Spectroscopy and Chemical Bonding in Transition Metal Complexes

Chapter
Part of the Structure and Bonding book series (STRUCTURE, volume 172)

Abstract

Optical spectroscopy of transition metal complexes plays an important role in establishing excited-state electronic and nuclear structures and thus in the elucidation of the multitude of photophysical and photochemical relaxation processes. The most important advances in this area of research over the past decade are due to the development of new experimental techniques such as ultrafast spectroscopy as well as structure determination in conjunction with other methods such as high-pressure and variable temperature techniques. In this contribution, several paradigmatic systems, namely, of complexes of chromium(III), iron(II), ruthenium(II), nickel(II), platinum(II) and palladium(II), are discussed with regard to their excited electronic and nuclear structures and photophysical relaxation processes.

Keywords

High pressure Intersystem crossing Photophysics and photochemistry Spectroscopy Spin crossover Transition metal complexes Ultrafast methods 

Notes

Acknowledgements

We thank all our collaborators and friends who over the years have contributed in one way or another to our research and our understanding of the photophysical and photochemical properties of transition metal complexes and compounds. We acknowledge G3 travel funding.

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© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  1. 1.Département de chimie physiqueUniversité de GenèveGenèveSwitzerland
  2. 2.Département de chimieUniversité de MontréalMontréalCanada

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