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Perspectives of Micro and Nanofabrication of Carbon for Electrochemical and Microfluidic Applications

  • R. Martinez-DuarteEmail author
  • G. Turon Teixidor
  • P. P. Mukherjee
  • Q. Kang
  • M. J. Madou
Chapter

Abstract

This chapter focuses on glass-like carbons, their method of micro and nanofabrication and their electrochemical and microfluidic applications. At first, the general properties of this material are exposed, followed by its advantages over other forms of carbon and over other materials. After an overview of the carbonization process of organic polymers we delve into the history of glass-like carbon. The bulk of the chapter deals with different fabrication tools and techniques to pattern polymers. It is shown that when it comes to carbon patterning, it is significantly easier and more convenient to shape an organic polymer and carbonize it than to machine carbon directly. Therefore the quality, dimensions and complexity of the final carbon part greatly depend on the polymer structure acting as a precursor. Current fabrication technologies allow for the patterning of polymers in a wide range of dimensions and with a great variety of tools. Even though several fabrication techniques could be employed such as casting, stamping or even Computer Numerical Controlled (CNC) machining, the focus of this chapter is on photolithography, given its precise control over the fabrication process and its reproducibility. Next Generation Lithography (NGL) tools are also covered as a viable way to achieve nanometer-sized carbon features. These tools include electron beam (e-beam), Focused-ion beam (FIB), Nano Imprint Lithography (NIL) and Step-and-Flash Imprint Lithography (SFIL). At last, the use of glass-like carbon in three applications, related to microfluidics and electrochemistry, is discussed: Dielectrophoresis, Electrochemical sensors, and Fuel Cells. It is exposed how in these applications glass-like carbon offers an advantage over other materials.

Keywords

Carbon Glass-like carbon Carbon MEMS SU-8 Photo-lithography Electron-beam Focused ion beam Nanoimprint lithography Microfluidics Dielectrophoresis Electrochemistry Nanoelectrodes Fractal electrodes Fuel cells 

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Copyright information

© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  • R. Martinez-Duarte
    • 1
    Email author
  • G. Turon Teixidor
    • 2
  • P. P. Mukherjee
    • 3
  • Q. Kang
    • 3
  • M. J. Madou
    • 2
  1. 1.Department of Mechanical and Aerospace EngineeringUniversity of CaliforniaIrvineUSA
  2. 2.Department of Mechanical and Aerospace EngineeringUniversity of CaliforniaIrvineUSA
  3. 3.Los Alamos National LaboratoryLos AlamosUSA

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