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Homoatomic Polyanions of the Early p-Block Elements

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Clusters – Contemporary Insight in Structure and Bonding

Part of the book series: Structure and Bonding ((STRUCTURE,volume 174))

Abstract

This article reviews the chemistry of homoatomic polyanions of the early p-block elements (groups 13–15). The focus is on species that have been structurally authenticated in solid-state compounds and/or isolated from solution. The structures, bonding, electronic properties, and formation pathways of these homoatomic species are described in detail.

Dedicated to Professor Hansgeorg Schnöckel on the occasion of his 75th birthday.

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Acknowledgments

The author thanks the Engineering and Physical Sciences Research Council (EPSRC) and the University of Oxford for the continued financial support.

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Goicoechea, J.M. (2016). Homoatomic Polyanions of the Early p-Block Elements. In: Dehnen, S. (eds) Clusters – Contemporary Insight in Structure and Bonding. Structure and Bonding, vol 174. Springer, Cham. https://doi.org/10.1007/430_2015_5003

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