Hypervalent Iodine Chemistry

Volume 373 of the series Topics in Current Chemistry pp 135-166


Arylation with Diaryliodonium Salts

  • Berit OlofssonAffiliated withArrhenius Laboratory, Department of Organic Chemistry, Stockholm UniversityStellenbosch Institute for Advanced Study (STIAS), Wallenberg Research Centre at Stellenbosch University Email author 

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This chapter focuses on recent developments in metal-free and metal-catalyzed arylations with diaryliodonium salts (diaryl-λ3-iodanes). Synthetic routes to diaryliodonium salts are briefly described, and chemoselectivity trends with unsymmetric iodonium salts are discussed.


Chemoselectivity Diaryl-λ3-iodanes Hypervalent iodine Iodine(III) compounds