NMR Studies of Electrolyte Solutions

  • E. von Goldammer
Chapter
Part of the Modern Aspects of Electrochemistry book series (MAOE, volume 10)

Abstract

In recent years, nuclear magnetic resonance spectroscopy has been applied to the study of interactions in solution with profitable results. This has been especially the case with studies of ionic hydra­tion in electrolyte solutions where magnetic resonance and relaxa­tion techniques have been used. In this chapter, the basis of, and recent results obtained from, this approach are described.

Keywords

Relaxation Rate Electrolyte Solution Electric Field Gradient Spin Relaxation Rotational Diffusion 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References

  1. 1.
    A. G. Redfield, in Advances in Magnetic Resonance, Ed. by J. S. Waugh, Academic Press, New York, 1965, Vol. 1, p. 1.Google Scholar
  2. 2.
    J. M. Deutch and I. Oppenheim, in Advances in Magnetic Resonance, Ed. by J. S. Waugh, Academic Press, New York, 1968, Vol. 3, p. 43.Google Scholar
  3. 3.
    R. Kubo, in Fluctuation, Relaxation and Resonance in Magnetic Systems, Ed. by D. Ter Haar, Oliver and Boyd, London, 1961, p. 23.Google Scholar
  4. 4.
    H. G. Hertz, in Progress in N. M. R. Spectroscopy, Ed. by J. W. Emsley, J. Feeney, and L. H. Sutcliffe, Pergamon Press, New York, 1967, Vol. 3, p. 159.Google Scholar
  5. 5.
    C. Deverell, in Progress in N. M. R. Spectroscopy, Ed. by J. W. Emsley, J. Feeney, and L. H. Sutcliffe, Pergamon Press, New York, 1969, Vol. 4, p. 235.Google Scholar
  6. 6.
    J. F. Hinton and E. S. Amis, Chem. Rev 67 (1967) 367.CrossRefGoogle Scholar
  7. 7.
    H. G. Hecht, in Magnetic Resonance Spectroscopy, Wiley, New York, 1967.Google Scholar
  8. 8.
    F. A. Bovey, in Nuclear Magnetic Resonance Spectroscopy, Academic Press, New York, 1969.Google Scholar
  9. 9.
    J. A. Pople, W. G. Schneider, and H. J. Bernstein, in High Resolution Nuclear Magnetic Resonance, McGraw-Hill, 1959.Google Scholar
  10. 10.
    J. W. Emsley, J. Feeney, and L. H. Sutcliffe, in High Resolution Nuclear Magnetic Resonance Spectroscopy, Pergamon Press, 1965.Google Scholar
  11. 11.
    C. P. Slichter, in Principles of Magnetic Resonance, Harper and Row, New York, 1963.Google Scholar
  12. 12.
    A. Lösche, Kerninduktion, Deutscher Verlag der Wissenschaften, Berlin, 1957.Google Scholar
  13. 13.
    A. Abragam, in The Principles of Nuclear Magnetism, Oxford University Press, Oxford, 1962.Google Scholar
  14. 14.
    D. Pines and C. P. Slichter, Phys. Rev 100 (1955) 1014.CrossRefGoogle Scholar
  15. 15.
    M. D. Zeidler, Ber. Bunsenges. Physik. Chem 75 (1971) 229.Google Scholar
  16. 16.
    R. C. Tolman, in Principles of Statistical Mechanics, Oxford University Press, Oxford, 1962.Google Scholar
  17. 17.
    J. P. Kintzinger and M. D. Zeidler, Ber. Bunsenges. Physik. Chem. 77 (1973) 98, 294E.Google Scholar
  18. 18.
    H. Pfeifer, in NMR-Basic Principles and Progress, Ed. by P. Diehl, E. Fluck, and P. Kosfeld, Springer, Berlin, 1972, Vol. 7, p. 53.Google Scholar
  19. 19.
    K. J. Packer, in Progress in N. M. R. Spectroscopy, Ed. by J. W. Emsley, J. Feeney, and L. H. Sutcliffe, Pergamon Press, New York, 1967, Vol. 3, p. 87.Google Scholar
  20. 20.
    B. J. Berne and G. D. Harp, Adv. Phys. Chem 17 (1970) 63.CrossRefGoogle Scholar
  21. 21.
    B. J. Berne, in Physical Chemistry-An Advanced Treatise, Ed. by H. Eyring, D. Henderson, and W. M. Jost, Academic Press, New York, 1971, Vol. IIIB, p. 539.Google Scholar
  22. 22.
    A. Rahman and F. H. Stillinger, J. Chem. Phys 55 (1971) 3336.CrossRefGoogle Scholar
  23. 23.
    F. H. Stillinger and A. Rahman, J. Chem. Phys 57 (1972) 1281.CrossRefGoogle Scholar
  24. 24.
    P. Debye, Z. Physik 36 (1935) 100.Google Scholar
  25. 25.
    I. Perrin, J. Phys. Radium 5 (1934) 497.CrossRefGoogle Scholar
  26. 26.
    L. D. Favro, Phys. Rev 119 (1960) 53CrossRefGoogle Scholar
  27. 27.
    A. Cabana, R. Bardoux, and A. Chamberland, Can. J. Chem 47 (1969) 2915.CrossRefGoogle Scholar
  28. 28.
    C. E. Favelukus, A. A. Clifford, and B. Crawford, J. Phys. Chem 72 (1968) 962.CrossRefGoogle Scholar
  29. 29.
    T. Fujiyama and B. Crawford, J. Phys. Chem 73 (1969) 4040.CrossRefGoogle Scholar
  30. 30.
    W. G. Rothschild, J. Chem. Phys 53 (1970) 990.CrossRefGoogle Scholar
  31. 31.
    E. N. Ivanov, Soy. Phys.-JETP 18 (1964) 1041.Google Scholar
  32. 32.
    W. T. Huntress, Jr., J. Chem. Phys 48 (1968) 3524.CrossRefGoogle Scholar
  33. 33.
    W T. Huntress, Jr., in Advances in Magnetic Resonance, Ed. by J. S. Waugh, Academic Press, New York, 1970, Vol. 4, p. 1.Google Scholar
  34. 34.
    D. E. Woessner, J. Chem. Phys. 36 (1962) 1; 37 (1962) 647.Google Scholar
  35. 35.
    H. J. Shimizu, J. Chem. Phys. 37 (1962) 765; 40 (1964) 754.Google Scholar
  36. 36.
    T. T. Bopp, J. Chem. Phys 47 (1967) 3621.CrossRefGoogle Scholar
  37. 37.
    D. E. Woessner, B. S. Snowdon, Jr., and E. T. Storm, Mol. Phys 14 (1968) 265.CrossRefGoogle Scholar
  38. 38.
    R. G. Gordon, J. Chem. Phys. 42 (1965) 3658; 43 (1965) 1307.Google Scholar
  39. 39.
    H. Shimizu, J. Chem. Phys 43 (1965) 2453.CrossRefGoogle Scholar
  40. 40.
    R. P. Young and R. N. Jones, Chem. Rev 71 (1971) 219.CrossRefGoogle Scholar
  41. 41.
    W. G. Rothschild, J. Chem. Phys. 53 (1970) 3265; 55 (1971) 1402.Google Scholar
  42. W. G. Rothschild, See also Chem. Phys. Letters 9 (1971) 149.CrossRefGoogle Scholar
  43. 42.
    W. G. Rothschild, J. Chem. Phys 57 (1972) 991.CrossRefGoogle Scholar
  44. 43.
    T. T. Wall, J. Chem. Phys 51 (1969) 113.CrossRefGoogle Scholar
  45. 44.
    K. Klier, J. Chem. Phys 58 (1973) 737.CrossRefGoogle Scholar
  46. 45.
    G. Lévi, M. Chalaye, F. Marsault-Herail, and J. P. Marsault, Mol. Phys 24 (1972) 1217.CrossRefGoogle Scholar
  47. 46.
    P van Konynenburg and W. A. Steele, J. Chem. Phys 56 (1972) 4776.CrossRefGoogle Scholar
  48. 47.
    D. A. Pinnow, S. J. Candau, and T. A. Litovitz, J. Chem. Phys 49 (1968) 347.CrossRefGoogle Scholar
  49. 48.
    F. J. Bartoli and T. A. Litovitz, J. Chem. Phys. 56 (1972) 404, 413.CrossRefGoogle Scholar
  50. 49.
    S. Bratoz, J. Rios, and Y. Guissani, J. Chem. Phys 52 (1970) 439.CrossRefGoogle Scholar
  51. 50.
    S. Bratoz and E. Marechal, Phys. Rev. A 4 (1971) 1078.CrossRefGoogle Scholar
  52. 51.
    R. R. G. Gordon, in Advances in Magnetic Resonance, Ed. by J. S. Waugh, Academic Press, 1968, Vol. 3, p. 5.Google Scholar
  53. 52.
    R. G. Gordon, J. Chem. Phys 44 (1966) 1830.CrossRefGoogle Scholar
  54. R. G. Gordon, See also R. E. McClung, J. Chem. Phys 51 (1969) 3842.CrossRefGoogle Scholar
  55. 53.
    A. A. Maryott, T. C. Farrar, and M. S. Malmberg, J. Chem. Phys 54 (1971) 64.CrossRefGoogle Scholar
  56. 54.
    H. W. Spiess, D. Schweitzer, U. Haeberlein, and K. H. Hausser, J. Mag. Res 5 (1971) 191.Google Scholar
  57. 55.
    M. Fixman and K. Rider, J. Chem. Phys 51 (1969) 2425.CrossRefGoogle Scholar
  58. 56.
    H. Shimizu, J. Chem. Phys 48 (1967) 2494.CrossRefGoogle Scholar
  59. 57.
    H. Sillescu, J. Chem. Phys 54 (1971) 2110.CrossRefGoogle Scholar
  60. 58.
    D. E. O’Reilly, J. Chem. Phys 56 (1972) 2924.CrossRefGoogle Scholar
  61. 59.
    D. Beckert and H. Pfeifer, Ann. Physik 16 (1965) 262.CrossRefGoogle Scholar
  62. 60.
    H. G. Hertz, Ber. Bunsenges. Physik. Chem. 71 (1967) 979, 999.Google Scholar
  63. 61.
    W. A. Steele, J. Chem. Phys 38 (1963) 2404, 2411.Google Scholar
  64. 62.
    D. Kivelson and Th. Keyes, J. Chem. Phys 57 (1972) 4599.CrossRefGoogle Scholar
  65. 63.
    S. Hubbard, Phys. Rev 131 (1963) 275.CrossRefGoogle Scholar
  66. 64.
    Myong-Ku Ahu, J. S. K. Jensen, and D. Kivelson, J. Chem. Phys 57 (1972) 2940.CrossRefGoogle Scholar
  67. 65.
    H. C. Torrey, Phys. Rev 92 (1953) 962.CrossRefGoogle Scholar
  68. 66.
    S. Chandrasekhar, in Noise and Stochastic Processes, Ed. by N. Wax, Dover, New York, 1954, p. 3.Google Scholar
  69. 67.
    E. v. Goldammer and H. G. Hertz, J. Phys. Chem 74 (1970) 3734.CrossRefGoogle Scholar
  70. 68.
    I. Oppenheim and M. Bloom, Can. J. Phys 39 (1961) 845.CrossRefGoogle Scholar
  71. 69.
    P K. Sharma and S. K. Joshi, Phys. Rev 132 (1963) 1431.CrossRefGoogle Scholar
  72. 70.
    J. F. Harmon and B. H. Muller, Phys. Rev 182 (1969) 400.CrossRefGoogle Scholar
  73. 71.
    R. Zwanzig, Ann. Phys. Rev 16 (1965) 67.CrossRefGoogle Scholar
  74. 72.
    P. A. Egelstaff, in An Introduction to the Liquid State, Academic Press, New York, 1967.Google Scholar
  75. 73.
    Transport Phenomena in Fluids Ed. by H. J. M. Hanley, Marcel Dekker, New York, 1969.Google Scholar
  76. 74.
    E. A. C. Lucken, in Nuclear Quadrupole Coupling Constants, Academic Press, 1969.Google Scholar
  77. 75.
    J. G. Powles, Ber. Bunsenges. Physik. Chem 67 (1963) 328.Google Scholar
  78. 76.
    N. Bloembergen, E. M. Purcell, and R. V. Pound, Phys. Rev 73 (1948) 679.CrossRefGoogle Scholar
  79. 77.
    P. S. Hubbard, Phys. Rev 131 (1963) 1155.CrossRefGoogle Scholar
  80. 78.
    J. Bender and M. D. Zeidler, Ber. Bunsenges. Physik. Chem 75 (1971) 236.Google Scholar
  81. 79.
    D. W. G. Smith and J. G. Powles, Mol. Phys 10 (1966) 451.CrossRefGoogle Scholar
  82. 80.
    E. L. Hahn, Phys. Rev 80 (1950) 580.CrossRefGoogle Scholar
  83. 81.
    H. Y. Carr and E. M. Purcell, Phys. Rev 94 (1954) 630.CrossRefGoogle Scholar
  84. 82.
    S. Meiboom and D. Gill, Rev. Sci. Instr 29 (1958) 688.CrossRefGoogle Scholar
  85. 83.
    T. C. Farrar and E. D. Becker, in Pulse and Fourier Transform NMR, Academic Press, New York, 1971.Google Scholar
  86. 84.
    W. G. Schneider, H. J. Bernstein, and J. A. Pople, J. Chem. Phys 28 (1958) 601.CrossRefGoogle Scholar
  87. 85.
    J. C. Hindman, J. Chem. Phys 44 (1966) 4582.CrossRefGoogle Scholar
  88. 86.
    E. R. Malinowsky, P. S. Knapp, and B. Feuer, J. Chem. Phys. 45 (1966) 4274; 47 (1967) 347 (E).Google Scholar
  89. 87.
    N. Müller and R. C. Reiter, J. Chem. Phys 42 (1965) 3265.CrossRefGoogle Scholar
  90. 88.
    N. Müller, J. Chem. Phys 43 (1965) 2555.CrossRefGoogle Scholar
  91. 89.
    H. H. Rüterjans and H. A. Scheraga, J. Chem. Phys 45 (1966) 3296.CrossRefGoogle Scholar
  92. 90.
    A. D. Buckingham, Can. J. Chem 38 (1960) 300.CrossRefGoogle Scholar
  93. 91.
    E. J. W. Verwey, Rec. Tray. Chim 60 (1941) 887.CrossRefGoogle Scholar
  94. 92.
    C. A. Coulson and D. Eisenberg, Proc. Roy. Soc. A291 (1966) 445, 454.Google Scholar
  95. 93.
    G. H. Haggis, J. B. Hasted, and T. J. Buchanan, J. Chem. Phys 20 (1952) 1452.CrossRefGoogle Scholar
  96. 94.
    G. Némethy and H. A. Scheraga, J. Chem. Phys 36 (1962) 3382.CrossRefGoogle Scholar
  97. 95.
    H. S. Frank and A. S. Quist, J. Chem. Phys 34 (1961) 604.CrossRefGoogle Scholar
  98. 95.
    G. E. Walrafen, J. Chem. Phys. 40 (1964) 3249; 44 (1966) 1546.Google Scholar
  99. 96.
    D. Eisenberg and W. Kauzmann, in The Structure and Properties of Water, Oxford University Press, Oxford, 1969.Google Scholar
  100. 97.
    M. Falk and T. A. Ford, Can. J. Chem 44 (1966) 1699.CrossRefGoogle Scholar
  101. 98.
    Z. Luz and G. Y. Yagil, J. Phys. Chem 70 (1966) 554.CrossRefGoogle Scholar
  102. 99.
    F. Fister and H. G. Hertz, Ber. Bunsenges. Physik. Chem 71 (1967) 1032.Google Scholar
  103. 100.
    R. Hausser, Z. Naturforsch 18A (1963) 1143.Google Scholar
  104. 101.
    J. G. Powles and D. W. G. Smith, Phys. Letters 9 (1964) 239.CrossRefGoogle Scholar
  105. 102.
    J. G. Powles, in Relaxation Processes, The Chemical Society, London, 1966, p. 451.Google Scholar
  106. 103.
    H. Simpson and H. Y. Carr, Phys. Rev 111 (1958) 1201.CrossRefGoogle Scholar
  107. 104.
    K. Krynicky, Physica 32 (1966) 167.CrossRefGoogle Scholar
  108. 105.
    See Ref. 96, p. 223.Google Scholar
  109. 106.
    See Ref. 96, p. 207.Google Scholar
  110. 107.
    R. Mills, J. Phys. Chem 73 (1973) 685.CrossRefGoogle Scholar
  111. 108.
    S. Gladstone, K. J. Laidler and H. Eyring, in The Theory of Rate Processes, McGraw-Hill, New York, 1941.Google Scholar
  112. 109.
    E. v. Goldammer and M. D. Zeidler, Ber. Bunsenges. Physik. Chem 73 (1969) 4.Google Scholar
  113. 110.
    J. G. Powles, J. Chem. Phys 21 (1953) 633.CrossRefGoogle Scholar
  114. 111.
    S. H. Glarum, J. Chem. Phys 33 (1960) 1371.CrossRefGoogle Scholar
  115. 112.
    T. W. Nee and R. W. Zwanzig, J. Chem. Phys 52 (1970) 6353.CrossRefGoogle Scholar
  116. 113.
    G. B. Benedek and E. M. Purcell, J. Chem. Phys 22 (1954) 2003.CrossRefGoogle Scholar
  117. 114.
    H. G. Hertz and C. Rädle, Z. Physik. Chem. (NF) 68 (1969) 324.CrossRefGoogle Scholar
  118. 115.
    See Ref. 96, p. 222.Google Scholar
  119. 116.
    R. E. Glick and K. C. Tewari, J. Chem. Phys 44 (1966) 546.CrossRefGoogle Scholar
  120. 117.
    S. Meiboom, Z. Luz, and D. Gill, J. Chem. Phys 27 (1957) 1411.CrossRefGoogle Scholar
  121. 118.
    S. Meiboom, J. Chem. Phys 34 (1961) 375.CrossRefGoogle Scholar
  122. 119.
    H. G. Hertz and M. D. Zeidler, Ber. Bunsenges. Physik. Chem 68 (1964) 821.Google Scholar
  123. 120.
    D. E. Woessner, J. Chem. Phys 40 (1964) 2341.CrossRefGoogle Scholar
  124. 121.
    G. Powles, M. Rhodes, and J. H. Strange, Mol. Phys 11 (1966) 515.CrossRefGoogle Scholar
  125. 122.
    S. W. Rabideau and J. A. Jackson, J. Chem. Phys 41 (1964) 3405.CrossRefGoogle Scholar
  126. 123.
    J. A. Glasel, Proc. Natl. Acad. Sci. U.S. 55 (1966) 479.CrossRefGoogle Scholar
  127. 124.
    B B. Garrett, A. B. Denison, and S. W. Rabideau, J. Phys. Chem 71 (1967) 2606.CrossRefGoogle Scholar
  128. 125.
    J. C. Hindman, A. J. Zielen, A. Svirmickas, and M. Wood, J. Chem. Phys 54 (1971), 621.CrossRefGoogle Scholar
  129. 126.
    H. L. Friedman, in Modern Aspects of Electrochemistry, Ed. by J. O. M. Bockris and B. E. Conway, Butterworths, London, 1971, Vol. 6, p. I.Google Scholar
  130. 127.
    J. G. Kirkwood, J. Chem. Phys 7 (1939) 911.CrossRefGoogle Scholar
  131. J. G. Kirkwood, See also G. Oster and J. G. Kirkwood, J. Chem. Phys 11 (1943) 175.CrossRefGoogle Scholar
  132. 128.
    R. W. Gurney, in Ionic Processes in Solutions, McGraw-Hill, New York, 1953.Google Scholar
  133. 129.
    H. Falkenhagen, Z. Physik, 30 (1929) 611.Google Scholar
  134. 130.
    M. Kaminsky, Disc. Faraday Soc 24 (1957) 171.CrossRefGoogle Scholar
  135. 131.
    H. G. Hertz, Ber. Bunsenges. Physik. Chem 68 (1966) 907.Google Scholar
  136. 132.
    H. G. Hertz, Ber. Bunsenges. Physik. Chem 74 (1970) 666.Google Scholar
  137. 133.
    H. G. Hertz, Ber. Bunsenges. Physik. Chem 75 (1971) 183.Google Scholar
  138. 134.
    H. G. Hertz, Ber. Bunsenges. Physik. Chem 75 (1971) 572.Google Scholar
  139. 135.
    N. J. Shoorley and B. J. Alder, J. Chem. Phys 23 (1955) 805.CrossRefGoogle Scholar
  140. 136.
    H. G. Hertz and W. Spalthoff, Z. Elektrochem. Ber. Bunsenges. Physik. Chem 63 (1959) 1096.Google Scholar
  141. 137.
    B. P. Fabricand and S. Goldberg, J. Chem. Phys 34 (1961) 1624.CrossRefGoogle Scholar
  142. 138.
    C. Hindman, J. Chem. Phys 36 (1962) 1000.CrossRefGoogle Scholar
  143. 139.
    M. S. Bergquist and E. Forslind, Acta Chem. Scand 16 (1962) 2069.CrossRefGoogle Scholar
  144. 140.
    C. Franconi, C. Dejak, and F. Conti, in Nuclear Magnetic Resonance in Chemistry, Ed. by B. Pesce, Academic Press, New York, 1965.Google Scholar
  145. 141.
    R. E. Glick, W. E. Stewart, and K. C. Tewari, J. Chem. Phys 45 (1966) 4049.CrossRefGoogle Scholar
  146. 142.
    H. G. Hertz, Ber. Bunsenges. Physik. Chem 67 (1963) 311.Google Scholar
  147. 142a.
    A. I. Ryss and I. V. Radchenko, J. Struct. Chem. 4 (1963) 611; 6 (1965) 171; 5 (1964) 489.Google Scholar
  148. 142b.
    J. G. Mathieson and B. E. Conway, J. Solution Chem 3 (1974) 455.CrossRefGoogle Scholar
  149. 143.
    R. N. Butler and M. C. R. Symons, Trans. Faraday Soc 65 (1969) 945, 2559.Google Scholar
  150. 144.
    J Davis, S. Ormondroyd, and M. C. R. Symons, Trans. Faraday Soc 67 (1971) 3465.CrossRefGoogle Scholar
  151. 145.
    H. S. Frank and W. Y. Wen, Disc. Faraday Soc 24 (1957) 133.CrossRefGoogle Scholar
  152. 146.
    J A. Jackson, J. F. Lemons, and H. Taube, J. Chem. Phys 32 (1960) 553.CrossRefGoogle Scholar
  153. 147.
    R. E. Connick and D. N. Fiat, J. Chem. Phys. 39 (1963) 1349; 44 (1966) 4103.Google Scholar
  154. 148.
    D. N. Fiat and R. E. Connick, J. Am. Chem. Soc. 88 (1966) 4754.CrossRefGoogle Scholar
  155. 149.
    N. Bloembergen, J. Chem. Phys 27 (1957) 595.CrossRefGoogle Scholar
  156. 150.
    T. J. Swift, J. G. Fritz, Jr., and F. A. Stephanson, J. Chem. Phys 46 (1967) 406.CrossRefGoogle Scholar
  157. 151.
    M. Alei, Jr. and J. A. Jackson, J. Chem. Phys 41 (1964) 3402.CrossRefGoogle Scholar
  158. 152.
    J. H. Swinehart and H. Taube, J. Chem. Phys 37 (1962) 1579.CrossRefGoogle Scholar
  159. 153.
    A. Fratiello, D. P. Miller, and R. Schuster, Mol. Phys 12 (1967) 111.CrossRefGoogle Scholar
  160. 154.
    A. Fratiello, R. Schuster, and D. P. Miller, J. Phys. Chem 71 (1967) 1948.CrossRefGoogle Scholar
  161. 155.
    W G. Movius and N. A. Matwiyoff, Inorg. Chem 6 (1967) 847.CrossRefGoogle Scholar
  162. 156.
    S. Thomas and W. L. Reynolds, J. Chem. Phys 44 (1966) 3148.CrossRefGoogle Scholar
  163. 157.
    S. Nakamura and S. Meiboom, J. Am. Chem. Soc. 89 (1967) 1765.CrossRefGoogle Scholar
  164. 158.
    N. A. Matwiyoff and W. G. Movius, J. Am. Chem. Soc. 89 (1967) 6077.CrossRefGoogle Scholar
  165. 159.
    N. A. Matwiyoff, Inorg. Chem 5 (1966) 788.CrossRefGoogle Scholar
  166. 160.
    R. E. Schuster and A. Fratiello, J. Chem. Phys 47 (1967) 1554.CrossRefGoogle Scholar
  167. 161.
    R. G. Wawro and T. J. Swift, J. Am. Chem. Soc 90 (1968) 2792.CrossRefGoogle Scholar
  168. 162.
    A. Fratiello and D. P. Miller, Mol. Phys 11 (1966) 37.CrossRefGoogle Scholar
  169. 163.
    N. A. Matwiyoff and H. Taube, J. Am. Chem. Soc 90 (1968) 2796.CrossRefGoogle Scholar
  170. 164.
    A. Fratiello, V. Kubo, R. E. Lee, and R. E. Schuster, J. Phys. Chem 74 (1970) 3726.CrossRefGoogle Scholar
  171. 165.
    R. D. Green and N. Sheppard, J. Chem. Soc. Faraday Trans. Part 1168 (1972) 821.CrossRefGoogle Scholar
  172. 166.
    A. Fratiello and D. C. Douglass, J. Chem. Phys 39 (1963) 2017.CrossRefGoogle Scholar
  173. 167.
    A. Fratiello and E. G. Christie, Trans. Faraday Soc. 61 (1965) 306.CrossRefGoogle Scholar
  174. 168.
    J. F. Hinton, L. S. McDowell and E. S. Amis, Chem. Commun. (1966) 776.Google Scholar
  175. 169.
    J. F. Hinton and E. S. Amis, Chem. Commun. (1967) 100.Google Scholar
  176. 170.
    A. Fratiello, R. E. Lee, V. M. Nishida, and R. E. Schuster, Chem. Commun. (1968) 173.Google Scholar
  177. 171.
    A. Fratiello, R. E. Lee, V. M. Nishida, and R. E. Schuster, J. Chem. Phys. 47 Phys. 47 (1967) 4951.Google Scholar
  178. 172a.
    J. F. Hinton and E. S. Amis, Chem. Rev 71 (1971) 627.CrossRefGoogle Scholar
  179. 172b.
    J. OM. Bockris and B. E. Conway, in Modern Aspects of Electrochemistry, Butterworths, London, 1954, Vol. 1, p. 67.Google Scholar
  180. 172c.
    J. O’M. Bockris, Quart. Rev. Chem. Soc 3 (1949) 173.CrossRefGoogle Scholar
  181. 173.
    A. Loewenstein, M. Shporer, P.S. Lauterbur, and J. E. Ramirez, Chem. Commun. (1968) 214.Google Scholar
  182. 174.
    B. W. Epperlein and O. Luz, Z. Naturforsch 23A (1968) 1413.Google Scholar
  183. 175.
    C. D. Deverell and K. Schaumburg, Anal. Chem 39 (1967) 1879.CrossRefGoogle Scholar
  184. 176.
    C. Deverell, K. Schaumburg, and H. J. Bernstein, J. Chem. Phys 49 (1968) 1276.CrossRefGoogle Scholar
  185. 177.
    A. K. Covington, T. H. Lilley, K. E. Newman, and G. A. Porthouse, J. Chem. Soc. Faraday Trans. Part 1 (1973) 963.CrossRefGoogle Scholar
  186. 178.
    P. M. Borodin, E. K. Legin, E. N. Sventitskii, M. B. Khusidman, and V. A. Shcherbakov, J. Struct. Chem 4 (1961) 240.CrossRefGoogle Scholar
  187. 179.
    R. Freeman, R. P. H. Gasser, and D. H. Wheeler, Mol. Phys 2 (1959) 75.CrossRefGoogle Scholar
  188. 180.
    R. P. H. Gasser and R. E. Richards, Mol. Phys 2 (1959) 357.CrossRefGoogle Scholar
  189. 181.
    J. Itoh and Y. Yamagata, J. Phys. Soc. Japan 13 (1958) 1182.CrossRefGoogle Scholar
  190. 182.
    O. Jardetzky and J. E. Wertz, J. Am. Chem. Soc 82 (1959) 318.CrossRefGoogle Scholar
  191. 183.
    C. Deverell and R. E. Richards, Mol. Phys 10 (1966) 551.CrossRefGoogle Scholar
  192. 184.
    J. D. Halliday, R. E. Richards, and R. R. Sharp, Proc. Roy. Soc A313 (1969) 45.CrossRefGoogle Scholar
  193. 185.
    C. Deverell, Mol. Phys 16 (1969) 491.CrossRefGoogle Scholar
  194. 186.
    C. Deverell and R. E. Richards, Mol. Phys 16 (1969) 421.CrossRefGoogle Scholar
  195. 187.
    C. H. Langford and T. R. Stengle, J. Am. Chem. Soc. 91 (1969) 4014.CrossRefGoogle Scholar
  196. 188.
    T. R. Stengle, Yu-Ching E. Pan, and C. H. Langford, J. Am. Chem. Soc 94 (1972) 9037.CrossRefGoogle Scholar
  197. 189.
    J. Kondo and J. Yamashita, J. Phys. Solids 10 (1959) 245.CrossRefGoogle Scholar
  198. 190.
    P S. Leung, S. M. Sanborm, and G. J. Safford, J. Phys. Chem 74 (1970) 3710.CrossRefGoogle Scholar
  199. 191.
    P S. Leung and S. M. Safford, J. Phys. Chem 74 (1970) 3696.CrossRefGoogle Scholar
  200. 192.
    G. J. Safford and P. S. Leung, Ber. Bunsenges. Physik. Chem 75 (1971) 366.Google Scholar
  201. 193.
    J. B. Hasted, D. M. Ritson, and C. H. Collie, J. Chem. Phys 16 (1948) 1.CrossRefGoogle Scholar
  202. 194.
    G. H. Haggis, J. B. Hasted, and T. J. Buchanan, J. Chem. Phys 20 (1952) 1452.CrossRefGoogle Scholar
  203. 195.
    J. B. Hasted and S. H. M. El Sabeh, Trans. Faraday Soc 49 (1953) 1009.CrossRefGoogle Scholar
  204. 196.
    J. B. Hasted and G. W. Roderick, J. Chem. Phys 29 (1958) 17.CrossRefGoogle Scholar
  205. 197.
    F. E. Harris and C. T. O’Konski, J. Phys. Chem 61 (1957) 310.CrossRefGoogle Scholar
  206. 198.
    P. S. Yastremskii, J. Struct. Chem. 2 (1961) 257.CrossRefGoogle Scholar
  207. 199.
    P S. Yastremskii, J. Struct. Chem. 3 (1962) 279.CrossRefGoogle Scholar
  208. 200.
    K. Giese, U. Kaatze, and R. Pottel, J. Phys. Chem 74 (1970) 3718.CrossRefGoogle Scholar
  209. 201.
    J. Barthel, H. Behret, and F. Schmithals, Ber. Bunsenges. Physik. Chem 75 (1971) 305.Google Scholar
  210. 202.
    V. M. Vdovenko and V. A. Shcherbakov, J. Struct. Chem. 1 (1960) 25, 111.Google Scholar
  211. 203.
    V. A. Vdovenko, 0. B. Stebunov, and V. A. Shcherbakov, J. Struct. Chem 2 (1961) 55.CrossRefGoogle Scholar
  212. 204.
    H. G. Hertz and M. D. Zeidler, Ber. Bunsenges. Physik. Chem 67 (1963) 774.Google Scholar
  213. 205.
    P. Fabricand, S. S. Goldberg, R. Leifer, and S. G. Ungar, Mol. Phys 7 (1964) 425.CrossRefGoogle Scholar
  214. 206.
    G. T. Jones and J. G. Powles, Mol. Phys 8 (1964) 607.CrossRefGoogle Scholar
  215. 207.
    B. P. Fabricand, Mol. Phys 9 (1965) 399.CrossRefGoogle Scholar
  216. 208.
    L. Endom, H. G. Hertz, B. Thül, and M. D. Zeidler, Ber. Bungsenges. Physik. Chem 71 (1967) 1008.Google Scholar
  217. 209.
    E. Woessner, B. S. Snowden, Jr., and A. G. Ostroff, J. Chem. Phys 49 (1968) 371.CrossRefGoogle Scholar
  218. 210.
    D. E. Woessner, B. S. Snowden, Jr., and A. G. Ostroff, J. Chem. Phys 50 (1969) 4714.CrossRefGoogle Scholar
  219. 211.
    G. Engel and H. G. Hertz, Ber. Bunsenges. Physik. Chem 72 (1968) 808.Google Scholar
  220. 212a.
    B. P. Fabricand and S. Goldberg, Mol. Phys 13 (1967) 323.CrossRefGoogle Scholar
  221. 212b.
    G. Hertz, Mol. Phys 14 (1968) 291.CrossRefGoogle Scholar
  222. 213.
    W. Lohmann, Z. Naturforsch 19A (1964) 814.Google Scholar
  223. 214.
    V. I. Ionov and R. K. Mazitov, J. Struct. Chem 7 (1966) 185.CrossRefGoogle Scholar
  224. 215.
    Y. Lee and J. Jonas, J. Mag. Res 5 (1971) 267.Google Scholar
  225. 216.
    H. G. Hertz and R. Klute, Z. Physik. Chem. (NF) 69 (1970) 101.CrossRefGoogle Scholar
  226. 217.
    D. E. O’Reilly and E. M. Peterson, J. Phys. Chem 74 (1970) 3280.CrossRefGoogle Scholar
  227. 218.
    S. Danyluk and E. S. Gore, Nature 203 (1964) 748.CrossRefGoogle Scholar
  228. 219.
    J. R. Zimmerman and W. E. Brittin, J. Phys. Chem 61 (1957) 1328.CrossRefGoogle Scholar
  229. 220.
    B. E. Conway and L. H. Laliberté, J. Phys. Chem 72 (1968) 4317.CrossRefGoogle Scholar
  230. 221.
    B. E. Conway and L. H. Laliberté, in Hydrogen Bonded Systems, Ed. by A. K. Covington and P. Jones, Taylor and Francis, London, 1968.Google Scholar
  231. 222.
    B. E. Conway and L. H. Laliberté, Trans. Faraday Soc 66 (1970) 1.CrossRefGoogle Scholar
  232. 223.
    J. L. Kavanau, in Water and Solute Interactions, Holden-Day, London, 1964.Google Scholar
  233. 2240.
    Ya. Samoilov, in Structure of Aqueous Electrolyte Solutions and Hydration of Ions, Transi. by D. J. G. Ives, Consultants Bureau, New York, 1965.Google Scholar
  234. 225.
    Ya. Samoilov, Disc. Faraday Soc. 24 (1957) 141.CrossRefGoogle Scholar
  235. 226.
    Ya. Samoilov, in Water and Aqueous Solutions, Ed. by R. A. Home, WileyInterscience, New York, 1972, p. 597.Google Scholar
  236. 227.
    J. Arnold and K. J. Packer, Mol. Phys 14 (1968) 241.CrossRefGoogle Scholar
  237. 228.
    K. A. Valiev and M. I. Emelyanov, J. Struct. Chem 5 (1964) 625.CrossRefGoogle Scholar
  238. 229.
    M. I. Emelyanov, J. Struct. Chem 6 (1964) 270.CrossRefGoogle Scholar
  239. 230.
    V. Matyash, A. I. Toryanik, and V. I. Yashkichev, J. Struct. Chem 5 (1964) 713.CrossRefGoogle Scholar
  240. 231.
    D. W. McCall and D. C. Douglass, J. Phys. Chem 69 (1965) 2001.CrossRefGoogle Scholar
  241. 232.
    M. I. Emel’yanov and A. S. Agishev, J. Struct. Chem 6 (1965) 870.CrossRefGoogle Scholar
  242. 233.
    J. H. Wang, J. Phys. Chem 58 (1954) 686.CrossRefGoogle Scholar
  243. 234.
    K. Wüthrich and R. E. Connick, Inorg. Chem 7 (1968) 1377.CrossRefGoogle Scholar
  244. 235.
    R. E. Connick and R. E. Wüthrich, J. Chem. Phys 71 (1969) 4506.CrossRefGoogle Scholar
  245. 236.
    M. Eisenstadt and H. L. Friedman, J. Chem. Phys 44 (1966) 1407.CrossRefGoogle Scholar
  246. 237.
    M. Eisenstadt and H. L. Friedman, J. Chem. Phys 46 (1967) 2182.CrossRefGoogle Scholar
  247. 238.
    K. A. Hartman, Jr., J. Phys. Chem 70 (1966) 270.CrossRefGoogle Scholar
  248. 239.
    Z. Kecki, P. Dryjanski, and E. Kozlowska, Roczniki Chem. 42 (1968) 1749.Google Scholar
  249. 240.
    G. E. Walrafen, J. Chem. Phys 52 (1970) 4176.CrossRefGoogle Scholar
  250. 241.
    H. G. Hertz, B. Lindman, and V. Siepe, Ber. Bunsenges. Physik. Chem 73 (1969) 542.Google Scholar
  251. 242.
    W. Larsen, J. Phys. Chem. 74 (1970) 3380; 75 (1971) 509.Google Scholar
  252. 243.
    S. Lindman, S. Forsén, and E. Forslind, J. Phys. Chem 72 (1968) 2805.CrossRefGoogle Scholar
  253. 244.
    B. Lindman, H. Wennerström, and S. Forsén, J. Phys. Chem 74 (1970) 754.CrossRefGoogle Scholar
  254. 245.
    J. Clifford and B. A. Pethica, Trans. Faraday Soc 61 (1965) 182.CrossRefGoogle Scholar
  255. 246.
    J. Clifford, B. A. Pethica, and W. A. Senior, Ann. N.Y. Acad. Sci 125 (1965) 458.CrossRefGoogle Scholar
  256. 247.
    H. S. Frank and M. W. Evans, J. Chem. Phys 13 (1945) 507.CrossRefGoogle Scholar
  257. See also D. D. Eley, Trans. Faraday Soc 35 (1939) 1281.CrossRefGoogle Scholar
  258. 248.
    B. E. Conway and R. E. Verrall, J. Chem. Phys. 70 (1966) 3952, 3961.Google Scholar
  259. 249.
    R. A. Craig and R. E. Richards, Trans. Faraday Soc 59 (1963) 1972.CrossRefGoogle Scholar
  260. 250.
    H. G. Hertz, R. Tutsch, and H. Versmold, Ber. Bunsenges. Physik. Chem. 75 (1971) 1177; 76 (1972) 81.Google Scholar
  261. 251.
    V. I. Ionov, R. V. Mazitov, and O. Ya. Samoilov, J. Struct. Chem 10 (1970) 335.CrossRefGoogle Scholar
  262. 252.
    P. A. Speight and R. L. Armstrong, Can. J. Phys 45 (1967) 2493.CrossRefGoogle Scholar
  263. 253a.
    R E. Richards and B. A. Yorke, Mol. Phys 6 (1963) 289.CrossRefGoogle Scholar
  264. 253b.
    H. G. Hertz, Mol. Phys 7 (1964) 499.CrossRefGoogle Scholar
  265. 254.
    D. E. O’Reilly and E. M. Peterson, J. Chem. Phys 51 (1969) 4906.CrossRefGoogle Scholar
  266. 255.
    C. Hall, R. E. Richards, G. N. Schulz, and R. R. Sharp, Mol. Phys 16 (1969) 529.CrossRefGoogle Scholar
  267. 256.
    J. Arnold and K. J. Packer, Mol. Phys 14 (1968) 249.CrossRefGoogle Scholar
  268. 257.
    G. J. Templeman and A. L. van Geet, J. Am. Chem. Soc 94 (1972) 5578.CrossRefGoogle Scholar
  269. 258.
    A. L. van Geet, J. Am. Chem. Soc 94 (1972) 5583.CrossRefGoogle Scholar
  270. 259.
    H. G. Hertz, Ber. Bunsenges. Physik. Chem 65 (1961) 20.Google Scholar
  271. 260.
    E. O’Reilly, G. E. Schacher, and K. Schug, J. Chem. Phys 39 (1963) 1756.CrossRefGoogle Scholar
  272. 261.
    C. Deverell, D. J. Frost, and R. E. Richards, Mol. Phys 9 (1965) 565.CrossRefGoogle Scholar
  273. 262.
    H. G. Hertz, G. Keller, and H. Versmold, Ber. Bunsenges. Physik. Chem. 73 (1969) 549.Google Scholar
  274. 263.
    G. Keller, Ber. Bunsenges. Physik. Chem 76 (1972) 24.Google Scholar
  275. 264.
    K. A. Valiev, Soy. Phys.-JETP 10 (1060) 77.Google Scholar
  276. 265.
    K. A. Valiev and M. M. Zaripov, J. Struct. Chem 7 (1960) 470.CrossRefGoogle Scholar
  277. 266.
    J. W. Akitt, N. N. Greenwood, and A. Storr, J. Chem. Soc. (1965) 4410.Google Scholar
  278. 267.
    C. Hall, G. L. Haller, and R. E. Richards, Mol. Phys. 16 (1969) 377.CrossRefGoogle Scholar
  279. 268.
    K. A. Valiev, Soy. Phys.-JETP 11 (1961) 883.Google Scholar
  280. 269.
    K. A. Valiev and M. B. Khabibullin, Russ. J. Phys. Chem 35 (1961) 1118.Google Scholar
  281. 270.
    R. M. Sternheimer, Phys. Rev. 84 (1951) 244; 86 (1952) 316; 95 (1954) 736.Google Scholar
  282. 271.
    R. M. Sternheimer, Phys. Rev 130 (1963) 1423.CrossRefGoogle Scholar
  283. 272.
    R. M. Sternheimer, Phys. Rev 132 (1963) 1637.CrossRefGoogle Scholar
  284. 273.
    M. H. Cohen and F. Reif, Solid State Phys. 5 (1957) 321.CrossRefGoogle Scholar
  285. 274.
    A. Dalgarno, Adv. Phys 11 (1962) 281.CrossRefGoogle Scholar
  286. 275.
    H. S. Harned and B. B. Owen, in The Physical Chemistry of Electrolytic Solutions, third edition, Reinhold, New York, 1958.Google Scholar
  287. 276.
    R. H. Stokes and R. A. Robinson, J. Am. Chem. Soc 70 (1948) 1870.CrossRefGoogle Scholar
  288. 277.
    E. Wicke and M. Eigen, Z. Elektrochem. Ber. Bunsenges. Phys. Chem 57 (1953) 319.Google Scholar
  289. 278a.
    H. G. Hertz and C. Rädle, Ber. Bunsenges. Physik. Chem. 77 (1973) 521.Google Scholar
  290. 278b.
    J. D. Bernal and R. H. Fowler, J. Chem. Phys 1 (1933) 515.CrossRefGoogle Scholar
  291. See also E. J. W. Verwey, Rec. Tray. Chim. 60 (1941) 887CrossRefGoogle Scholar
  292. F. Vaslow, J. Phys. Chem 67 (1963) 2773.CrossRefGoogle Scholar
  293. 278c.
    G. H. F. Diercksen and W. P. Krämer, Chem. Phys. Letters 5 (1970) 570.CrossRefGoogle Scholar
  294. See also P. Russegger, H. Lischka, and P. Schuster, Theoret. Chim. Acta 24 (1972) 191.CrossRefGoogle Scholar
  295. 279.
    R. A. Bernheim, T. H. Brown, H. S. Gutowsky, and D. E. Woessner, J. Chem. Phys 30 (1959) 950.CrossRefGoogle Scholar
  296. 280.
    A. W. Nolle and L. O. Morgan, J. Chem. Phys 26 (1957) 642.CrossRefGoogle Scholar
  297. 281.
    L. O. Morgan and A. W. Nolle, J. Chem. Phys 31 (1959) 365.CrossRefGoogle Scholar
  298. 282.
    R. Hausser and G. Laukien, Z. Physik 153 (1959) 394.CrossRefGoogle Scholar
  299. 283.
    N. Bloembergen and L. O. Morgan, J. Chem. Phys 34 (1961) 842.CrossRefGoogle Scholar
  300. 284.
    H. Pfeifer, Ann. Physik 8 (1961) 1.CrossRefGoogle Scholar
  301. 285.
    H. Pfeifer, Z. Naturforsch 17A (1962) 279.Google Scholar
  302. 286.
    D. Geschke and H. Pfeifer, J. Struct. Chem 5 (1964) 184.CrossRefGoogle Scholar
  303. 287.
    U. Lindner, Ann. Physik 16 (1965) 319.CrossRefGoogle Scholar
  304. 288.
    R. Hausser and F. Noack, Z. Physik 182 (1964) 93.CrossRefGoogle Scholar
  305. 289.
    K. Günther and H. Pfeifer, J. Struct. Chem 5 (1964) 177.CrossRefGoogle Scholar
  306. 299.
    R. Sperling and H. Pfeifer, Z. Naturforsch 19A (1964) 1342.Google Scholar
  307. 291.
    H. Pfeifer, D. Michel, D. Sames, and H. Sprinz, Mol. Phys 11 (1966) 591.CrossRefGoogle Scholar
  308. 292.
    H. Levanon and Z. Luz, J. Chem. Phys 49 (1968) 2031.CrossRefGoogle Scholar
  309. 293.
    I. Solomon, Phys. Rev 99 (1955) 559.CrossRefGoogle Scholar
  310. 294.
    I. Solomon and N. Bloembergen, J. Chem. Phys 25 (1956) 261.CrossRefGoogle Scholar
  311. 295.
    Z. Luz and S. Meiboom, J. Chem. Phys. 40 (1964) 1058, 1066, 2686.CrossRefGoogle Scholar
  312. See also Z. Luz, J. Chem. Phys 41 (1964) 1748, 1756.Google Scholar
  313. 296.
    T. J. Swift and R. E. Connick, J. Chem. Phys. 37 (1962) 307; 41 (1964) 255E.Google Scholar
  314. 297.
    H. S. Gutowsky, D. W. McCall, and C. P. Slichter, J. Chem. Phys 21 (1953) 279.CrossRefGoogle Scholar
  315. 298.
    H. M. McConnell, J. Chem. Phys 28 (1958) 430.CrossRefGoogle Scholar
  316. 299.
    M. Grant, H. W. Dodgen, and J. P. Hunt, Inorg. Chem 10 (1971) 71.CrossRefGoogle Scholar
  317. 300.
    A. M. Chmelnick and D. Fiat, J. Mag. Res 8 (1972) 325.Google Scholar
  318. 301.
    A. M. Chmelnick and D. Fiat, J. Chem. Phys 51 (1969) 4238.CrossRefGoogle Scholar
  319. 302.
    J. S. Rowlinson, Essay in Chemistry, Academic Press, New York, 1971, p. 1Google Scholar
  320. See also F. Reif, in Fundamentals of Statistical and Thermal Physics, McGraw-Hill, New York, 1965.Google Scholar
  321. 303.
    J. G. Kirkwood, in Theory of Solutions, Ed. by I. Oppenheim and Z. W. Salsburg, Gordon-Breach, New York, 1968.Google Scholar
  322. 304.
    B. E. Conway, R. E. Verrall, and J. E. Desnoyer, Z. Physik. Chem. (Leipzig), 230 (1965) 157.Google Scholar
  323. 305.
    B. E. Conway, Ann. Rev. Phys 17 (1966) 481.CrossRefGoogle Scholar
  324. 306.
    H. L. Friedman and C. V. Krishnan, in Water A Comprehensive Treatise, Ed. by F. Franks, Plenum Press, 1973, Vol. 3, p. 1.Google Scholar
  325. 307.
    R. Pottel, in Water, A Comprehensive Treatise, Ed. by F. Franks, Plenum Press, 1973, Vol. 3, p. 401.Google Scholar
  326. 308.
    L. H. Laliberté and B. E. Conway, J. Phys. Chem 74 (1970) 4116.CrossRefGoogle Scholar
  327. 309.
    A. K. Covington and K. E. Newman, J. Chem. Soc. Faraday Trans. Part 1(1973) 973.Google Scholar
  328. 310.
    H. E. Müser and J. Peterson, Fortschritte Physik 19 (1971) 559.CrossRefGoogle Scholar
  329. 311.
    D. D. Eley and M. G. Evans, Trans. Faraday Soc 34 (1938) 1098.CrossRefGoogle Scholar
  330. 312.
    E. R. Nightingale, Jr., J. Phys. Chem 63 (1959) 138.Google Scholar

Copyright information

© Plenum Press, New York 1975

Authors and Affiliations

  • E. von Goldammer
    • 1
  1. 1.Lehrstuhl f. Physik, Fachbereich BiologieUniversität RegensburgRegensburgGermany

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