Metal Catalyzed Reductive C–C Bond Formation pp 1-23

Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 279) | Cite as

Nickel-Catalyzed Reductive Couplings of Aldehydes and Alkynes

Chapter

Abstract

The nickel-catalyzed coupling of aldehydes and alkynes has evolved into a broadly useful procedure for the preparation of allylic alcohols. An overview of the many variants of the process, illustrations of complex synthetic applications, and a discussion of mechanism is provided. Additionally, a brief summary of mechanistically related nickel-catalyzed processes as well as a description of alternate strategies for the reductive coupling of aldehydes and alkynes using other metals is provided.

Allylic alcohol Nickel Reductive coupling Reductive cyclization Reductive cycloaddition 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2007

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of MichiganAnn ArborUSA

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