Ozone Modeling over Italy: A Sensitivity Analysis to Precursors Using BOLCHEM Air Quality Model

  • Alberto Maurizi
  • Mihaela Mircea
  • Massimo D’Isidoro
  • Lina Vitali
  • Fabio Monforti
  • Gabriele Zanini
  • Francesco Tampieri
Part of the NATO Science for Peace and Security Series Series C: Environmental Security book series (NAPSC)

Abstract

The sensitivity of ozone to the reduction of NOx and VOC over Italy has been investigated with the air quality model BOLCHEM, which includes two photochemical mechanisms: SAPRC-90 and CB-IV. The study has been carried out for some case studies during the years 1999 and 2003. The results show the relative importance of precursors in reducing the ozone levels and allow identifying regions of Italy where local emissions reduction strategies are less effective. This study also shows the effect of the errors in isoprene inventories on ozone concentrations.

Keywords

Air Quality BOLCHEM ozone photochemistry 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Baertsch-Ritter N, Keller J, Dommen J, Prevot ASH (2004) Effects of various meteorological conditions and spatial emission resolutions on the ozone con-centration and ROG/NOx limitation in the Milan area, Atmos. Chem. Phys., 4, 423-438.CrossRefGoogle Scholar
  2. Buzzi A, D’Isidoro M, Davolio S (2003) A case-study of an orographic cyclone south of the Alps during MAP SOP, Quart. J. Roy. Met. Soc., 129, 1795-1818.CrossRefGoogle Scholar
  3. Carter WPL (1990) A detailed mechanism for the gas-phase atmospheric reactions of organic compounds, Atmos. Environ., 24A, 481-518.Google Scholar
  4. Gery MW, Witten GZ, Killus JP, Dodge MC (1989) A photochemical kinetics mechanism for urban and regional scale computer modeling. J. Geophys. Res., 94 (D10), 12925-12956.CrossRefGoogle Scholar
  5. D’Isidoro M, Fuzzi S, Maurizi A, Monforti F, Mircea M, Tampieri F, Zanini G, Villani MG (2005) Development and Preliminary Results of a Limited Area Atmosphere-Chemistry Model: BOLCHEM, First ACCENT Symposium, Urbino 12-16, September, 2005.Google Scholar
  6. Gabusi V, Volta M (2005) Seasonal modelling assessment of ozone sensitivity to precursors over northern Italy, Atmos. Environ., 39, 2795-2804.CrossRefGoogle Scholar
  7. Junier M, Kirchner F, Clappier A, van den Bergh H (2005) The chemical mech-anism generation programme CHEMATA-Part2: comparison of four chemical mechanisms for mesoscale calculation of atmospheric pollution, Atmos. Environ., 39, 1161-1171.CrossRefGoogle Scholar
  8. Kang D, Aneja VP, Mathur R, Ray JD (2004) Observed and modelled VOC chemi-stry under high VOC/NOx conditions in the Southeast United States national parks, Atmos. Environ., 38, 4969-4974.CrossRefGoogle Scholar
  9. Mircea M, D’Isidoro, Massimo, Maurizi, Alberto, Vitali L, Monforti F, Zanini G, Tampieri, Francesco (2008) A comprehensive performance evaluation of the air quality model BOLCHEM to reproduce the ozone concentrations over Italy, Atmos. Environ., 42, 1169-1185.CrossRefGoogle Scholar
  10. Zanini G, Monforti F, Ornelli P, Vialetto G, Brusasca G, Calori G, Finardi G, Silibello C (2004) The MINNI project, 9th Conference on Harmonization within Atmospheric Dispersion Modelling for Regulatory Purposes, 1-4 June 2004, Garmisch-Partenkirchen, Germany.Google Scholar

Copyright information

© Springer Science + Business Media B.V 2008

Authors and Affiliations

  • Alberto Maurizi
  • Mihaela Mircea
    • 1
  • Massimo D’Isidoro
  • Lina Vitali
  • Fabio Monforti
  • Gabriele Zanini
  • Francesco Tampieri
  1. 1.Istituto di Scienze dellBolognaItaly

Personalised recommendations