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Peracids and free radicals: A theoretical and experimental approach

  • Jacques Fossey
  • Daniel Lefort
  • Janine Sorba
Chapter
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 164)

Abstract

Organic peracids behave as a source of alkyl radicals and serve as a good model for studying their chemistry. The OH transfer by alkyl radicals and the stereoelectronic control of the reaction were investigated in detail. Inter- and the intramolecular hydrogen shifts by alkyl radicals were also studied. These results were used in order to undertake selective hydroxylation of hydrocarbons. Finally we turned our attention to the reactivity of electrophilic radicals towards peracids.

Keywords

Chain Mechanism Reflux Temperature Tertiary Alcohol Torsional Effect Intramolecular Hydrogen Transfer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag 1993

Authors and Affiliations

  • Jacques Fossey
    • 1
  • Daniel Lefort
    • 2
  • Janine Sorba
    • 1
  1. 1.Laboratoire des Mécanismes Réactionnels, URA 1307, Ecole PolytechniqueDCMRPalaiseauFrance
  2. 2.LECSO; UMR 28 CNRSThiaisFrance

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