Replacement of Monocrystals

Chapter

A concept of metasomatic replacement of crystals is established on the basis of experimental investigations of about 200 model systems including sulphates, chromates, phosphates, nitrates, halides, and organometallic compounds. The results cover spread mineralogical phenomena of polymineral products, hollow and box-like pseudomorphs and display new effects like isomorphic replacement by simultaneous dissolution and growth, implantation of liquid or solid inclusions into a continuous protocrystal, and replacement of inclusions in protocrystals. Products are classified in order of the inheritance degree of protocrystal structure and shape from isomorphic monocrystal pseudomorphs to different polycrystal products and then to amorphous ones. Extent of preservation of the primary crystal shape is defined by the kinetic, first of all, diffusion properties of the system, while the product structure, effect of volume deficit or excess, and the reaction rate depend upon the type of phase equilibrium the system possesses, which is described by the concentration phase diagrams.

Keywords

Replacement Product Contrib Miner Petrol Metasomatic Rock Initial Crystal Econ Geol 
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