of Stainless Steel in Pumped Sodium Loops and its Effect on Microstructure
Abstract
In the operation of sodium cooled reactors the mass transfer behaviour of corrosion products requires consideration from the standpoint of maintenance procedures if one is dealing with activated constituents from stainless steel fuel cladding (1,2,3), and also from the thermal hydraulic standpoint if in addition we are dealing with spalled oxides, entrained metal swarf or fragments from pipework surfaces. The paper highlights, using suitable photomicrographs, the type of corrosion which can occur in various parts of a loop and the form of the corrosion products which can collect in the circuit when the loops are operated with sodium containing 10 and 25 ppm oxygen. It also indicates how difficult it is to achieve a mass balance in sodium loops when the stainless steel pipework adds significantly to the corrosion product burden in the system.
Keywords
Corrosion Product Sigma Phase Downstream Position Corrosion Zone Sodium FerratePreview
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References
- 1.W. F. Brehm, J. C. McGuire, R. P. Colburn, H. P. Mafei, W. H. Olsen, 2nd Int.Conf.on Liquid Metal Technology in Energy Production, Richland, Washington, April 1980.Google Scholar
- 2.G. Menken, U. Quandt, J. Ebbernik, 2nd Int.Conf.on Liquid Metal Technology in Energy Production, Richland, Washington, April 1980.Google Scholar
- 3.I. H. Newson, K. T. Claxton, R. W. Dawson, P. Hawtin, 2nd Int.Conf.on Liquid Metal Technology in Energy Production, Richland, Washington, April 1980.Google Scholar
- 4.A. W. Thorley, A. C. Raine, The Alkali Metals. Special Publication No. 22, The Chemical Society, 1967.Google Scholar
- 5.P. Roy, D. Dutina, Section 3 GEAP 10394.Google Scholar
- 6.S. A. Shiels, C. Bagnall, A. R. Keeton, R. F. Witkowski, R. P. Anantatmula, 2nd Int.Conf.on Liquid Metal Technology in Energy Production, Richland, Washington, April 1980.Google Scholar
- 7.H. U. Borgstedt, 2nd Int.Conf.on Liquid Metal Technology in Energy Production, Richland, Washington, April 1980.Google Scholar
- 8.B. H. Kolster, 2nd Int.Conf.on Liquid Metal Technology in Energy Production, Richland, Washington, April 1980.Google Scholar
- 9.C. S. Campbell, M. W. J. Lewis, 2nd Int.Conf.on Liquid Metal Technology in Energy Production, Richland, Washington, April 1980.Google Scholar
- 10.P. Gross, G. L. Wilson, Jnl.Chem.Soc.(A) 1970, p. 1913.Google Scholar
- 11.A. W. Thorley, J. A. Bardsley, Proceedings of Royal Microscopical Society, Vol. 1, Pt. 3, 448 (1966).Google Scholar
- 12.A. W. Thorley, C. Tyzack, A. Blundell, A. C. Raine, 2nd Int.Conf.on Liquid Metal Technology in Energy Production, Richland, Washington, April 1980.Google Scholar
- 13.A. W. Thorley, C. Tyzack, B. Longson, A. C. Raine, Int. Conf.on Liquid Metal Technology in Energy Production, Champion, Pennsylvania, April 1976.Google Scholar