Molecular Electronic Structures of Transition Metal Complexes I pp 17-28

Part of the Structure and Bonding book series (STRUCTURE, volume 142)

Electronic Structures of Oxo-Metal Ions


The dianionic oxo ligand occupies a very special place in coordination chemistry, owing to its ability to donate π electrons to stabilize high oxidation states of metals. The ligand field theory of multiple bonding in oxo-metal ions, which was formulated in Copenhagen 50 years ago, predicts that there must be an “oxo wall” between Fe–Ru–Os and Co–Rh–Ir in the periodic table. In this tribute to Carl Ballhausen, we review this early work as well as new developments in the field. In particular, we discuss the electronic structures of beyond-the-wall (groups 9 and 10) complexes containing metals multiply bonded to O- and N-donor ligands.


Ferryl Ligand field theory Oxo wall Vanadyl 

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© Springer-Verlag Berlin Heidelberg 2011

Authors and Affiliations

  1. 1.Beckman Institute, California Institute of TechnologyPasadenaUSA

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