Characteristics of Emulsion Polymerization and Copolymerization of Polar Monomers

  • V. I. Eliseeva
  • S. S. Ivanchev
  • S. I. Kuchanov
  • A. V. Lebedev
Chapter

Abstract

The quantitative theory of emulsion polymerization presented in Chapter 2 was formulated during mathematical examination of a model of the process which did not take into consideration molecular interaction at the interface. It is apparent that during polymerization in an aqueous medium this factor has greater significance the more polar the monomer. This interaction influences such important polymerization parameters as particle interaction, true and colloidal solubility of the monomer, emulsifier adsorption, equilibrium concentration of the monomer in particles, etc. The significant difference of these parameters during polymerization between polar and hydrophobic monomers should lead to significant changes in the mechanism of particle formation, in the kinetics of the process, and in the colloidal behavior of the latex systems formed.

Keywords

Emulsion Polymerization Latex Particle Sodium Lauryl Sulfate Vinyl Acetate Butyl Acrylate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Consultants Bureau, New York 1981

Authors and Affiliations

  • V. I. Eliseeva
  • S. S. Ivanchev
  • S. I. Kuchanov
  • A. V. Lebedev

There are no affiliations available

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