Lubricants and Mold-Release Agents

  • J. Štěpek
  • H. Daoust
Part of the Polymers book series (POLYMERS, volume 5)

Abstract

Lubricants are added to most polymers at low levels to increase the overall rate of processing or to improve surface properties [1–4]. They have been used in the past to facilitate extrusion, injection, compression, etc., of many polymers, mainly PVC, acrylonitrile-butadiene-styrene terpolymer (ABS), PS, PMMA, cellulose acetate (CA), polytetrafluoroethylene (PTFE), and so on. Figure 2.1 shows the relative importance of these polymers as far as the use of lubricants is concerned [5]. The most used lubricants and their relative importance in the United States in 1978 were [6]: Ca and Zn stearates, 45% by weight Waxes, 23.5% by weight Fatty acid amides, 19% by weight Fatty acid esters, 12% by weight When used with a good knowledge of the problem to be solved, lubricants often improve the properties of products (brightness, heat stability in the course of a processing operation, light stability, resistance to degradation by corrosive agents and to water absorption, better dispersion of additives, improved electrical, optical, and mechanical properties, etc. [7]). Some examples of lubricants are stearic acid and its Ca, Li, Ba, Al, Pb, etc., salts, natural waxes, microcrystalline paraffins with a high melting point (to avoid a cloudy appearance and greasy touch of finished products), mineral and vegetable oils, and whale fat (used to transform Teflon powder into some products).

Keywords

Fatty Acid Ester Calcium Stearate Sodium Stearate Lubricant Molecule Glyceryl Monostearates 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Borovik, M.C.: Mod. Plast. Encycl. 37, 356 (1960)Google Scholar
  2. 2.
    Kargin, V.A., Andrianov, G.I.: Vysokomol. Soed., Ser. A, 13, 1564 (1971)Google Scholar
  3. 3.
    Akutin, MS.: Plast. massy No. 10, 34 (1973)Google Scholar
  4. 4.
    Bower, J.D.: Mod. Plast. Encycl. 56, 198 (1979-1980)Google Scholar
  5. 5.
    Pfahler, G., Riedel, T.: Kunststoffe 66, 694 (1976)Google Scholar
  6. 6.
    Martino, R.J.: Mod. Plast. Encycl. 55, 51 (1978)Google Scholar
  7. 7.
    Dolež, B.: Die Beständigkeit von Plaste und Gummi. Carl Hanser Verlag, Munich, 1978Google Scholar
  8. 8.
    Matlack, J.D., Metzger, P.J.: J. Polym. Sci. B, 4, 11 (1966)CrossRefGoogle Scholar
  9. 9.
    Illman, G.: SPE J. 23, 71 (1967)Google Scholar
  10. 10.
    Van Veersen, J.: Plastics 21, 328 (1968)Google Scholar
  11. 11.
    Andrews, K.E., Butters, C., Wain, B.J.: Brit. Plast. 43, 88 (1970)Google Scholar
  12. 12.
    Worscheck, K., Wolf, K.: Kunststoffe 61, 645 (1971)Google Scholar
  13. 13.
    Stoklasa, K., Toufar, J.: Plast. Kaustch. 8, 193 (1971) (Czechoslovakia)Google Scholar
  14. 14.
    Werblinski, W.: Polim. Tworz. Wielk. 16, 462 (1971)Google Scholar
  15. 15.
    Ceskay, C., Szabados, M.: Muanyag es Gummi 8, 395 (1971)Google Scholar
  16. 16.
    Misterek, B.: Polim. Tworz. Wielk. 17, 628 (1972)Google Scholar
  17. 17.
    Mascia, L.: The Role of Additives in Plastics. Edward Arnold, London, 1974Google Scholar
  18. 18.
    Bowden, F.P., Tabor, D.: The Friction and Lubrication of Solids. Oxford University Press, London, 1950Google Scholar
  19. 19.
    Akhmato, A.S.: Molecular Physics of Boundary Friction. Israel Program for Scientific Translation, 1966Google Scholar
  20. 20.
    Foelsch, D.H.: Plastics Engineering 32, 44 (1976)Google Scholar
  21. 21.
    Berens, A.R., Folt, V.L.: Trans. Soc. Rheology 11, 95 (1967)CrossRefGoogle Scholar
  22. 22.
    Jacobson, U.: Brit. Plast. 34, 328 (1961)Google Scholar
  23. 23.
    Plato, G., Schröter, G.: Kunststoffe 50, 163 (1960)Google Scholar
  24. 24.
    Ragnes, P.: Kunststoffe 51, 428 (1961)Google Scholar
  25. 25.
    di Francesco, A.: Mat. Plast. Elast. 32, 10 (1966)Google Scholar
  26. 26.
    Sternagel, H.G.: Kunststoffetechnik 9, 428 (1970)Google Scholar
  27. 27.
    Altmann, V., Št ěp ek, J.: unpublished resultsGoogle Scholar
  28. 28.
    Reithmayer, A.S.: Gummi-Asbest-Kunststoffe 18, 435 (1965)Google Scholar
  29. 29.
    Gentner, A.W.: Kunststoffe 51, 8 (1961)Google Scholar
  30. 30.
    Anon.: Plastics World 35, 50 (1977)Google Scholar
  31. 31.
    Hoechst, A.G., Augsburg (BRD): Kunststoffadditive HoechstGoogle Scholar
  32. 32.
    Van Vonno, N.C.: Mod. Plast. Encycl. 53, (10A) 200 (1976-77)Google Scholar
  33. 33.
    Anon.: Mod. Plast. Encycl. 53, (10A) 669 (1976-77)Google Scholar
  34. 34.
    Anon.: Encyclopedia of Polymer Science and Technology, Vol. 8, Interscience, New York, 1968, pp. 330–336Google Scholar

Copyright information

© Springer Science+Business Media New York 1983

Authors and Affiliations

  • J. Štěpek
    • 1
  • H. Daoust
    • 2
  1. 1.Prague Institute of Chemical TechnologyPragueCzechoslovakia
  2. 2.Université de MontréalMontréalCanada

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