Hollow Inorganic Capsules via Colloid-Templated Layer-by-Layer Electrostatic Assembly

  • Frank Caruso
Chapter
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 227)

Abstract

The preparation of hollow inorganic capsules of defined shape, composition and with tailored properties is of immense scientific and technological interest. This chapter highlights a recently developed layer-by-layer (LbL) assembly process for the creation of coated colloid particles (core-shell colloids), which are subsequently converted into hollow inorganic capsules. Sacrificial core template particles are coated with multiple layers of preformed inorganic nanoparticles, or inorganic molecular precursors, and oppositely charged polyelectrolyte, utilizing electrostatic attraction for construction of the layers on the particles. Calcination of the core-shell nanocomposite colloids yields hollow inorganic capsules of defined size and composition, determined by the template diameter and the nature of the charged inorganic species deposited, respectively. The capsule wall thickness can be controlled with nanoscale precision through the number of layers formed on the particles. The flexibility of the LbL strategy is demonstrated by a number of examples of nanoengineered hollow capsules. The creation of macroporous materials from the hollow capsules is also described. Additionally, the potential applications of the hollow colloid particles prepared are briefly discussed.

Keywords

Colloids Nanoparticles Multilayers Self-assembly 

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References

  1. 1.
    Wilcox DL, Berg M, Bernat T, Kellerman D, Cochran JK (eds) (1995) Hollow and solid spheres and microspheres: science and technology associated with their fabrication and application, vol 372. Materials Research Society Proceedings, PittsburghGoogle Scholar
  2. 2.
    Cochran JK (1998) Curr Opin Solid State Mater Sci 3:474CrossRefGoogle Scholar
  3. 3.
    Caruso F (2000) Chem Eur J 6:413CrossRefGoogle Scholar
  4. 4.
    Wilcox DL, Berg M (1995) Microsphere fabrication and application: an overview. In: Wilcox DL, Berg M, Bernat T, Kellerman D, Cochran JK (eds) Hollow and solid spheres and microspheres: science and technology associated with their fabrication and application, vol 372. Materials Research Society Proceedings, Pittsburgh, pp 3–13Google Scholar
  5. 5.
    Kawahashi N, Matijevic E (1991) J Colloid Interface Sci 143:103CrossRefGoogle Scholar
  6. 6.
    Garg A, Matijevic E (1988) J Colloid Interface Sci 126:243CrossRefGoogle Scholar
  7. 7.
    Kawahashi N, Matijevic E (1990) J Colloid Interface Sci 138:534CrossRefGoogle Scholar
  8. 8.
    Ohmori M, Matijevic E (1992) J Colloid Interface Sci 150:594CrossRefGoogle Scholar
  9. 9.
    Giersig M, Ung T, Liz-Marzan LM, Mulvaney P (1997) Adv Mater 9:570CrossRefGoogle Scholar
  10. 10.
    Giersig M, Liz-Marzan LM, Ung T, Su DS, Mulvaney P (1997) Ber Bunsenges Phys Chem 101:1617Google Scholar
  11. 11.
    Bamnolker H, Nitzan B, Gura S, Margel S (1997) J Mater Sci Lett 16:1412CrossRefGoogle Scholar
  12. 12.
    Walsh D, Mann S (1995) Nature 377:320CrossRefGoogle Scholar
  13. 13.
    Margel S, Weisel E (1984) J Polym Sci Chem Ed 22:145CrossRefGoogle Scholar
  14. 14.
    Philipse AP, van Bruggen MPB, Pathmamanoharan C (1994) Langmuir 10:92CrossRefGoogle Scholar
  15. 15.
    Caruso F (2001) Adv Mater 13:11CrossRefGoogle Scholar
  16. 16.
    Hotz J, Meier W (1998) Langmuir 14:1031CrossRefGoogle Scholar
  17. 17.
    Discher BM, Won Y-Y, Ege DS, Lee JC-M, Bates FS, Discher DE, Hammer DA (1999) Science 284:1143CrossRefGoogle Scholar
  18. 18.
    Zhao M, Sun L, Crooks RM (1998) J Am Chem Soc 120:4877CrossRefGoogle Scholar
  19. 19.
    Wendland MS, Zimmerman SC (1999) J Am Chem Soc 121:1389CrossRefGoogle Scholar
  20. 20.
    Thurmond KB, Kowalewski T, Wooley KL (1997) J Am Chem Soc 119:6656CrossRefGoogle Scholar
  21. 21.
    Thurmond KB, Huang H, Clark CG Jr, Kowalewski T, Wooley KL (1999) Colloids Surf B Biointerfaces 16:45CrossRefGoogle Scholar
  22. 22.
    Caruso F, Caruso RA, Möhwald H (1998) Science 282:1111CrossRefGoogle Scholar
  23. 23.
    Donath E, Sukhorukov GB, Caruso F, Davis SA, Möhwald H (1998) Angew Chem Int Ed 37:2201CrossRefGoogle Scholar
  24. 24.
    Iler RK (1966) J Colloid Interface Sci 21:569CrossRefGoogle Scholar
  25. 25.
    Decher G, Hong J-D (1991) Ber Bunsen-Ges Phys Chem 95:1430Google Scholar
  26. 26.
    Decher G, Hong J-D (1991) Makromol Chem Macromol Symp 46:321Google Scholar
  27. 27.
    Decher G (1997) Science 277:123CrossRefGoogle Scholar
  28. 28.
    Decher G (1996). In: Sauvage J-P, Hosseini MW (eds) Templating, self-assembly and self-organisation, vol 9. Pergamon, Oxford, pp 507–528Google Scholar
  29. 29.
    Bertrand P, Jonas A, Laschewsky A, Legras R (2000) Macromol Rapid Commun 21:319CrossRefGoogle Scholar
  30. 30.
    Hammond PT (1999) Curr Opin Colloid Interface Sci 4:430CrossRefGoogle Scholar
  31. 31.
    Keller SW, Johnson SA, Brigham ES, Yonemoto EH, Mallouk TE (1995) J Am Chem Soc 117:12879CrossRefGoogle Scholar
  32. 32.
    Chen T, Somasundaran P (1998) J Am Ceram Soc 81:140CrossRefGoogle Scholar
  33. 33.
    Dokoutchaev A, James JT, Koene SC, Pathak S, Prakash GKS, Thompson ME (1999) Chem Mater 11:2389CrossRefGoogle Scholar
  34. 34.
    Caruso F, Donath E, Möhwald H (1998) J Phys Chem B 102:2011CrossRefGoogle Scholar
  35. 35.
    Sukhorukov GB, Donath E, Davis S, Lichtenfeld H, Caruso F, Popov VI, Möhwald H (1998) Polym Adv Technol 9:759CrossRefGoogle Scholar
  36. 36.
    Caruso F, Lichtenfeld H, Donath E, Möhwald H (1999) Macromolecules 32:2317CrossRefGoogle Scholar
  37. 37.
    Caruso F, Schüler C, Kurth DG (1999) Chem Mater 11:3394CrossRefGoogle Scholar
  38. 38.
    Kurth DG, Caruso F, Schüler C (1999) Chem Commun 1579Google Scholar
  39. 39.
    Caruso F, Lichtenfeld H, Möhwald H, Giersig M (1998) J Am Chem Soc 120:8523CrossRefGoogle Scholar
  40. 40.
    Caruso F, Möhwald H (1999) Langmuir 15:8276CrossRefGoogle Scholar
  41. 41.
    Caruso RA, Susha A, Caruso F (2001) Chem Mater 13:400CrossRefGoogle Scholar
  42. 42.
    Rhodes K, Davis SA, Caruso F, Zhang B, Mann S (2000) Chem Mater 12:2832CrossRefGoogle Scholar
  43. 43.
    Caruso F, Susha AS, Giersig M, Möhwald H (1999) Adv Mater 11:950CrossRefGoogle Scholar
  44. 44.
    Caruso F, Spasova M, Susha A, Giersig M, Caruso RA (2001) Chem Mater 13:109CrossRefGoogle Scholar
  45. 45.
    Gittins DI, Susha AS, Schöler B, Caruso F (2002) Adv Mater 14:508CrossRefGoogle Scholar
  46. 46.
    Caruso F, Spasova M, Salgueiriño-Maceira V, Liz-Marzán LM (2001) Adv Mater 13:1090CrossRefGoogle Scholar
  47. 47.
    Cassagneau T, Caruso F (2002) Adv Mater 14:732CrossRefGoogle Scholar
  48. 48.
    Susha A, Caruso F, Rogach AL, Sukhorukov GB, Kornowski A, Máhwald H, Giersig M, Eychmüller A, Weller H (2000) Colloids Surf A Physicochem Eng Aspects 163:39CrossRefGoogle Scholar
  49. 49.
    Rogach A, Susha A, Caruso F, Sukhorukov G, Kornowski A, Kershaw S, Möhwald H, Eychmüller A, Weller H (2000) Adv Mater 12:333CrossRefGoogle Scholar
  50. 50.
    Caruso F, Shi X, Caruso RA, Susha A (2001) Adv Mater 13:740CrossRefGoogle Scholar
  51. 51.
    Mayya KS, Gittins DI, Dibaj AM, Caruso F (2001) Nano Letters 1:727CrossRefGoogle Scholar
  52. 52.
    Mayya, KS, Gittins DI, Caruso F (2001) Chem Mater 13:3833CrossRefGoogle Scholar
  53. 53.
    Wang XD, Yang WL, Tang Y, Wang YJ, Fu SK, Gao Z (2000) Chem Commun 2161Google Scholar
  54. 54.
    Valtchev V (2002) Chem Mater 14:956CrossRefGoogle Scholar
  55. 55.
    Valtchev V, Mintova S (2001) Micropor Mesopor Mater 43:41CrossRefGoogle Scholar
  56. 56.
    Dong AG, Wang YJ, Tang Y, Ren W, Yang WL, Gao Z (2002) Chem Commun 350Google Scholar
  57. 57.
    Sukhorukov GB, Donath E, Lichtenfeld H, Knippel E, Knippel M, Möhwald H (1998) Colloids Surf A Physicochem Eng Aspects 137:253CrossRefGoogle Scholar
  58. 58.
    Voigt A, Lichtenfeld H, Sukhorukov GB, Zastrow H, Donath E, Bäumler H, Möhwald H (1999) Ind Eng Chem Res 38:4037CrossRefGoogle Scholar
  59. 59.
    Lichtenfeld H, Knapschinsky L, Sonntag H, Shilov V (1995) Colloids Surf A Physicochem Eng Aspects 104:313CrossRefGoogle Scholar
  60. 60.
    Lichtenfeld H, Knapschinsky L, Dürr C, Zastrow H (1997) Progr Colloid Polym Sci 104:148CrossRefGoogle Scholar
  61. 61.
    Kerker M (1969) The scattering of light and other electromagnetic radiation. Academic Press, New York LondonGoogle Scholar
  62. 62.
    Caruso F, Caruso RA, Möhwald H (1999) Chem Mater 11:3309CrossRefGoogle Scholar
  63. 63.
    Schmitt J, Decher G, Dressick WJ, Brandow SL, Geer RE, Shashidhar R, Calvert JM (1997) Adv Mater 9:61CrossRefGoogle Scholar
  64. 64.
    Ung T, Liz-Marzán LM, Mulvaney P (2001) J Phys Chem B 105:3441CrossRefGoogle Scholar
  65. 65.
    Caruso F, Shi X, Caruso RA, Susha A (2001) Adv Mater 13:740CrossRefGoogle Scholar
  66. 66.
    Hanprasopwattana A, Rieker T, Sault AG, Dayte AK (1997) Catal Lett 45:165CrossRefGoogle Scholar
  67. 67.
    Möckel H, Giersig M, Willig F (1999) J Mater Chem 9:3051CrossRefGoogle Scholar
  68. 68.
    Baskaran S, Song L, Liu J, Chen YL, Graff GL (1998) J Am Ceram Soc 81:401CrossRefGoogle Scholar
  69. 69.
    Shi X, Caruso F (2002) Langmuir 18:904CrossRefGoogle Scholar
  70. 70.
    Brinker CJ, Scherer GW (eds) (1990) Sol-gel science: the physics and chemistry of sol-gel processing. Academic Press, San DiegoGoogle Scholar
  71. 71.
    Wang D, Caruso F (2002) Chem Mater 14:1909CrossRefGoogle Scholar
  72. 72.
    Velev OD, Kaler EW (2000) Adv Mater 12:531CrossRefGoogle Scholar
  73. 73.
    Xia Y, Gates B, Yin Y, Liu Y (2000) Adv Mater 12:693CrossRefGoogle Scholar
  74. 74.
    Velev OD, Tessier PM, Lenhoff AM, Kaler EW (1999) Nature 401:548CrossRefGoogle Scholar
  75. 75.
    Kulinowski KM, Jiang P, Vaswani H, Colvin VL (2000) Adv Mater 12:833CrossRefGoogle Scholar
  76. 76.
    Wijnhoven JEGJ, Vos WL (1998) Science 281:802CrossRefGoogle Scholar
  77. 77.
    Holland BT, Blanford CF, Stein A (1998) Science 281:538CrossRefGoogle Scholar
  78. 78.
    Vlasov YA, Yao N, Norris DJ (1999) Adv Mater 11:165CrossRefGoogle Scholar
  79. 79.
    Zakhidov AA, Baughman RH, Iqbal Z, Cui CX, Khayrullin I, Dantas SO, Marti I, Ralchenko VG (1998) Science 282:897CrossRefGoogle Scholar
  80. 80.
    Blanco A, Chomski E, Grabtchak S, Ibisate M, John S, Leonard SW, Lopez C, Meseguer F, Miguez H, Mondia JP, Ozin GA, Toader O, van Driel HM (2000) Nature 405:437CrossRefGoogle Scholar
  81. 81.
    Gates B, Yin Y, Xia Y (1999) Chem Mater 11:2827CrossRefGoogle Scholar
  82. 82.
    Johnson SA, Olivier PJ, Mallouk TE (1999) Science 283:963CrossRefGoogle Scholar
  83. 83.
    Jiang P, Cizeron J, Bertone JF, Colvin VL (1999) J Am Chem Soc 121:11,630Google Scholar
  84. 84.
    Wang D, Caruso F (2001) Adv Mater 13:350CrossRefGoogle Scholar
  85. 85.
    Cassagneau T, Caruso F (2002) Adv Mater 14:34CrossRefGoogle Scholar
  86. 86.
    Wang D, Salgueiriño-Maceira V, Liz-Marzán LM, Caruso F (2002) Adv Mater 14:908CrossRefGoogle Scholar
  87. 87.
    Wang D, Caruso RA, Caruso F (2001) Chem Mater 13:364CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2003

Authors and Affiliations

  • Frank Caruso
    • 1
  1. 1.Department of Chemical and Biomolecular EngineeringThe University of MelbourneAustralia

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