Interfacially Controlled Phenomena in the System K2CO3-KA1O2
Abstract
Potassium carbonate has become of special interest to a number of ceramists because of its use as ionizing seed material which is added to combustion gases to produce a conductive plasma in magneto-hydrodynamic electrical power generators. In this high temperature environment, chemical interaction occurs not only with ceramic components of the system such as electrodes and insulators, but also with the mineral ash of the coal used to fuel the generator. As a result, potassium aluminate is an important component of the slags accummulating in such generators [1–3]. The system K2CO3-KA1O2 is under investigation as part of a more general study of potassium carbonate — slag interaction. This note is a summary of some preliminary observations on the phase equilibria of K2CO3-KA1O2 with focus on the unusual melting behavior of K2CO3/KA1O2 mixtures, which appears to have its origin in interfacial interaction.
Keywords
Potassium Carbonate Powder Pattern JANAF Thermochemical Table Extra Line Potassium AluminatePreview
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References
- 1.E. R. Plante and L. P. Cook, Proc. 17th Symp. Eng. Aspects Magnetohydrodynamic Electrical Power Generation, Stanford, C.1.1. (1978).Google Scholar
- 2.L. P. Cook, 7th Int. Conf. on Magnetohydrodynamic Electrical Power Generation, Cambridge, Mass., V. 1, 212 (1980).Google Scholar
- 3.L. P. Cook, R. S. Roth, H. S. Parker, and T. Negas, Am. Mineral., 62 1180 (1977).Google Scholar
- 4.D. K. Smith, Norelco Reporter, 10 19 (1963).Google Scholar
- 5.A. Bon, C. Gleitzer, A. Courtois and J. Protas, C. R. Acad. Sci. Paris, 278C 785 (1974).Google Scholar
- 6.JANAF Thermochemical Tables, 2nd Ed., NSRDS-NBS 37, U.S. Dept. Commerce (1971).Google Scholar
- 7.R. S. Roth, Advances In Chemistry Series, Amer. Chem. Soc, Washington, D.C. (in press).Google Scholar
- 8.F. E. Spencer, J. C. Hendrie, Jr., and D. Bienstock, 6th Int. Conf. on Magnetohydrodynamic Electrical Power Generation, Washington, D.C., V. 2, 181 (1975).Google Scholar
- 9.C. L. McDaniel, Nat. Bur. Stand., pers. comm. (1980).Google Scholar
- 10.E. R. Plante, Nat. Bur. Stand., pers. comm. (1980).Google Scholar
- 11.P. M. deWolff, File No. 16-280, JCPDS Int. Centre for Diff. Data, Swarthmore, Pa.Google Scholar
- 12.S. J. Schneider and E. M. Levin, J. Amer. Ceram. Soc, 56 218 (1973).CrossRefGoogle Scholar
- 13.P. G. de Gennes, The Physics of Liquid Crystals, Oxford Univ. Press, London (1974).Google Scholar
- 14.B. Dickens and L. W. Schroeder, Nat. Bur. Stand. Tech. Note 893, 71 p. (1976).Google Scholar
- 15.G. C. Dubbeldam and P. M. deWolff, Acta Cryst., B25 2665 (1969).Google Scholar
- 16.M. O’Keeffe and B. G. Hyde, Trans. Amer. Crystallog. Assoc, 115 65 (1979).Google Scholar