Uranyl photophysics

  • Christian K. Jørgensen
  • Renata Reisfeld
Conference paper
First Online:
Part of the Structure and Bonding book series (STRUCTURE, volume 50)

Abstract

The electron transfer bands of the triatomic uranyl group are due to a complicated manifold of excited levels described by relativistic effects in linear symmetry. The lowest of these levels can live for longer than 1 millisecond (in the absence of adjacent hydrogen atoms) and has its own chemistry, reacting with many anions, univalent silver and thallium, in a way entirely different from the groundstate. It is nearly as oxidizing as free fluorine; forms exciplexes; and abstracts hydrogen atoms from organic molecules (perhaps also in the ocean) and from water. The spectroscopic and luminescent properties are compared with the hexafluorides and the dioxo complexes of quinquevalent and sexivalent uranium, neptunium, plutonium and americium, and with roughly octahedral species, and tungstates. Uranyl glasses are useful for energy transfer to lanthanides and converting solar energy via photovoltaics.

Keywords

Uranium Hexafluoride Electronic Origin Luminescent Solar Concentrator Uranyl Salt Optical Electronegativity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Notes

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Copyright information

© Springer-Verlag 1982

Authors and Affiliations

  • Christian K. Jørgensen
    • 1
  • Renata Reisfeld
    • 2
  1. 1.Département de Chimie minérale, analytique et appliquéeUniversité de GenèveGeneva 4Switzerland
  2. 2.Department of Inorganic and Analytical Chemistry, and the Energy CenterHebrew UniversityJerusalemIsrael

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