Biochemistry of Dioxygen pp 7-20 | Cite as
Ground-State Dioxygen
Chapter
Abstract
The critical characteristic of ground state dioxygen is that it is a triplet instead of a singlet state. This fact contributes to the kinetic barrier in reactions with ground-state dioxygen and also influences the type of reactions that do occur.
Preview
Unable to display preview. Download preview PDF.
References
- Alyea, H. M., and Backstrom, H. J. J., 1929. The inhibitive effect of alcohols on the oxidation of sodium sulfite, J. Am. Chem. Soc. 51: 90–109.CrossRefGoogle Scholar
- Barber, M., Faven, J., and Linnet, J. W., 1963. The mass spectrophotometric study of the reaction of methyl radicals with oxygen, Proc. R. Soc. London Ser. A 274: 306–318.CrossRefGoogle Scholar
- Clyne, M. A. A., and Thrush, B. A., 1963. Rates of elementary processes in the chain reaction between hydrogen and oxygen, Proc. R. Soc. London Ser. A 275: 559–574.CrossRefGoogle Scholar
- Coulson, C. A., 1947. Representation of simple molecules by molecular orbitals, Q. Rev. Chem. Soc. 1: 144–178.CrossRefGoogle Scholar
- Fletcher, A. N. and Heller, C. A., 1965. Chemiluminescence quenching terms, Photochem and Photobiol. 4: 1051–1058.CrossRefGoogle Scholar
- George, P., 1964. The fitness of oxygen, in Oxidases and Related Redox Systems, T. E. King, H. S. Mason, and M. Morrison (eds.), John Wiley, New York, pp. 1–36.Google Scholar
- Hiatt, R., Mill, T., and Mayo, F. R., 1968a. Homolytic decompositions of hydroperoxides. I. Summary and implications for autoxidation, J. Org. Chem. 33: 1416–1420.CrossRefGoogle Scholar
- Hiatt, R., Mill, T., Irvin, K. C., and Castleman, J. H., 1968b. Homolytic decompositions of hydroperoxides. III. Radical-induced decompositions of primary and secondary hydroperoxides, J. Org. Chem. 33: 1428–1430.CrossRefGoogle Scholar
- Howard, J. A., and Ingold, K. U., 1968a. Absolute rate constants for hydrocarbon oxidation. XI. The reactions of tertiary peroxy radicals, Can. J. Chem. 46: 2655–2660.Google Scholar
- Howard, J. A., and Ingold, K. U., 1968b. Absolute rate constants for hydrocarbon oxidation. XII. The reactions of secondary peroxy radicals, Can. J. Chem. 46: 2661–2666.Google Scholar
- Howard, J. A., and Ingold, K. U., 1968c. The self-reaction of sec-butyl-peroxy-radicals: Confirmation of the Russell mechanism, J. Am. Chem. Soc. 90: 1056–1058.CrossRefGoogle Scholar
- Ingold, K. V., 1969. Peroxy radicals, Acc. Chem. Res. 2: 1–9.CrossRefGoogle Scholar
- Kemal, C., Chan, T. W., and Bruice, T. C., 1977. Reaction of 302 with dihydroflavins. 1. N3,5-Dimethyl-1,5-dihydrolumiflavin and 1,5-dihydroisoalloxazines, J. Am. Chem. Soc. 99: 7272–7286.PubMedCrossRefGoogle Scholar
- Latimer, W. M. (ed.), 1938. The Oxidation States of the Elements and Their Potentials in Aqueous Solutions, Prentice Hall, New York.Google Scholar
- Mayo, F. R., 1968. Free radical autoxidation of hydrocarbons, Acc. Chem. Res. 1: 193–201.CrossRefGoogle Scholar
- Methoff, R. C., and Branch, G. E. K., 1930. The kinetics of the reaction of hexaphenylethylene with oxygen, J. Am. Chem. Soc. 52: 255–268.CrossRefGoogle Scholar
- Paris, D. P., 1965. Chemiluminescence of tetrakis-(dimethylamino)-ethylene, Photochem and Photobiol. 4: 1059–1065.CrossRefGoogle Scholar
- Porter, N. A., Dixon, J., and Ramdas, I., 1978. Cyclic peroxides and the thiobarbiturate assay, Biochim. Biophys. Acta 441: 506–512.Google Scholar
- Porter, N. A., Weber, B. A., Weenen, H., and Khan, J. A., 1980a. Autoxidation of polyunsaturated lipids: Factors controlling the stereochemistry of product hydroperoxides, J. Am. Chem. Soc. 102: 5597–5601.CrossRefGoogle Scholar
- Porter, N. A., Roe, N. A., and McPhail, A. T., 1980b. Serial cyclization of peroxy free radicals: Models for polyolefin oxidation, J. Am. Chem. Soc. 102: 7574–7576.CrossRefGoogle Scholar
- Porter, N. A., Lehman, L. S., Weber, B. A., and Smith, K. J., 1981. Unified mechanism for polyunsaturated fatty acid autoxidation: Composition of peroxy radical hydrogen atom abstraction, R-scission and cyclization, J. Am. Chem. Soc. 103: 6447–6455.CrossRefGoogle Scholar
- Russell, G. A., 1957. Deuterium-isotope effects in the autoxidation of aralkyl hydrocarbons: Mechanism of the interaction of peroxy radicals, J. Am. Chem. Soc. 79: 3871–3877.CrossRefGoogle Scholar
- Russell, G. H., Moye, A. J., and Nagpal, K. L., 1962. Effect of structure on the rate of reaction of carbanions with molecular oxygen, J. Am. Chem. Soc. 84: 4154–4155.CrossRefGoogle Scholar
- Sawyer, D. T., and Gibian, M. J., 1979. The chemistry of superoxide ion, Tetrahedron 35: 1471–1481.CrossRefGoogle Scholar
- Sawyer, D. T., and Seo, E. T., 1977. One electron mechanism for the electrondonical reduction of molecular oxygen, Inorg. Chem. 16: 499–501.CrossRefGoogle Scholar
- Taube, H., 1965. Mechanisms of oxidation with oxygen, J. Gen. Physiol. 49:Part 2, 29–50.PubMedCrossRefGoogle Scholar
- Tovrog, B. S., Mares, F., and Diamond, S. E. E., 1980. Cobalt-nitro complexes as oxygen transfer agents: Oxidation of olefins, J. Am. Chem. Soc. 102: 6616–6618.CrossRefGoogle Scholar
- Walsh, A. D., 1946. Processes in the oxidation of hydrocarbon fuels II, Trans. Faraday Soc. 43: 297–304.CrossRefGoogle Scholar
- Wilshire, J., and Sawyer, D. T., 1978. Redox chemistry of dioxygen species, Acc. Chem. Res. 12: 105–110.CrossRefGoogle Scholar
- Wood, P. M., 1974. The redox potential of the system oxygen-superoxide, FEBS Lett. 44: 22–24.CrossRefGoogle Scholar
Copyright information
© Plenum Press, New York 1985