Advances in Cryogenic Engineering pp 1883-1890 | Cite as
A Semi-Theoretical Cubic Equation of State for Calculating Properties of Cryogenic Fluids
Chapter
Abstract
The analytical perturbed hard-sphere equation of state (EOS), recently developed from the square-well-linear-extension potential function, has been simplified. The resulting EOS is cubic in terms of volume while retaining the structure of the original equation. It was successfully applied to the prediction of thermodynamic properties of the molecular model fluids (square-well and Lennard-Jones), and saturated properties for seven cryogenic fluids (methane, argon, nitrogen, neon, oxygen, krypton and xenon).
Keywords
Fluid Phase Average Absolute Deviation Saturated Property Cryogenic Fluid Average Absolute Percent Deviation
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
Preview
Unable to display preview. Download preview PDF.
References
- 1.M.D. Donohue and J.M. Prausnitz, Perturbed hard chain theory for fluid mixtures: Thermodynamic properties for mixtures in natural gas and petroleum technology, AIChE J. 24: 849 (1978).CrossRefGoogle Scholar
- 2.M.D. Donohue and P. Vimalchand, The perturbed-hard-chain theory, extensions and application, Fluid Phase Equilib. 40: 185 (1988).CrossRefGoogle Scholar
- 3.G.M. Sowers and S.I. Sandler, Equation of state from generalized perturbation theory. Part II.The Lennard-Jones fluid, Fluid Phase Equilib. 67: 127 (1991).CrossRefGoogle Scholar
- 4.S. Shen and B.C.-Y. Lu, A simple perturbed equation of state from a pseudo-potential function, Fluid Phase Equilib. 84: 9 (1993).CrossRefGoogle Scholar
- 5.S. Shen and B.C.-Y. Lu, Extension of the SWLE equation of state to property calculations for soft-core fluids, Fluid Phase Equilib. 86: 27 (1993).CrossRefGoogle Scholar
- 6.N.F. Carnahan and K.E. Starling, Intermolecular repulsions and the equation of state for fluids, AIChE J. 18: 1184 (1972).CrossRefGoogle Scholar
- 7.J.A. Barker and D. Henderson, Perturbation theory and equation of state for fluids: II. A successful theory of liquid, J.Chem. Phys. 47: 4714 (1967).CrossRefGoogle Scholar
- 8.H.-M. Lin, H. Kim, T.-M. Guo and K.C. Chao, Cubic Chain-of-rotators equation of state and VLE calculations, Fluid Phase Equilib. 13: 143 (1983).CrossRefGoogle Scholar
- 9.D. Henderson, W.G. Madden and D.D. Fitts, Monte Carlo and hypernetted chain equation of state for the square-well fluid, J. Chem. Phys. 64: 5026 (1976).CrossRefGoogle Scholar
- 10.M.-X. Guo, W.-C. Wang and H.-Z. Lu, Equation of state for pure and mixture square-well fluid.II. Equation of State, Fluid Phase Equilib. 60: 221 (1990).CrossRefGoogle Scholar
- 11.K. Aim and I. Nezbeda, Perturbed hard sphere equation of state of real liquids. I. Examination of a simple equation of the second order, Fluid Phase Equilib. 12: 235(1983).CrossRefGoogle Scholar
- 12.K.H. Lee, Lombardo and S.I. Sandler, The generalized van der Waals partition function. II. Application to the square-well fluid, Fluid Phase Equilib. 21: 177 (1985).CrossRefGoogle Scholar
- 13.K.H. Lee and S.I. Sandler, The generalized van der Waals partition function. IV. Local composition models for mixtures of unequal-size molecules, Fluid Phase Equilib. 34: 113 (1987)CrossRefGoogle Scholar
- 14.Jr., J.R. Elliott and T.E. Daubert, The temperature dependence of the hard-sphere diameter, Fluid Phase Equilib. 34: 113 (1987).CrossRefGoogle Scholar
- 15.Y. Adachi, T. Fijhara, M. Takamiya and K. Nakanishi, Generalized equation of state for Lennard-Jones fluids- I. Pure fluids and simple mixtures, Fluid Phase Equilib. 39: 1 (1988)CrossRefGoogle Scholar
- 16.Yuhua Song and E. A. Masoon, Statistical-mechanical theory of a new analytical equation of state, J. Chem. Phys. 91: 7840 (1989).CrossRefGoogle Scholar
- 17.L.N. Canjar and F.S. Manning, “Thermodynamic Properties and Reduced Correlations for Gases,” Gulf publishing company, Houston (1967).Google Scholar
- 18.S. Angus and B. Armstrong, “International Thermodynamic Tables of the Fluid State, Argon,” Butterworths, London (1971).Google Scholar
- 19.S. Angus, B. Armstrong and K.M. deReuck, “International Thermodynamic Tables of the Fluid State, Nitrogen,” Pergamon, Oxford (1979).Google Scholar
- 20.N.B. Vargaftik, “Tables on the thermophysical properties of liquids and gases,” 2nd ed. Hemisphere Pub. Co., Washington, DC (1975).Google Scholar
Copyright information
© Springer Science+Business Media New York 1994