Promises and Challenges of Unconventional Electrocatalyst Supports

Chapter
Part of the Lecture Notes in Energy book series (LNEN, volume 9)

Abstract

One of the most significant roadblocks in the commercialization and widespread implementation of proton exchange membrane fuel cells is the identification of low-cost, high-stability, high-activity electrocatalysts. An overwhelming amount of the work that has been done in this area has targeted the electrochemically active material, which has been the focus of much of this book. However, a key component to any catalyst is its support. Interaction between the catalyst and support dictates some of the most critical parameters for fuel cell performance including catalyst dispersion, particle size, faceting, and stability. Some supports, like graphitic carbon, interact very weakly with Pt and have a limited influence on catalyst activity and stability. On the other hand, recent work by several groups has shown that a strongly interacting support can drastically impact both catalyst activity and stability.

Keywords

Carbon Black Oxygen Reduction Reaction Proton Exchange Membrane Fuel Cell Membrane Electrode Assembly Carbon Aerogel 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Gasteiger HA, Kocha SS, Sompalli B, Wagner FT (2005) Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt Oxygen reduction catalysts for PEMFCs. Appl Catal B 56(1–2):9–35Google Scholar
  2. 2.
    Sheng W, Chen S, Vescovo E, Shao-Horn Y (2012) Size influence on the oxygen reduction reaction activity and instability of supported nanoparticles. J Electrochem Soc 159(2):B96–B103CrossRefGoogle Scholar
  3. 3.
    Perez-Alonzo FJ, McCarthy DN, Nierhoff A, Hernandez-Fernandez P, Strebel C, Stephens IEL, Hielsen JH, Charkendorff I (2012) The effect of size on the oxygen electroreduction activity of mass-selected platinum nanoparticles. Angew Chem Int Ed 51(16):1–4Google Scholar
  4. 4.
    Yamamoto S (2006) US Patent 7022642Google Scholar
  5. 5.
    Bezerra CWB, Zhang L, Liu H, Lee K, Marques ALB, Marques EP, Wang H, Zhang J (2007) A review of heat-treatment effects on stability of PEM fuel cell catalysts for oxygen reduction reaction. J Power Sourc 173(2):891–908CrossRefGoogle Scholar
  6. 6.
    Hernández-Fernández P, Montiel M, Ocón P, de la Fuente JLG, García-Rodríguez S, Rojas S, Fierro JLG (2010) Functionalization of multi-walled carbon nanotubes and application as a support for electrocatalysts in proton-exchange membrane fuel cell. Appl Catal B 99(1–2):343–352Google Scholar
  7. 7.
    Antolini E, Salgado JRC, Gonzalez ER (2006) The stability of Pt-M (M = first row transition metal) alloy catalysts and its effect on the activity in low temperature fuel cells. J Power Sourc 160(2):957–968CrossRefGoogle Scholar
  8. 8.
    Shao-Horn Y, Sheng WC, Chen S, Ferreira PJ, Holby EF, Morgan D (2007) Instability of supported platinum nanoparticles in low-temperature fuel cells. Top Catal 46(3–4):285–305CrossRefGoogle Scholar
  9. 9.
    Wilson MS, Garzon FH, Sickafus KE, Gottesfeld S (1993) Surface area loss of supported platinum in polymer electrolyte fuel cells. J Electrochem Soc 140(10):2872–2877CrossRefGoogle Scholar
  10. 10.
    Tada T (2003) High dispersion catalysts including novel carbon supports. In: Vielstich W, Lamm A, Gasteiger HA (eds) Handbook of fuel cells – fundamentals, technology and applications, vol 3. Wiley, New YorkGoogle Scholar
  11. 11.
    Eberl DD, Drits VA, Srodon J (1998) Deducing growth mechanisms for minerals from the shapes of crystal size distributions. Am J Sci 298(6):499–533CrossRefGoogle Scholar
  12. 12.
    Ferreira PJ, la O’ GJ, Shao-Horn Y, Morgan D, Makharia R, Kocha S, Gasteiger HA (2005) Instability of Pt/C electrocatalysts in proton exchange membrane fuel cells. J Electrochem Soc 152(11):A2256–A2271CrossRefGoogle Scholar
  13. 13.
    Mayrhofer KJJ, Meier JC, Ashton SJ, Wiberg GKH, Kraus F, Hanzlikn M, Arenz M (2008) Fuel cell catalyst degradation on the nanoscale. Electrochem Commun 10(8):1144–1147CrossRefGoogle Scholar
  14. 14.
    Mayrhofer KJJ, Ashton SJ, Meier JC, Wiberg GKH, Hanzlik M, Arenz M (2008) Non-destructive transmission electron microscopy study of catalyst degradation under electrochemical treatment. J Power Sourc 185(2):734–739CrossRefGoogle Scholar
  15. 15.
    Borup R et al (2007) Scientific aspects of polymer electrolyte fuel cell durability and degradation. Chem Rev 107(10):3904–3951CrossRefGoogle Scholar
  16. 16.
    Darling RM, Meyers JP (2003) Kinetic model of platinum dissolution in PEMFCs. J Electrochem Soc 150(11):A1523–A1527CrossRefGoogle Scholar
  17. 17.
    Darling RM, Meyers JP (2005) Mathematical model of platinum movement in PEM fuel cells. J Electrochem Soc 152(1):A242–A247CrossRefGoogle Scholar
  18. 18.
    Tang H, Qi Z, Ramani M, Elter JF (2006) PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode. J Power Sourc 158(2):1306–1312CrossRefGoogle Scholar
  19. 19.
    Maass S, Finsterwalder F, Frank G, Hartmann R, Merten C (2008) Carbon support oxidation in PEM fuel cell cathodes. J Power Sourc 176(2):444–451CrossRefGoogle Scholar
  20. 20.
    Passalacqua E, Antonucci PL, Vivaldi M, Patti A, Antonucci V, Giordano N, Kinoshita K (1992) The influence of Pt pn the electroxidation behaviour of carbon in phosphoric acid. Electrochim Acta 37(15):2725–2730CrossRefGoogle Scholar
  21. 21.
    Kinoshita K (1988) Carbon: electrochemical and physicochemical properties. Wiley, New YorkGoogle Scholar
  22. 22.
    Myers JP, Darling RM (2006) Model of carbon corrosion in PEM fuel cells. J Electrochem Soc 153(8):A1432–A1442CrossRefGoogle Scholar
  23. 23.
    Rodríguez-Reinoso F, Sepúlveda-Escribano A (2009) Carbon as catalyst support. In: Serp P, Figueiredo JL (eds) Carbon materials for catalysis. Wiley, New JerseyGoogle Scholar
  24. 24.
    Costamanga P, Srinivasan S (2001) Quantum jumps in the PEMFC science and technology from the 1960s to the year 2000: Part I. Fundamental scientific aspects. J Power Sourc 102(1–2):242–252CrossRefGoogle Scholar
  25. 25.
    Esmaeilifar A, Rowshanzamir S, Eikani MH, Ghanzanfari E (2010) Synthesis methods of low Pt-loading electrocatalysts for proton exchange membrane fuel cell systems. Energy 35(9):3941–3957CrossRefGoogle Scholar
  26. 26.
    Wee JH, Lee KY, Kim SH (2007) Fabrication methods for low-Pt-loading electrocatalysts in proton exchange membrane fuel cell systems. J Power Sourc 165(2):667–677CrossRefGoogle Scholar
  27. 27.
    Pumera M (2010) Graphene-based nanomaterials and their electrochemistry. Chem Soc Rev 39(11):4146–4157CrossRefGoogle Scholar
  28. 28.
    Rodríguez-Reinoso F (1998) The role of carbon materials in heterogeneous catalysis. Carbon 36(3):159–175CrossRefGoogle Scholar
  29. 29.
    Bandosz TJ (2009) Surface chemistry of carbon materials. In: Serp P, Figueiredo JL (eds) Carbon materials for catalysis. Wiley, New JerseyGoogle Scholar
  30. 30.
    Yoshitake T, Shimakawa Y, Kuroshima S, Kimura H, Ichihashi T, Kubo Y, Kasuya D, Takahashi K, Kokai F, Yudasaka M, Iijima S (2002) Preparation of fine platinum catalyst supported on single-wall carbon nanohorns for fuel cell application. Phys B 323(1–4):124–126CrossRefGoogle Scholar
  31. 31.
    Brunelle JP (1978) Preparation of catalysts by metallic complex adsorption on mineral oxides. Pure Appl Chem 50:1211–1229CrossRefGoogle Scholar
  32. 32.
    Bitter JP, De Jong KP (2009) Preparation of carbon-supported metal catalysts. In: Serp P, Figueiredo JL (eds) Carbon materials for catalysis. Wiley, New JerseyGoogle Scholar
  33. 33.
    Yu X, Ye S (2007) Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC: Part I. Physico-chemical and electronic interaction between Pt and carbon support, and activity enhancement of Pt/C catalyst. J Power Sourc 172(1):133–144MathSciNetCrossRefGoogle Scholar
  34. 34.
    Coloma F, Sepúlveda-Escribano A, Fierro JLG, Rodríguez-Reinoso F (1994) Preparation of platinum supported on pregraphitized carbon blacks. Langmuir 10(3):750–755CrossRefGoogle Scholar
  35. 35.
    Peigney A, Laurent C, Flahaut E, Bacsa R, Rousset A (2001) Specific surface area of carbon nanotubes and bundles of carbon nanotubes. Carbon 39(4):507–514CrossRefGoogle Scholar
  36. 36.
    Baughman RH, Zakhidov AA, de Heer WA (2002) Carbon nanotubes-the route towards applications. Science 297(5582):787–792CrossRefGoogle Scholar
  37. 37.
    Baxendale M (2003) The physics and applications of carbon nanotubes. J Mater Sci Mater Electron 14(10–12):657–659CrossRefGoogle Scholar
  38. 38.
    Georgakilas V, Gournis D, Tzitzios V, Pasquato L, Guldi DM, Prato M (2007) Decorating carbon nanotubes with metal or semiconductor nanoparticles. J Mater Chem 17(26):2679–2694CrossRefGoogle Scholar
  39. 39.
    Saha MS, Kundu A (2010) Functionalizing carbon nanotubes for proton exchange membrane fuel cells electrode. J Power Sourc 195(19):6255–6261CrossRefGoogle Scholar
  40. 40.
    Lee K, Zhang J, Wang H, Wilkinson DP (2006) Progress in the synthesis of carbon nanotube- and nanofiber-supported Pt electrocatalysts for PEM fuel cell catalysis. J Appl Electrochem 36(5):507–522CrossRefGoogle Scholar
  41. 41.
    Choi HC, Shim M, Bangsaruntip S, Dai H (2002) Spontaneous reduction of metal ions on the sidewalls of carbon nanotubes. J Am Chem Soc 124(31):9058–9059CrossRefGoogle Scholar
  42. 42.
    Sheng W, Lee SW, Crumlin EJ, Chen S, Shao-Horn Y (2011) Synthesis, activity, and durability of Pt nanoparticles supported on multi-walled carbon nanotubes for oxygen reduction. J Electrochem Soc 158(11):B1398–B1404CrossRefGoogle Scholar
  43. 43.
    Wang J, Yin G, Shao Y, Wang Z, Gao Y (2008) Electrochemical durability investigation of single-walled and multi-walled carbon nanotubes under potentiostatic conditions. J Power Sourc 176(1):128–131CrossRefGoogle Scholar
  44. 44.
    Castro Neto AH, Guinea F, Peres NMR, Novoselov KS, Geim AK (2009) The electronic properties of graphene. Rev Mod Phys 81(1):109–162CrossRefGoogle Scholar
  45. 45.
    Castro EV, Novoselov KS, Morozov SV, Peres NMR, Lopes dos Santos JMB, Nilsson J, Guinea F, Castro Neto AH (2007) Biased bilayer graphene: semiconductor with a gap tunable by the electric field effect. Phys Rev Lett 99(21):216802CrossRefGoogle Scholar
  46. 46.
    Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6(3):183–191CrossRefGoogle Scholar
  47. 47.
    Geim AK (2009) Graphene: status and prospects. Science 324(5934):1530–1534CrossRefGoogle Scholar
  48. 48.
    Park S, Ruoff RS (2009) Chemical methods for the production of graphenes. Nat Nanotechnol 4(4):217–224CrossRefGoogle Scholar
  49. 49.
    Kou R, Shao Y, Wang D, Engelhard MH, Kwak JH, Wang J, Viswanathan VV, Wang C, Lin Y, Wang Y, Aksay IA, Liu J (2009) Enhanced activity and stability of Pt catalysts on functionalized graphene sheets for electrocatalytic oxygen reduction. Electrochem Commun 11(5):954–957CrossRefGoogle Scholar
  50. 50.
    Serp P, Corrias M, Kalck P (2003) Carbon nanotubes and nanofibers in catalysis. Appl Catal A 253(2):337–358CrossRefGoogle Scholar
  51. 51.
    De Jong KP, Geus JW (2000) Carbon nanofibers: catalytic synthesis and application. Catal Rev Sci Eng 42(4):481–510CrossRefGoogle Scholar
  52. 52.
    Rodriguez NM (1993) A review of catalytically grown carbon nanofibers. J Mater Res 8(12):3233–3250CrossRefGoogle Scholar
  53. 53.
    Biddinger EJ, Ozkan US (2010) Role of graphitic edge plane exposure in carbon nanostructures for oxygen reduction reaction. J Phys Chem C 114(36):15306–15314CrossRefGoogle Scholar
  54. 54.
    Zheng JS, Zhang XS, Li P, Zhou XG, Yuan WK (2008) Microstructure effect of carbon nanofiber on electrocatalytic oxygen reduction reaction. Catal Today 131(1–4):270–277CrossRefGoogle Scholar
  55. 55.
    Zheng JS, Zhang XS, Li P, Zhu J, Zhou XG, Yuan WK (2007) Effect of carbon nanofiber microstructure on oxygen reduction activity of supported palladium electrocatalyst. Electrochem Commun 9(5):895–900CrossRefGoogle Scholar
  56. 56.
    Ngo Q, Cassell AM, Austin AJ, Li J, Krishnan S, Meyyappan M, Yang CY (2006) Characteristics of aligned carbon nanofibers for interconnect via applications. IEEE Electron Device Lett 27(4):221–224CrossRefGoogle Scholar
  57. 57.
    Ngo Q, Yamada T, Suzuki M, Ominami Y, Cassell AM, Li J, Meyyappan M, Yang CY (2007) Structural and electrical characterization of carbon nanofibers for interconnect via applications. IEEE Trans Nanotechnol 6(6):688–695CrossRefGoogle Scholar
  58. 58.
    Yoon SH, Lim S, Hong SH, Qiao W, Whitehurst DD, Mochida I, An B, Yokogawa K (2004) Carbon nano-rod as a structural unit of carbon nanofibers. Carbon 42(15):3087–3095CrossRefGoogle Scholar
  59. 59.
    Yoon SH, Lim S, Hong SH, Qiao W, Whitehurst DD, Mochida I, An B, Yokogawa K (2005) A conceptual model for the structure of catalytically grown carbon nano-fibers. Carbon 43(9):1828–1838CrossRefGoogle Scholar
  60. 60.
    Al-Muhtaseb SA, Ritter JA (2003) Preparation and properties of resorcinol-formaldehyde organic and carbon gels. Adv Mater 15(2):101–114CrossRefGoogle Scholar
  61. 61.
    Moreno-Castilla C, Maldonado-Hódar FJ (2005) Carbon aerogels for catalysis applications: an overview. Carbon 43(3):455–465CrossRefGoogle Scholar
  62. 62.
    Gavalda S, Kaneko K, Thomson KT, Gubbins KE (2001) Molecular modeling of carbon aerogels. Colloids Surf A 187–188:531–538CrossRefGoogle Scholar
  63. 63.
    Job N, Théry A, Pirard R, Marien J, Kocon L, Rouzaud JN, Béguin F, Pirard JP (2005) Carbon aerogels, cryogels and xerogels: influence of drying method on the textural properties of porous carbon materials. Carbon 43(12):2481–2494CrossRefGoogle Scholar
  64. 64.
    Smirnova A, Dong X, Hara H, Vasiliev A, Sammes N (2005) Novel carbon aerogel-supported catalysts for PEM fuel cell application. Int J Hydrogen Energy 30(2):149–158CrossRefGoogle Scholar
  65. 65.
    Ryoo R, Joo SH, Jun S (1999) Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation. J Phys Chem B 103(37):7743–7746CrossRefGoogle Scholar
  66. 66.
    Jun S, Joo SH, Ryoo R, Kruk M, Jaroniec M, Liu Z, Ohsuna T, Terasaki O (2000) Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure. J Am Chem Soc 122(43):10712–10713CrossRefGoogle Scholar
  67. 67.
    Lee J, Kim J, Kyeon T (2006) Recent progress in the synthesis of porous carbon materials. Adv Mater 18(16):2073–2094CrossRefGoogle Scholar
  68. 68.
    Ryoo R, Joo SH, Kruk M, Jaroniec M (2001) Ordered mesoporous carbon. Adv Mater 13(9):677–681CrossRefGoogle Scholar
  69. 69.
    Lee HI, Kim JH, You DJ, Lee JE, Kim JM, Ahn WS, Pak C, Joo SH, Chang H, Seung D (2008) Rational synthesis pathway for ordered mesoporous carbon with controllable 30- to 100-Angstrom pores. Adv Mater 20(4):757–762CrossRefGoogle Scholar
  70. 70.
    Joo SH, Choi SJ, Oh I, Kwak J, Liu Z, Terasaki O, Ryoo R (2001) Ordered nanoporous arrays of carbon supporting high dispersion of platinum nanoparticles. Nature 412(6843):169–172CrossRefGoogle Scholar
  71. 71.
    Shrestha S, Liu Y, Mustain WE (2011) Electrocatalytic activity and stability of Pt clusters on state-of-art supports: a review. Catal Rev Sci Eng 53(3):256–336CrossRefGoogle Scholar
  72. 72.
    Du CY, Yang T, Shi PF, Yin GP, Cheng XQ (2006) Performance analysis of the ordered and the conventional catalyst layers in proton exchange membrane fuel cells. Electrochim Acta 51(23):4934–4941CrossRefGoogle Scholar
  73. 73.
    Fang B, Kim M, Kim JH, Yu JS (2008) Controllable synthesis of hierarchical nanostructured hollow core/mesoporous shell carbon for electrochemical hydrogen storage. Langmuir 24(20):12068–12072CrossRefGoogle Scholar
  74. 74.
    Gross AF, Nowak AP (2010) Hierarchical carbon foams with independently tunable mesopore and macropore size distributions. Langmuir 26(13):11378–11383CrossRefGoogle Scholar
  75. 75.
    Fang B, Kim JH, Lee C, Yu JS (2008) Hollow macroporous core/mesoporous shell carbon with a tailored structure as a cathode electrocatalysts support for proton exchange membrane fuel cells. J Phys Chem C 112(2):639–645CrossRefGoogle Scholar
  76. 76.
    Fang B, Kim JH, Kim M, Kim M, Yu JS (2009) Hierarchical nanostructured hollow spherical carbon with mesoporous shell as a unique cathode catalyst support in proton exchange membrane fuel cell. Phys Chem Chem Phys 11(9):1380–1387CrossRefGoogle Scholar
  77. 77.
    Fang B, Kim JH, Kim M, Yu JS (2009) Ordered hierarchical nanostructured carbon as a highly efficient cathode catalyst support in proton exchange membrane fuel cell. Chem Mater 21(5):789–796CrossRefGoogle Scholar
  78. 78.
    Khomyakov PA, Giovannetti G, Rusu PC, Brocks G, van den Brink J, Kelly PJ (2009) First-principles study of the interaction and charge transfer between graphene and metals. Phys Rev B 79(19):195425CrossRefGoogle Scholar
  79. 79.
    Gong C, Lee G, Shan B, Vogel EM, Wallace RM, Cho K (2010) First-principle study of metal-graphene interfaces. J Appl Phys 108(12):123711CrossRefGoogle Scholar
  80. 80.
    Kong KJ, Choi Y, Ryu BH, Lee JO, Chang H (2006) Investigation of metal/carbon-related materials for fuel cell applications by electronic structure calculations. Mater Sci Eng C 26(5–7):1207–1210CrossRefGoogle Scholar
  81. 81.
    Okamoto Y (2006) Density-functional calculations of icosahedral M13 (M = Pt and Au) clusters on graphene sheets and flakes. Chem Phys Lett 420(4–6):382–386CrossRefGoogle Scholar
  82. 82.
    Wang JG, Lv YA, Li XN, Dong M (2009) Point-defect mediated bonding of Pt clusters on (5, 5) carbon nanotubes. J Phys Chem C 113(3):890–893CrossRefGoogle Scholar
  83. 83.
    Yumura T, Kimura K, Kobayashi H, Tanaka R, Okumura N, Yamabe T (2009) The use of nanometer-sized hydrographene species for support material for fuel cell electrode catalysts: a theoretical proposal. Phys Chem Chem Phys 11(37):8275–8284CrossRefGoogle Scholar
  84. 84.
    Qin W, Li X (2010) A theoretical study on the catalytic synergetic effects of Pt/graphene nanocomposites. J Phys Chem C 114(44):19009–19015CrossRefGoogle Scholar
  85. 85.
    Okazaki-Maeda K, Morikawa Y, Tanaka S, Kohyama M (2010) Structures of Pt clusters on graphene by first-principles calculations. Surf Sci 604(2):144–154CrossRefGoogle Scholar
  86. 86.
    Yamakawa S, Okazaki-Maeda K, Kohyama M, Hyodo S (2008) Phase-field model for deposition process of platinum nanoparticles on carbon substrate. J Phys Conf Ser 100:072042CrossRefGoogle Scholar
  87. 87.
    Kolasinski KW (2008) Surface science: foundations of catalysis and nanoscience, 2nd edn. Wiley, ChichesterGoogle Scholar
  88. 88.
    Zoval JV, Lee J, Gorer S, Penner RM (1998) Electrochemical preparation of platinum nanocrystallite s with size selectivity on basal plane oriented graphite surfaces. J Phys Chem B 102(7):1166–1175CrossRefGoogle Scholar
  89. 89.
    Toyoda E, Jinnouchi R, Hatanaka T, Morimoto Y, Mitsuhara K, Visikovskiy A, Kido Y (2011) The d-band structure of Pt nanoclusters correlated with the catalytic activity for an oxygen reduction reaction. J Phys Chem C 115(43):21236–21240CrossRefGoogle Scholar
  90. 90.
    Jinnouchi R, Toyoda E, Hatanaka T, Morimoto Y (2010) First principles calculations on site-dependent dissolution potentials of supported and unsupported Pt particles. J Phys Chem C 114(3):17557–17568CrossRefGoogle Scholar
  91. 91.
    Roy S, Christensen PA, Hamnett A, Thomas KM, Trapp V (1996) Direct methanol fuel cell cathodes with sulfur and nitrogen-based carbon functionality. J Electrochem Soc 143(10):3073–3079CrossRefGoogle Scholar
  92. 92.
    Ye S, Vijh AK, Dao LH (1996) A new fuel cell electrocatalyst based on highly porous carbonized polyacrylonitrile foam with very low platinum loading. J Electrochem Soc 143(1):L7–L9CrossRefGoogle Scholar
  93. 93.
    Ye S, Vijh AK, Dao LH (1996) Oxygen reduction on a new electrocatalyst based on highly porous carbonized polyacrylonitrile microcellular foam with very low platinum loading. J Electroanal Chem 415(1–2):115–121Google Scholar
  94. 94.
    Ye S, Vijh AK, Wang ZY, Dao LH (1997) A new electrocatalyst consisting of a molecularly homogeneous platinum-aerogel nanocomposite. Can J Chem 75(11):1666–1673CrossRefGoogle Scholar
  95. 95.
    Ye S, Vijh AK, Dao LH (1997) A new fuel cell electrocatalyst based on carbonized polyacrylonitrile foam. J Electrochem Soc 144(1):90–95CrossRefGoogle Scholar
  96. 96.
    Ye S, Vijh AK, Dao LH (1997) Fractal dimension of platinum particles dispersed in highly porous carbonized polyacrylonitrile microcellular foam. J Electrochem Soc 144(5):1734–1738CrossRefGoogle Scholar
  97. 97.
    Matter PH, Ozkan US (2006) Non-metal catalysts for dioxygen reduction in an acidic electrolyte. Catal Lett 109(3–4):115–123CrossRefGoogle Scholar
  98. 98.
    Gong K, Du F, Xia Z, Durstock M, Dai L (2009) Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction. Science 323(5915):760–764CrossRefGoogle Scholar
  99. 99.
    Qu L, Liu Y, Baek JB, Dai L (2010) Nitrogen-doped graphene as a efficient metal-free electrocatalyst for oxygen reduction in fuel cells. ACS Nano 4(3):1321–1326CrossRefGoogle Scholar
  100. 100.
    Shao Y, Sui J, Yin G, Gao Y (2008) Nitrogen-doped carbon nanostructures and their composites as catalytic materials for proton exchange membrane fuel cell. Appl Catal B 79(1):89–99CrossRefGoogle Scholar
  101. 101.
    Czerw R, Terrones M, Charlier JC, Blasé X, Foley B, Kamalakaran R, Grobert N, Terrones H, Tekleab D, Ajayan PM, Blau W, Rühle M, Carroll DL (2001) Identification of electron donor states in N-doped carbon nanotubes. Nano Lett 1(9):457–460CrossRefGoogle Scholar
  102. 102.
    Ma X, Wang E, Zhou W, Jefferson DA, Chen J, Deng S, Xu N, Yuan J (1999) Polymerized carbon nanobells and their field-emission properties. Appl Phys Lett 75(20):3105–3107CrossRefGoogle Scholar
  103. 103.
    Kurt R, Karimi A (2001) Influence of nitrogen on the growth mechanism of decorated C:N nanotubes. Chemphyschem 2(6):388–392CrossRefGoogle Scholar
  104. 104.
    Sjöström H, Stafström S, Boman M, Sundgren JE (1995) Superhard and elastic carbon nitride thin films having fullerenelike microstructure. Phys Rev Lett 75(7):1336–1339CrossRefGoogle Scholar
  105. 105.
    Maldonado S, Stevenson KJ (2005) Influence of nitrogen doping on oxygen reduction electrocatalysis at carbon nanofiber electrodes. J Phys Chem B 109(10):4707–4716CrossRefGoogle Scholar
  106. 106.
    Stafström S (2000) Reactivity of curved and planar carbon-nitride structures. Appl Phys Lett 77(24):3941–3943CrossRefGoogle Scholar
  107. 107.
    Pels JR, Kaptejin F, Moulijn JA, Zhu Q, Thomas KM (1995) Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis. Carbon 33(11):1641–1653CrossRefGoogle Scholar
  108. 108.
    Holme T, Zhou Y, Pasquarelli R, O’Hayre R (2010) First principles study of doped carbon supports for enhanced platinum catalysts. Phys Chem Chem Phys 12(32):9461–9468CrossRefGoogle Scholar
  109. 109.
    Groves MN, Chan ASW, Malardier-Jugroot C, Jugroot M (2009) Improving platinum catalyst binding energy to graphene through nitrogen doping. Chem Phys Lett 481(4–6):214–219CrossRefGoogle Scholar
  110. 110.
    Zhou Y, Neyerlin K, Olson TS, Plypenko S, Bult J, Dinh HN, Gennett T, Shao Z, O’Hayre R (2010) Enhancement of Pt and Pt-alloy fuel cell catalyst activity and durability via nitrogen-modified carbon supports. Energy Environ Sci 3(10):1437–1446CrossRefGoogle Scholar
  111. 111.
    Antolini E (2009) Carbon supports for low-temperature fuel cell catalysts. Appl Catal B 88(1–2):1–24CrossRefGoogle Scholar
  112. 112.
    Sheng ZH, Gao HL, Bao WJ, Wang FB, Xia XH (2012) Synthesis of boron doped graphene for oxygen reduction reaction in fuel cells. J Mater Chem 22(2):390–395CrossRefGoogle Scholar
  113. 113.
    Yang Z, Yao Z, Li G, Fang G, Nie H, Liu Z, Zhou X, Chen X, Huang S (2012) Sulfur-doped graphene as an efficient metal-free cathode catalyst for oxygen reduction. ACS Nano 6(1):205–211CrossRefGoogle Scholar
  114. 114.
    Yang L, Jiang S, Zhao Y, Zhu L, Chen S, Wang X, Wu Q, Ma J, Ma Y, Hu Z (2011) Boron-doped carbon nanotubes as metal-free electrocatalysts for the oxygen reduction reaction. Angew Chem Int Ed 50(31):7132–7135CrossRefGoogle Scholar
  115. 115.
    Liu ZW, Peng F, Wang HJ, Yu H, Zheng WX, Yang J (2011) Phosphorous-doped graphite layers with high electrocatalytic activity for the O2 reduction in an alkaline medium. Angew Chem Int Ed 50(14):3257–3261CrossRefGoogle Scholar
  116. 116.
    Wang J, Chen Y, Zhang Y, Ionescu MI, Li R, Sun X, Ye S, Knights S (2011) 3D boron doped carbon nanorods/carbon nanofiber hybrid composite: synthesis and application in highly stable proton exchange membrane fuel cell. J Mater Chem 21(45):18195–18198CrossRefGoogle Scholar
  117. 117.
    Acharya CK, Turner CH (2006) Stabilization of platinum clusters by substitutional boron dopants in carbon supports. J Phys Chem B 110(36):17706–17710CrossRefGoogle Scholar
  118. 118.
    Acharya CK, Sullivan DI, Turner CH (2008) Characterizing the interaction of Pt and PtRu clusters with boron-doped, nitrogen-doped, and activated carbon: density functional theory calculations and parameterization. J Phys Chem C 112(35):13607–13622CrossRefGoogle Scholar
  119. 119.
    Acharya CK, Li W, Liu Z, Kwon G, Turner CH, Lane AM, Nikles D, Klein T, Weaver M (2009) Effect of boron doping in the carbon support on platinum nanoparticles and carbon corrosion. J Power Sourc 192(2):324–329CrossRefGoogle Scholar
  120. 120.
    Deak DV, Biddinger EJ, Luthman KA, Ozkan US (2010) The effect of phosphorous in nitrogen-containing nanostructures on oxygen reduction in PEM fuel cells. Carbon 48(12):3637–3659CrossRefGoogle Scholar
  121. 121.
    Ozaki J, Kimura N, Anahara T, Oya A (2007) Preparation and oxygen reduction activity of BN-doped carbons. Carbon 45(9):1847–1853CrossRefGoogle Scholar
  122. 122.
    Ikeda T, Boero M, Huang SF, Terakura K, Oshima M, Ozaki JI, Miyata S (2010) Enhanced catalytic activity of carbon alloy catalysts codoped with boron and nitrogen for oxygen reduction reaction. J Phys Chem C 114(19):8933–8937CrossRefGoogle Scholar
  123. 123.
    Wohlgemuth SA, White RJ, Willinger MG, Titirici MM, Antonietti M (2012) A one-pot hydrothermal synthesis of sulfur and nitrogen doped carbon aerogels with enhanced electrocatalytic activity for oxygen reduction reaction. Green Chem 14:1515–1523CrossRefGoogle Scholar
  124. 124.
    Ganesan R, Lee JS (2005) Tungsten carbide microspheres as a noble-metal-economic electrocatalyst for methanol oxidation. Angew Chem Int Ed 44(40):6557–6560CrossRefGoogle Scholar
  125. 125.
    Zellner MB, Chen JG (2005) Surface science and electrochemical studies of WC and W2C PVD films as potential electrocatalysts. Catal Today 99(3–4):299–307CrossRefGoogle Scholar
  126. 126.
    Esposito DV, Chen JG (2011) Monolayer platinum supported on tungsten carbides as low-cost electrocatalysts: opportunities and limitations. Energy Environ Sci 4(10):3900–3912CrossRefGoogle Scholar
  127. 127.
    Liu Y, Mustain WE (2011) Structural and electrochemical studies of Pt clusters supported on high-surface-area tungsten carbide for oxygen reduction. ACS Catal 1(3):212–220CrossRefGoogle Scholar
  128. 128.
    Chhina H, Campbell S, Kesler O (2007) Thermal and electrochemical stability of tungsten carbide catalyst supports. J Power Sourc 164(2):431–440CrossRefGoogle Scholar
  129. 129.
    Chhina H, Campbell S, Kesler O (2008) High surface area synthesis, electrochemical activity, and stability of tungsten carbide supported Pt during oxygen reduction in proton exchange membrane fuel cells. J Power Sourc 179(1):50–59CrossRefGoogle Scholar
  130. 130.
    Wang Y, Song S, Maragou V, Shen PK, Tsiakaras P (2009) High surface area tungsten carbide microspheres as effective Pt catalyst support for oxygen reduction reaction. Appl Catal B 89(1–2):223–228CrossRefGoogle Scholar
  131. 131.
    Liang C, Ding L, Li C, Pang M, Su D, Li W, Wang Y (2010) Nanostructured WCx/CNT as highly efficient support of electrocatalysts with low Pt loading for oxygen reduction reaction. Energy Environ Sci 3(8):1121–1127CrossRefGoogle Scholar
  132. 132.
    Hsu IJ, Hansgent DA, McCandless BE, Willis BG, Chen JG (2011) Atomic layer deposition of Pt on tungsten monocarbide (WC) for the oxygen reduction reaction. J Phys Chem C 115(9):3709–3715CrossRefGoogle Scholar
  133. 133.
    Li G, Ma C, Zheng Y, Zhang W (2005) Preparation and electrocatalytic activity of hollow global tungsten carbide with mesoporosity. Microporous Mesoporous Mater 85(3):234–240CrossRefGoogle Scholar
  134. 134.
    Hara Y, Minami N, Matsumoto H, Itagaki H (2007) New synthesis of tungsten carbide particles and the synergistic effect with Pt metal as a hydrogen oxidation catalyst for fuel cell applications. Appl Catal A 332(2):289–296CrossRefGoogle Scholar
  135. 135.
    Li G, Ma C, Tang J, Zheng Y (2007) Preparation of tungsten carbide porous sphere core wrapped by porous multiwall. Mater Lett 61(4–5):991–993CrossRefGoogle Scholar
  136. 136.
    Liu Y, Shrestha S, Mustain WE (2012) Synthesis of nanosize tungsten oxide and its evaluation as an electrocatalyst support for oxygen reduction in acid media. ACS Catal 2(3):456–463CrossRefGoogle Scholar
  137. 137.
    Chhina H, Campbell S, Kesler O (2007) Ex situ evaluation of tungsten oxide as a catalyst support for PEMFCs. J Electrochem Soc 154(6):B533–B539CrossRefGoogle Scholar
  138. 138.
    Reichman B, Bard AJ (1979) The electrochromic process at WO3 electrodes prepared by vacuum evaporation and anodic oxidation of W. J Electrochem Soc 126(4):583–591CrossRefGoogle Scholar
  139. 139.
    Chen KY, Tseung ACC (1996) Effect of nafion dispersion on the stability of Pt/WO3 electrodes. J Electrochem Soc 143(9):2703–2707CrossRefGoogle Scholar
  140. 140.
    Raghuveer V, Viswanathan B (2005) Synthesis, characterization and electrochemical studies of Ti-incorporated tungsten trioxides as platinum supports for methanol oxidation. J Power Sourc 144(1):1–10CrossRefGoogle Scholar
  141. 141.
    Timperman L, Lewera A, Vogel W, Alonso-Vante N (2010) Nanostructured platinum becomes alloyed at oxide-composite substrate. Electrochem Commun 12(12):1772–1775CrossRefGoogle Scholar
  142. 142.
    Lewera A, Timperman L, Roguska A, Alonso-Vante N (2011) Metal-support interactions between nanosized Pt and metal oxides (WO3 and TiO2) studied using X-ray photoelectron spectroscopy. J Phys Chem C 115(41):20153–20159CrossRefGoogle Scholar
  143. 143.
    Liu Y, Mustain WE (2012) Evaluation of tungsten carbide as the electrocatalyst support for platinum hydrogen evolution/oxidation catalysts. Int J Hydrogen Energy 37(11):8929–8938CrossRefGoogle Scholar
  144. 144.
    Pang M, Li C, Ding L, Zhang J, Su D, Li W, Liang C (2010) Microwave-assisted preparation of Mo2C/CNTs nanocomposites as efficient electrocatalyst supports for oxygen reduction reaction. Ind Eng Chem Res 49(9):4169–4174CrossRefGoogle Scholar
  145. 145.
    Weigert EC, Esposito DV, Chen JG (2009) Cyclic voltammetry and X-ray photoelectron spectroscopy studies of electrochemical stability of clean and Pt-modified tungsten and molybdenum carbide (WC and Mo2C) electrocatalysts. J Power Sourc 193(2):501–506CrossRefGoogle Scholar
  146. 146.
    Hayden BE, Malevich DV, Pletcher D (2001) Electrode coatings from sprayed titanium dioxide nanoparticles − behaviour in NaOH solutions. Electrochem Commun 3:390–394CrossRefGoogle Scholar
  147. 147.
    Tauster SJ, Fung SC, Garten RL (1978) Strong metal-support interactions: group 8 noble metals supported on titanium dioxide. J Am Chem Soc 100(1):170–175CrossRefGoogle Scholar
  148. 148.
    Tauster SJ, Fung SC, Baker RTK, Horsley JA (1981) Strong interactions in metal-supported catalysts. Science 211(4487):1121–1125CrossRefGoogle Scholar
  149. 149.
    Hammer B, Norskov JK (2000) Theoretical surface science and catalysis-calculations and concepts. Adv Catal 45:71–129CrossRefGoogle Scholar
  150. 150.
    Ioroi T, Siroma Z, Fujiwara N, Yamazaki SI, Yasuda K (2005) Sub-stoichiometric titanium oxide-supported platinum electrocatalyst for polymer electrolyte fuel cells. Electrochem Commun 7(2):183–188CrossRefGoogle Scholar
  151. 151.
    Chhina H, Campbell S, Kesler O (2006) An oxidant-resistant indium tin oxide catalyst support for proton exchange membrane fuel cells. J Power Sourc 161(2):893–900CrossRefGoogle Scholar
  152. 152.
    Smith JR, Walsh FC, Clarke RL (1998) Electrodes based on magnéli phase titanium oxides: the properties and applications of Ebonex® materials. J Appl Electrochem 28(10):1021–1033CrossRefGoogle Scholar
  153. 153.
    Bartholomew RF, Frankl DR (1969) Electrical properties of some titanium oxides. Phys Rev 187(3):828–833CrossRefGoogle Scholar
  154. 154.
    Graves JE, Pletcher D, Clarke RL, Walsh FC (1991) The electrochemistry of magnéli phase titanium oxide ceramic electrodes: Part I. The deposition and properties of metal coatings. J Appl Electrochem 21(10):848–857CrossRefGoogle Scholar
  155. 155.
    Hu F, Ding F, Song S, Shen PK (2006) Pd electrocatalyst supported on carbonized TiO2 nanotube for ethanol oxidation. J Power Sourc 163(1):415–419CrossRefGoogle Scholar
  156. 156.
    Shanmugam S, Gedanken A (2007) Carbon-coated anatase TiO2 nanocomposite as a high-performance electrocatalyst support. Small 3(7):1189–1193CrossRefGoogle Scholar
  157. 157.
    Chen G, Bare SR, Mallouk TE (2002) Development of supported bifunctional electrocatalysts for united regenerative fuel cells. J Electrochem Soc 149(8):A1092–A1099CrossRefGoogle Scholar
  158. 158.
    Chhina H (2009) Oxidation resistant catalyst support for proton exchange membrane fuel cells. Ph.D. Thesis, Mechanical and Industrial Engineering, University of TorontoGoogle Scholar
  159. 159.
    Park KW, Seol KS (2007) Nb-TiO2 supported Pt cathode catalyst for polymer electrolyte membrane fuel cells. Electrochem Commun 9(9):2256–2260CrossRefGoogle Scholar
  160. 160.
    Nakada M, Ishihara A, Mitsushima S, Kamiya N, Ota K (2007) Effect on tin oxides on oxide formation and reduction of platinum particles. Electrochem Solid State Lett 10(1):F1–F4CrossRefGoogle Scholar
  161. 161.
    Saha MS, Li R, Cai M, Sun X (2007) High electrocatalytic activity of platinum nanoparticles on SnO2 nanowire-based electrodes. Electrochem Solid State Lett 10(8):B130–B133CrossRefGoogle Scholar
  162. 162.
    Chang G, Oyama M, Hirao K (2006) In situ chemical reductive growth on platinum nanoparticles on indium tin oxide surfaces and their electrochemical applications. J Phys Chem B 110(4):1860–1865CrossRefGoogle Scholar
  163. 163.
    Chang G, Oyama M, Hirao K (2006) Seed-mediated growth of palladium nanocrystals on indium tin oxide surfaces and their applicability as modified electrodes. J Phys Chem B 110(41):20362–20368CrossRefGoogle Scholar
  164. 164.
    Garsany Y, Epshteyn A, Purdy AP, More KL, Swider-Lyons KE (2010) High-activity, durable oxygen reduction electrocatalyst: nanoscale composite of platinum-tantalum oxyphosphate on vulcan carbon. J Phys Chem Lett 1(13):1977–1981CrossRefGoogle Scholar
  165. 165.
    Shao Y, Liu J, Wang Y, Lin Y (2009) Novel catalyst support materials for PEM fuel cells: current status and future prospects. J Mater Chem 19(1):46–59CrossRefGoogle Scholar
  166. 166.
    Marković NM, Schmidt TJ, Stamenković V, Ross PN (2001) Oxygen reduction reaction on Pt and Pt bimetallic surfaces: a selective review. Fuel Cells 1(2):105–116CrossRefGoogle Scholar
  167. 167.
    Ramirez-Caballero GE, Hirunsit P, Balbuena PB (2010) Shell-anchor-core structures for enhanced stability and catalytic oxygen activity. J Chem Phys 133(13):134705CrossRefGoogle Scholar
  168. 168.
    Liu Y, Mustain WE (2013) High stability, high activity Pt/ITO oxygen reduction electrocatalysts. J Am Chem Soc 135:530–533Google Scholar

Copyright information

© Springer-Verlag London 2013

Authors and Affiliations

  1. 1.Department of Chemical and Biomolecular EngineeringUniversity of ConnecticutStorrsUSA

Personalised recommendations