Abstract
A structural model of precipitation membranes proposed by Hirsch-Ayalon (see [4]) is tested by the following experiments: (a) Measurements of the zeta potential of suspended BaSO4 crystals are used to estimate the sign and the absolute value of the charge density of the adsorption charges of the crystals forming the membrane, (b) the concentration limits for maintaining the membrane properties of BaSO4 precipitation zones, as well as for generating precipitation zones with membrane properties are established. Measurements of the non-ohmic current-voltage characteristics of a BaSO4 precipitation membrane demonstrate that Ba++ ions can be partially replaced by La+++ ions to maintain the membrane properties of BaSO4 precipitation zones.
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References
Terazawa T (1954) Jpn J Med Sci, Tokyo 3:139
Hirsch-Ayalon P (1956) Chemisch Weekblad 52:557
Woermann D (1984) Z Phys Chem Neue Folge 142:117
Ayalon A (1984) J Membr Sci 20:93
van Oss CJ (1984) In: Matijevic E (ed) Surface and Colloid Science, Vol 13, Plenum Press
Ortmann R, Woermann D (1986) Z Phys Chem Neue Folge 148:231
Buchanan AS, Heymann E (1949) J Coll Sci 4:137
Morimato T (1964) Bull Chem Soc Japan 37:386
Hirsch-Ayalon P (1979) J Membr Biol 51:1
Ortmann R, Woermann D (1984) React Polym 2:133
Helfferich F, Katchalsky A (1970) J Phys Chem 74:308
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© 1987 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
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Forke, R., Ortmann, R., Woermann, D., Mohamed, O. (1987). Electrochemical properties of barium sulfate precipitation membranes. In: Hoffmann, H. (eds) New Trends in Colloid Science. Progress in Colloid & Polymer Science, vol 73. Steinkopff. https://doi.org/10.1007/3-798-50724-4_63
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DOI: https://doi.org/10.1007/3-798-50724-4_63
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Online ISBN: 978-3-7985-1697-7
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