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The Mixing Zone Between Waters of the Severnaya Dvina River and the White Sea

  • Viacheslav V. GordeevEmail author
  • Oleg S. Pokrovsky
  • Vladimir P. Shevchenko
Chapter
Part of the The Handbook of Environmental Chemistry book series (HEC, volume 81)

Abstract

The geochemical processes in the river-sea mixing zone (the Marginal Filter of the Severnaya Dvina Rivers) are considered in this chapter. The general trend in transformation of the elements and components as a result of physical, chemical, and biogeochemical processes in this zone is the transition from dissolved forms of element existence into particulate suspended forms with the following sedimentation on the bottom. So, the Marginal Filter is a very effective barrier on the way of dissolved and suspended sedimentary materials from the continent to the sea.

The results of the behavior of major elements, organic carbon, nutrients, and trace elements in the Severnaya Dvina estuary are presented and discussed. All the chemical elements are divided into three groups with different types of geochemical behavior in the MF zone – conservative, biogenic, and lithogenic ones with significant difference in their losses in the marginal filter.

The results of element determination along the profiles from the land to the sea in the Dvina Bay show that only Fe, rarely Mn, and several insoluble metals are non-conservative, while other trace elements are conservative in this area that is not typical in many other rivers in the world. The explanation consists in some peculiarities of the Severnaya Dvina river – first of all, in quite low concentrations of suspended matter (in 50 times less than in the global river discharge) and, on the contrary, in high concentration of DOC (at least 3–4 times more than global average in rivers). The extremely important role of the colloidal forms of elements was demonstrated in the nearest works. The non-conservative behavior of Fediss. and divalent insoluble elements is the consequence of the process of flocculation of colloidal fractions of the elements. The very important result of this transformation of river material is significant increase in the concentration of the “truly” dissolved elements. This last fraction does not have any losses in the mixing zone. The consequences of these processes will be more intensive in conditions of the climate warming, especially in the arctic conditions.

Keywords

Conservative and non-conservative behavior of elements Flocculation of colloidal forms of elements Processes in the mixing zone (marginal filter) Severnaya Dvina estuary Total and net fluxes of elements 

Notes

Acknowledgments

This research was performed in the framework of the state assignment of FASO Russia (Theme No. 0149-2018-0016), and analytical data were processed within the RSF grant (Project No. 14-27-00114-p).

References

  1. 1.
    Lisitsyn AP (1995) The marginal filter of the ocean. Oceanology 34(5):671–682 (in Russian)Google Scholar
  2. 2.
    Gordeev VV (1983) River runoff into the ocean and the peculiarities of its geochemistry. Nauka, Moscow, 160 pp (in Russian)Google Scholar
  3. 3.
    Gordeev VV (2012) Geochemistry of the river-sea system. Matushkina II, Moscow, 452 pp (in Russian)Google Scholar
  4. 4.
    Gordeev VV, Lisitsyn AP (2014) Geochemical interaction between the freshwater and marine hydrosphere. Russ Geol Geophys 55(5–6):562–581CrossRefGoogle Scholar
  5. 5.
    Pokrovsky OS, Shirokova LS, Viers J, Gordeev VV, Shevchenko VP, Chupakov AV, Vorobieva TY, Chandaudap F, Causserand C, Lanzanova A, Zouiten C (2014) Fate of colloids during estuarine mixing in the Arctic. Ocean Sci 10:107–124CrossRefGoogle Scholar
  6. 6.
    Pokrovsky OS, Shirokova LS, Viers J, Gordeev VV, Shevchenko VP, Chupakov AV, Gordeev VV (2017) Dissolved organic carbon and organo-mineral colloids in the mixing zone of the largest European Arctic River. In: Pokrovsky OS, Shirokova LS (eds) Dissolved organic matter (DOM). Properties, applications and behavior. Nova Science, New York, pp 273–292Google Scholar
  7. 7.
    Lisitsyn AP (1999) The continental-ocean boundary as a marginal filter in the world oceans. In: Gray JS, Ambrose Jr W, Szaniawska A (eds) Biogeochemical cycling and sediment ecology. Kluwer, Dordrecht, pp 69–103CrossRefGoogle Scholar
  8. 8.
    Savenko AV (2003) Geochemistry of Sr, F and B in the river-sea mixing zone. GEOS, Moscow, 170 pp (in Russian)Google Scholar
  9. 9.
    Monin AS, Gordeev VV (1988) Amazonia. Nauka, Moscow, 214 pp (in Russian)Google Scholar
  10. 10.
    Pokrovsky OS, Viers J, Shirokova LS, Shevchenko VP, Filippov AS, Dupré B (2010) Dissolved, suspended and colloidal fluxes of organic carbon, major and trace elements in Severnaya Dvina River and its tributary. Chem Geol 273:136–149CrossRefGoogle Scholar
  11. 11.
    Artemiev VE (1993) Geochemistry of organic substances in the river-sea system. Nauka, Moscow, 204 pp (in Russian)Google Scholar
  12. 12.
    Gordeev VV, Filippov AS, Kravchishina MD, Novigatsky AN, Pokrovsky OS, Shevchenko VP, Dara OM (2012) The geochemical peculiarities of the river discharge to the White Sea. The White Sea system. Water column and interacting with it in atmosphere, cryosphere, river runoff and the biosphere, vol 2. Scientific World, Moscow, pp 225–308 (in Russian)Google Scholar
  13. 13.
    Pokrovsky OS, Shirokova LS (eds) (2017) Dissolved organic matter (DOM). Properties, applications and behavior. Nova Science, New York, 323 ppGoogle Scholar
  14. 14.
    Sholkovitz ER (1976) Flocculation of dissolved organic and inorganic matter during the mixing of river water and sea water. Geochim Cosmochim Acta 40(7):831–845CrossRefGoogle Scholar
  15. 15.
    Redfield AC, Ketchum BH, Richards FA (1963) The influence of organisms on the composition of seawater. In: Hill MN (ed) The sea. Ideas and observations on progress in the study of the seas, vol 2. Wiley, London, pp 26–77Google Scholar
  16. 16.
    Shiller AM, Boyle EA (1991) Trace elements in the Mississippi River Delta outflow region: behavior at high discharge. Geochim Cosmochim Acta 55(11):3241–3251CrossRefGoogle Scholar
  17. 17.
    Kattner G, Lobbes J, Fritznar HP, Engbrodt R, Lara RJ (1999) Tracing dissolved organic substances and nutrients from the Lena Riva through Laptev Sea (Arctic). Mar Chem 65:25–35CrossRefGoogle Scholar
  18. 18.
    Koehler H, Meon B, Gordeev VV, Spitzy A, Amon RMW (2003) Dissolved organic matter (DOM) in the estuaries of Ob and Yenisey and the adjacent Kara Sea, Russia. Mar Sci 6:281–309Google Scholar
  19. 19.
    Amon RMW, Rinehart AJ, Duan S, Louchouarn P, Prokushkin A, Guggenberger G, Bauch D, Stedmon C, Raymond PA, Holmes RM, Mc Lelland JW, Peterson BJ, Walker SA, Zhulidov AV (2012) Dissolved organic matter sources in the large Arctic rivers. Geochim Cosmochim Acta 94:217–237CrossRefGoogle Scholar
  20. 20.
    Gordeev VV, Lutsarev SV, Demina LL (2004) Dissolved and suspended metals and organic carbon in period of spring flood of 2003 in the Dvinsky Bay of the White Sea. In: Geology of oceans and seas. The XVI international conference on marine geology, vol 1. GEOS, Moscow, pp 52–53 (in Russian)Google Scholar
  21. 21.
    Pokrovsky OS, Viers J, Vasyukova EV, Shevchenko VP, Shirokova LS, Kravchishina MD, Bogunov AYu (2007) The forms of existence of trace elements and organic matter in the White Sea basin (the river Severnaya Dvina and Pinega). In: Geology of oceans and seas. The XVII international scientific conference on marine geology, vol 3. GEOS, Moscow, pp 301–303 (in Russian)Google Scholar
  22. 22.
    Pokrovsky OS, Viers J, Dupré B, Chabaux F, Gaillardet J, Audry S, Prokushkin AS, Shirokova LS, Kiprotin SN, Lapitsky SA, Shevchenko VP (2012) Biogeochemistry of carbon, major and trace elements in watersheds of northern Eurasia drained to the Arctic Ocean: the change of fluxes, sources and mechanisms under the climate warming perspective. Compt Rendus Geosci 344:663–667CrossRefGoogle Scholar
  23. 23.
    Wen L-S, Santschi P, Gill G, Paternostro C (1999) Estuarine trace metal distributions in Galveston Bay: importance of colloidal forms in the speciation of the dissolved phase. Mar Chem 63:185–212CrossRefGoogle Scholar
  24. 24.
    Shevchenko VP, Bogunov AY, Lebedev AA, Leshchev AV, Mozgovaya GA, Moreva OY, Pokrovsky OS, Skibinsky LE, Stoikin MV, Filatova TB, Filippov AS, Khlebopashev PV, Chultsova AL, Yakovlev AE (2008) Multidisciplinary investigations in the estuarine zone of the Severnaya Dvina River and on the Pinega River in February–March of 2007. The ecological problems of the North. The proceedings of the reports of the youth scientific conference. 11–13 March 2008. Institute of Cological Problems of the North of Ural Department of the Russian Academy of Sciences, Arkhangelsk, pp 100–103Google Scholar
  25. 25.
    Savenko AV, Shevchenko VP (2005) Seasonal variability of the distribution of dissolved forms of biogenic elements and alkalinity in the Northern Dvina mouth. Water Resour 32(4):459–463 (in Russian)CrossRefGoogle Scholar
  26. 26.
    Savenko AV, Yefimova LE (2007) Transformation of dissolved substances discharge in the mixing zone of river and sea waters. Geoecological conditions of the Arctic coast of the Russian Federation and safety management. GEOS, Moscow, pp 285–299Google Scholar
  27. 27.
    Gordeev VV, Chultsova AL, Kochenkova AI, Belorukov SK, Chupakova AA, Moreva AA, Neverova NV, Chupakov AV (2018) Seasonal variations of dissolved inorganic biogenic elements in the lower Severnaya Dvina and in the river-sea mixing zone. Water Chem Ecol 4–6:73–85 (in Russian)Google Scholar
  28. 28.
    Savenko AV, Demidenko NA, Pokrovsky OS (2016) Chemical transformation of the runoff of dissolved matter in the mouth areas of the Onega and Mezen’ rivers. Geochem Int 54(5):439–448CrossRefGoogle Scholar
  29. 29.
    Savenko AV, Pokrovsky OS, Kozhin MN (2011) Transformation of the dissolved components runoff in the mouth areas of small watersheds of the southern coast of the Kola Peninsula. Oceanology 51(5):785–795CrossRefGoogle Scholar
  30. 30.
    Pokrovsky OS, Schott J (2002) Iron colloids/organic matter associated transport of major and trace elements in small boreal rivers and their estuaries (NW Russia). Chem Geol 190:141–179CrossRefGoogle Scholar
  31. 31.
    Sholkovitz R (1978) The flocculation of dissolved Fe, Mn, Al, Cu, Ni, Co and Cd during estuarine mixing. Earth Planet Sci Lett 41(1):77–86CrossRefGoogle Scholar
  32. 32.
    Kuma K, Katsumoto A, Nishioka J, Matsunaga K (1998) Size-fractioned iron concentrations and Fe (III) hydroxide solubility in various coastal waters. Estuar Coast Shelf Sci 47:275–283CrossRefGoogle Scholar
  33. 33.
    Stolpe B, Hassellöv M (2007) Changes in size distribution of fresh water nanoscale colloidal matter and associated elements on mixing with seawater. Geochim Cosmochim Acta 71:3292–3301CrossRefGoogle Scholar
  34. 34.
    Meybeck M (1982) Carbon, nitrogen and phosphorus transport by world rivers. Am J Sci 282:401–450CrossRefGoogle Scholar
  35. 35.
    Kravchishina ML, Lisitsyn AP (2011) Grain size composition of suspended matter in the marginal filter of the Severnaya Dvina River. Oceanology 51(1):94–109CrossRefGoogle Scholar

Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • Viacheslav V. Gordeev
    • 1
    Email author
  • Oleg S. Pokrovsky
    • 2
    • 3
    • 4
  • Vladimir P. Shevchenko
    • 1
  1. 1.Shirshov Institute of OceanologyRussian Academy of Sciences (IO RAS)MoscowRussia
  2. 2.Georesources and Environment Toulouse GET, CNRSUniversity Paul SabatierToulouseFrance
  3. 3.BIO-GEO-CLIM LaboratoryTomsk State UniversityTomskRussia
  4. 4.N. Laverov Federal Center for Integrated Arctic ResearchRussian Academy of SciencesArkhangelskRussia

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