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Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?: A Fruitful Interplay Anyway

Part 3: Catalysis by Group 10 and 11 Elements and Bimetallic Catalysis
  • Ullrich JahnEmail author
Chapter
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 320)

Abstract

This review summarizes the current status of transition metal catalyzed reactions involving radical intermediates in organic chemistry. This part focuses on radical-based methods catalyzed by group 10 and group 11 metal complexes. Reductive and redox-neutral C–C bond formations catalyzed by low-valent metal complexes as well as catalytic oxidative methods are reviewed. Catalytic processes which rely on the combination of two metal complexes are also covered.

Keywords

Catalysis Transition metals Radicals Electron transfer Cross-coupling Addition Cyclization 

Notes

Acknowledgments

This manuscript is dedicated to the memory of Professor Dr. Athelstan L. J. Beckwith, a pioneer of radical chemistry. Generous funding of the work by the Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic (Z4 055 0506), and the Grant Agency of the Czech Republic (203/09/1936) is gratefully acknowledged. I thank my group for critical reading of the manuscript and many helpful comments and discussions. I apologize to all colleagues for the omission of their work that were necessary due to space constraints of the manuscript.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2011

Authors and Affiliations

  1. 1.Institute of Organic Chemistry and BiochemistryAcademy of Sciences of the Czech RepublicPrague 6Czech Republic

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