Isomerization Reaction Kinetics of Catechins in Packaged Tea Drinks During Processing

  • Yoshihiro Komatsu
  • Shinichi Suematsu
  • Yoshihiro Hisanobu
  • Hideaki Saigo
  • Ryoko Matsuda
  • Kyoko Hara

Abstract

Stability of tea catechins during processing of tea drinks was examined. A dominant change of tea catechins by heating was epimerization. Effects of pH and temperature on reaction kinetics of degradation of -EC, -EGC, -ECg, and -EGCg in green tea infusion were investigated. A turning point temperature on the Arrhenius plot of apparent first order reaction rate constants was observed at 2.82 x 10-3 (1/K); 82 °C. Apparent energies of activation were temperature-dependent and increased by 7.3–11.4 times above the turning point temperature. The reaction rate constant of catechins in slightly acidified green tea infusion was less than half as much as that in the original infusion.

Keywords

Apparent Activation Energy Arrhenius Plot First Order Reaction Isomerization Reaction Original Infusion 
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References

  1. 1.
    Suematsu, S., Hisanobu, Y., Saigo, H., Matsuda, R., Hara, K., and Komatsu, Y., Effect of pH on stability of constituents in canned tea drinks, Nippon Shokuhin Kogyo Gakkaiski (in Japanese), 1992, 39, 178–82.CrossRefGoogle Scholar
  2. 2.
    Komatsu, Y., Suematsu, S., Hisanobu, Y., Saigo, H., Matsuda, R., and Hara, K., Effects of pH and temperature on reaction kinetics of catechins in green tea infusion. Biosci. Biotech. Biochem., 1993, 57(6), 907–10.CrossRefGoogle Scholar
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    Terada, S., Maeda, Y., Masui, T., Suzuki, Y., and Ina, K., Comparison of caffeine and catechin components in infusion of various tea and tea drinks. Nippon Shokuhin Kogyo Gakkaishi (in Japanese), 1987, 34, 20–27.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 1994

Authors and Affiliations

  • Yoshihiro Komatsu
    • 1
  • Shinichi Suematsu
    • 1
  • Yoshihiro Hisanobu
    • 1
  • Hideaki Saigo
    • 1
  • Ryoko Matsuda
    • 1
  • Kyoko Hara
    • 1
  1. 1.Toyo Institute of Food TechnologyKawanishi, Hyogo 666Japan

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